GJ - Privredna komora Srbije

GJ - Privredna komora Srbije GJ - Privredna komora Srbije

18.11.2014 Views

a) Slika 4. a) Adsorpciona izoterma b) Linearizovana Freundlich-ova adsorpciona izoterma b) Ravnoteţna adsorpcija Pb 2+ moţe se adekvatno predstaviti Freundlich-ovim modelom, na šta ukazuje visoka vrednost koeficijenta regresije. U tabeli 5, date su vrednosti parametara odreĊenih iz Freundlich-ovog modela adsorpcione izoterme. Pogodnost ovog modela potvrĊena je i u radovima Yuvaraja i sar., Singh i sar. [2,7]. Tabela 5. Ravnoteţni parametri izraĉunati iz Freundlich-ove adsorpcione izoterme za Pb 2+ na trini K F n R 2 190546,1 0,66 0,847 3.4. Uticaj granulometrijskog sastava na proces adsorpcije Veliĉina ĉestica adsorbensa u velikoj meri utiĉe na brzinu adsorpcije. Što su ĉestice sitnije, veća je dodirna površina trine i veća mogućnost adsorpcije na spoljnoj površini ĉestica. TakoĊe, prilikom difuzije metala u unutrašnje pore adsorbensa veći je otpor kod krupnijih ĉestica [15]. Ĉestice adsorbensa trebale bi da budu dovoljno male da bi njegova površina omogućila maksimalni kapacitet adsorpcije Pb 2+ ‒jona. Trina je prosejana na laboratorijskim sitima frakcije < 1mm i to 0,25; 0,45; 0,63; 0,85 mm i 1 mm. Zavisnost kapaciteta adsorpcije od veliĉine ĉestica trine data je na slici 5. Adsorpcija Pb 2+ ‒jona u neznatnoj meri zavisi od veliĉine ĉestica trine. Za ĉestice trine veliĉine: 0,25; 0,45 i 0,63 mm, kapacitet adsorpcije Pb 2+ bio je konstantan (9,94 mg g -1 ), dok je za veliĉinu ĉestica trine od 0,85 mm kapacitet adsorpcije jona Pb 2+ bio manji (9,78 mg g -1 ). Zakljuĉuje se da veliĉina ĉestica trine ne utiĉe znaĉajno na kapacitet adsorpcije. 4. Zakljuĉak Slika 5. Promena kapaciteta adsorpcije u zavisnosti od veliĉine ĉestica trine Proces adsorpcije koji se odvija na biosorbentima, sve se ĉešće koristi kao alternativna metoda za uklanjanje jona teških metala iz otpadnih voda. Tokom procesa adsorpcije Pb 2+ ‒jona na trini, na samom poĉetku dolazi do naglog smanjenja pH vrednosti rastvora, nakon ĉega pH poĉinje da raste dok ne postigne ravnoteţu. 471

Eksperimentalni podaci su pokazali da je maksimalni kapacitet adsorpcije Pb 2+ ‒jona na trini 9,6 mg g -1 . Kinetika adsorpcije predstavljena je jednaĉinom pseudo-drugog-reda, a Freundlich-ova izoterma se pokazala kao pogodna za predstavljanje ravnoteţne adsorpcije. Kapacitet adsorpcije jona bio je neznatno veći na sitnijoj frakciji trine, ali se moţe zakljuĉiti da granulometrijski sastav trine nije bitno uticao na kapacitet adsorpcije. Na osnovu eksperimentalnih podataka, trina se moţe okarakterisati kao pogodan adsorbens za uklanjanje Pb 2+ iz otpadnih voda. Zahvalnost Autori se zahvaljuju Ministrastvu ţivotne sredine, rudarstva i prostornog planiranja Republike Srbije na finansijskoj podršci (Projekti: br. 46010 i br. 33038). Reference: [1] Kumar P.S., Vincent C., Kirthika K., Kumar K.S.; Kinetics and equilibrium studies of Pb 2+ ion removal from aqueous solutions by use of nano-silversol-coated activated carbon; Brazilian Journal of Chemical Engineering; 27 (2), (2010), 339 – 346. [2] Yuvaraja G., Subbaiah M.V., Ramaiah K.P., Krishnaiah A.; Biosorption of Pb(II) from aqueous solution using Caesalpinia bonducella seed powder; Journal of Chemical and Pharmaceutical Research; 3(3), (2011), 214-222. [3] Li Y.-H., Di Z., Ding J., Wu D., Luan Z., Zhu Y.; Adsorption thermodynamic, kinetic and desorption studies of Pb 2+ on carbon nanotubes; Water Research; 39, (2005), 605–609. [4] Bulgariu L., Lupea M., Ciubota-Rosie C., Macoveanu M.; Possibility of using algae biomass for removing Pb (II) ions from aqeous solutions; Lucrări ştiinţifice; 53 (1), (2010), seria Agronomie. [5] Lim J., Kang H.-M., Kim L.-H., Ko S.-O.; Removal of Heavy Metals by Sawdust Adsorption: Equilibrium and Kinetic Studies; Environmental Engineering Research; 13 (2), (2008), 79-84. [6] Sud D., Mahajan G., Kaur M.P.; Agricultural waste material as potential adsorbent for sequestering heavy metal ions from aqueous solutions - A review; Bioresource Technology; 99 (2008), 6017–6027. [7] Singh K.K., Singh U., Yadav A.; Abatement of toxic heavy metals from highway runoff using sawdust as adsorbent; Journal of Chemical and Pharmaceutical Research; 3 (1), (2011), 338-348. [8] Argun M.E., Dursun S., Ozdemir C., Karatas M.; Heavy metal adsorption by modified oak sawdust: Thermodynamics and kinetics; Journal of Hazardous Materials 141, (2007), 77–85. [9] Boţić D., Stanković V., Gorgievski M., Bogdanović G., Kovaĉević R.; Adsorption of heavy metal ions by sawdust of decidous trees; Journal of Hazardous Materials; 171, (2009), 684–692. [10] Jeon C., Kim J.H.; Removal of lead ions using phosphorylated sawdust; Journal of Industrial and Engineering Chemistry; 15, (2009), 910–913. [11] Taty-Costodes V.C., Fauduet H., Porte C., Delacroix A.; Removal of Cd(II) and Pb(II) ions, from aqueous solutions, by adsorption onto sawdust of Pinus sylvestris; Journal of Hazardous Materials; B105 (2003), 121–142. [12] Baig K.S., Doan H.D., Wu J.; Multicomponent isotherms for biosorption of Ni 2+ and Zn 2+ ; Desalination; 249, (2009), 429–439. [13] Bhatti H.N., Samin G., Hanif M.A.; Enhanced Removal of Cu(II) and Pb(II) from Aqueous Solutions by Pretreated Biomass of Fusarium solani; Journal of the Chinese Chemical Society; 55, (2008), 1235- 1242. [14] Gil A., Assis F.C.C., Albeniz S., Korili S.A.; Removal of dyes from wastewaters by adsorption on pillared clays; Chemical Engineering Journal; 168, (2011), 1032–1040. [15] Shukla A., Zhang Y.-H., Dubey P., Margrave J.L., Shukla S.S.; The role of sawdust in the removal of unwanted materials from water; Journal of Hazardous Materials; B95 (2002), 137–152. 472

Eksperimentalni podaci su pokazali da je maksimalni kapacitet adsorpcije Pb 2+ ‒jona na trini 9,6 mg g -1 .<br />

Kinetika adsorpcije predstavljena je jednaĉinom pseudo-drugog-reda, a Freundlich-ova izoterma se pokazala<br />

kao pogodna za predstavljanje ravnoteţne adsorpcije. Kapacitet adsorpcije jona bio je neznatno veći na<br />

sitnijoj frakciji trine, ali se moţe zakljuĉiti da granulometrijski sastav trine nije bitno uticao na kapacitet<br />

adsorpcije. Na osnovu eksperimentalnih podataka, trina se moţe okarakterisati kao pogodan adsorbens za<br />

uklanjanje Pb 2+ iz otpadnih voda.<br />

Zahvalnost<br />

Autori se zahvaljuju Ministrastvu ţivotne sredine, rudarstva i prostornog planiranja Republike <strong>Srbije</strong> na<br />

finansijskoj podršci (Projekti: br. 46010 i br. 33038).<br />

Reference:<br />

[1] Kumar P.S., Vincent C., Kirthika K., Kumar K.S.; Kinetics and equilibrium studies of Pb 2+ ion removal<br />

from aqueous solutions by use of nano-silversol-coated activated carbon; Brazilian Journal of Chemical<br />

Engineering; 27 (2), (2010), 339 – 346.<br />

[2] Yuvaraja G., Subbaiah M.V., Ramaiah K.P., Krishnaiah A.; Biosorption of Pb(II) from aqueous solution<br />

using Caesalpinia bonducella seed powder; Journal of Chemical and Pharmaceutical Research; 3(3),<br />

(2011), 214-222.<br />

[3] Li Y.-H., Di Z., Ding J., Wu D., Luan Z., Zhu Y.; Adsorption thermodynamic, kinetic and desorption<br />

studies of Pb 2+ on carbon nanotubes; Water Research; 39, (2005), 605–609.<br />

[4] Bulgariu L., Lupea M., Ciubota-Rosie C., Macoveanu M.; Possibility of using algae biomass for<br />

removing Pb (II) ions from aqeous solutions; Lucrări ştiinţifice; 53 (1), (2010), seria Agronomie.<br />

[5] Lim J., Kang H.-M., Kim L.-H., Ko S.-O.; Removal of Heavy Metals by Sawdust Adsorption:<br />

Equilibrium and Kinetic Studies; Environmental Engineering Research; 13 (2), (2008), 79-84.<br />

[6] Sud D., Mahajan G., Kaur M.P.; Agricultural waste material as potential adsorbent for sequestering<br />

heavy metal ions from aqueous solutions - A review; Bioresource Technology; 99 (2008), 6017–6027.<br />

[7] Singh K.K., Singh U., Yadav A.; Abatement of toxic heavy metals from highway runoff using sawdust as<br />

adsorbent; Journal of Chemical and Pharmaceutical Research; 3 (1), (2011), 338-348.<br />

[8] Argun M.E., Dursun S., Ozdemir C., Karatas M.; Heavy metal adsorption by modified oak sawdust:<br />

Thermodynamics and kinetics; Journal of Hazardous Materials 141, (2007), 77–85.<br />

[9] Boţić D., Stanković V., Gorgievski M., Bogdanović G., Kovaĉević R.; Adsorption of heavy metal ions<br />

by sawdust of decidous trees; Journal of Hazardous Materials; 171, (2009), 684–692.<br />

[10] Jeon C., Kim J.H.; Removal of lead ions using phosphorylated sawdust; Journal of Industrial and<br />

Engineering Chemistry; 15, (2009), 910–913.<br />

[11] Taty-Costodes V.C., Fauduet H., Porte C., Delacroix A.; Removal of Cd(II) and Pb(II) ions, from<br />

aqueous solutions, by adsorption onto sawdust of Pinus sylvestris; Journal of Hazardous Materials;<br />

B105 (2003), 121–142.<br />

[12] Baig K.S., Doan H.D., Wu J.; Multicomponent isotherms for biosorption of Ni 2+ and Zn 2+ ; Desalination;<br />

249, (2009), 429–439.<br />

[13] Bhatti H.N., Samin G., Hanif M.A.; Enhanced Removal of Cu(II) and Pb(II) from Aqueous Solutions<br />

by Pretreated Biomass of Fusarium solani; Journal of the Chinese Chemical Society; 55, (2008), 1235-<br />

1242.<br />

[14] Gil A., Assis F.C.C., Albeniz S., Korili S.A.; Removal of dyes from wastewaters by adsorption on<br />

pillared clays; Chemical Engineering Journal; 168, (2011), 1032–1040.<br />

[15] Shukla A., Zhang Y.-H., Dubey P., Margrave J.L., Shukla S.S.; The role of sawdust in the removal of<br />

unwanted materials from water; Journal of Hazardous Materials; B95 (2002), 137–152.<br />

472

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!