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=-HKEGF ¢l/Z2B-H69J9EGF38D-¨-¨/oAY8M2¦57570hckHU-*Fd£UJ=2J98D/3<
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69-HJ90gFM2B8:-¨6=2;8D/Y-¨8:/>-¨6;FJ£UF>-H69-¨/¥6=K`57/hZ ¢rAYJ95T2f e.-¨83-H8D/>-HA ›¦29Fb57/('K^3570>-H69J=29K7L Z
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1KFM2B/>8:J#DUKU/ ' ¨ ¨ e.-H296 1KH72 © 'M‚ ¾ › ¦ Ÿ -¨698:AY-H/Z2 i œ i ‚ Ë0>/3F>6=2*NÆš&570>6=EGF n8D6=-H/Q5703EGFP8D-¤š¤8MLN-H69-¨/Y ¨-¨/ 8:/rjlege#N JN ¨-HU-*HU-H/ !geR-H6

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4
4
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570Jc
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8:J=2,-¨6 œ - -¨8:J9-€›¦8D/3J98DEGFZ29-¨/m8D/m-¨/3-¨/
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4
10 0 (Pt)
Oberflächenbedeckung
10 -1
10 -2
10 -3
10 -4
10 -5
10 -6
O C
H
CO
H 2
O
OH
0.01 0.011 0.012
Axiale Position [m]
jŠeJe>8mF:0>/gH gN&¢ ¨ ¦6=K Í FD- -H6 ©peR-H6&1TEGF>-¨/ e.-¨-HÊ I03/gHU-¨/ 57A I-*H78D/>/ -¨J IT5C2G5KF 298bZ
J9EGF3-¨/ I-H69-¨8:EGF>J%¾X578D5Keb5T298DJ9EGF3-?^`8:AW0gFD5T2B8:KU/DË2N¨›¦8D/gHZ5T/gHUJae.-¨6=EGFb0>J=J ¨ % JaF Ÿ A œ ›¦8D/JHZ57/gHUJ2B-HA Ÿ -¨695T2B0>6 ¨ ' ! 4œ
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0KMF_N‰Z ‚ j
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H-¨J=J9- H7-6n;KU/>/>-H/ nI-H69-H/ I_£U/>/>-H/#N / jŠeJe#N gN ' 8:J=2q-¨6dI7-¨/3/~e>576 œ /3-*FmFŒDU-H6ae>69570>EGFZ2yn8:696=EGF 8:- e.-¨8¢-H6 © ¦`8D-H69J=29K7L
2BFb5T/>J0c 6=-¨8}n;-¨6=-¨/3- 176=AY- Í />-H20n;-¨8:29-¨6ŒIC57/b5KFD5Ketn 1T6=2BJO-H69AV-cš¤-¨F Z
›
6=KMHU-¨/38D-¨6=0>/gHY-¨J !ge>6=8mHMHU-6egFD8:-*e.-¨/>-H/› 29Fb57/>JlJ=2G5C292WN‚š¤-H6 » 0b5KFM2B8D5T2B8bDU-
-¨EGF>J=-*F8:/-¨/ ¦6=K1 ¨-HJ9J9-H/‡n8:69EGFBeR-H8DA
I-H296B57EGFZ29-¨/t-¨J 0-H6aFD570Jc -¨J-¨6 ©pe.-¨6 &17EGF>-H/hZ
e.-¨-HÊ I03/gHU-¨/~8D/-¨/k-¨6=J=29-¨/ ¤ 8mFGFD8:AY-42B-¨6=/h-¨JfIC5T2B5KFs5KF 2B8DJ=EGF>-¨/jŠe>J=EGF>/>8M292B-HJO-¨0`2LFD8:EGF
jlege#N gN¢zË2N'jr-*e.-¨/ 0>/ eR-6FD-*HT2B-¨/ j%J9K76 Ÿ 298DKU/>J Ÿ F1C2f ¨-H/Q8:J=2\57Ajl/JcX57/gHy^3570>-H69J=29K7L8:-
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4
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% i O¡&£¦¥¨§© Q"¡ &¥)$%¡¤§@¥£¢ © $&© ¦$&O"¢+©l¥)©*,+¤¢" ©¤§l¡¤
a)
0.8
b)
0.76
C 2
H 6
-Umsatz
0.7
0.6
C 2
H 4
-Selektivität
0.72
0.68
0.5
0 1 2 3
H 2
/O 2
-Volumenverhältnis
0.64
0 1 2 3
H 2
/O 2
-Volumenverhältnis
c)
0.25
d)
0.12
Bodke
Zerkle
DETCHEM CHANNEL
CO-Selektivität
0.2
0.15
CH 4
-Selektivität
0.1
0.08
0.06
0.1
0 1 2 3
H 2
/O 2
-Volumenverhältnis
0.04
0 1 2 3
H 2
/O 2
-Volumenverhältnis
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n0>6=-rF:-¨8GHMFD8:EGFm-¨8D/
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2B8:J9EGF>-H/ I-H69-H8DEGF D7KU/ ¡¦hË A | 17/gHU-Bc KMFGH72o-¨6 ¨¢Ë A¥FD57/gHU-BjŠe3J9EGF>/>8M292
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e.-¨8>D7-¨6=J9EGF>8:-¨-H/>-¨/ -HA..-¨695T2B0>6=-¨/ Fs5TJ9J9-H/
l/Z2B-H69J=EGF>8D-H-t8DA[r-¨5KIZ2B8DK7/>JaHU-HJ9EGF>-HF>-¨/
„FD8:Ê I,570hcN8:-`^.-H8D-¨J>69K UFD-%8:A /3/>-¨6=-¨/V-¨J [-‚5KIZ2BK769J¦-¨6dI7-H/hZ
J98:EGFBFD-¨8:EGFZ2¦0>6=EGFY-H8D/>-H/
2B8:J9EGF>-H/jle>J9EGF>/38:2929J¤J2G5T2=2WN &57JrF>-H8©72 ö57J>Fb57J=-¨/hZƒ[r-¨5KIZ2B8:KU/>-¨/qJ98:/>8DJ+¨0 @-¨A7R-H6B5T290>69-H/BD7KU/tE‚5JN ©¨¦!¦ ‹ aŠN
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% O¡&£¦¥¨§© Q"¡ &¥)$%¡¤§@¥£¢ © $&©¡ ¦$&O"¢+©l¥)©*,+¤¢" ©¤§l¡¤
575 O C
700 O C
Katalysator
775 O C
0 0.06
0 C 2
H 4
Mol-Bruch 6 %
gN i£¢ ¦69K UFD-;-¨Ja ' v¦¥aZ ¤ KMFD-H/~e3690>EGF>J¦8:Aj¤/>/10gFD57696=-‚5KIZ29KU6>c"!>64DU-H69J9EGF38D-¨-
jŠeJe>8mF:0>/gH
57/>69-H/#N28:/gFs5TJ9Jae.-¨-¨/~8D/ Fb5TJ9-tJ=2B5T292 b/>-42WN lA
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¡ 3h¡&¤(¡&rr©¡¤ §I" %
¨¢57J43Fb57J9- ¨0W8:/>8:298D8:-¨69-H/#N¤570>6=EGFW-¨6=F!UFZ2 J=8DEGF,KEGF
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-HA..-¨695T2B0369-¨/ b/>-H/m8D- [r-¨5KIZ2B8:KU/>-¨/Q8D/Qe.-6D7KU6W-H6
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57J9J=-¨6q5KFDJ v¤570`2¡>6=K`0JI129-KN ;8DJ i % ¦M‹Ga-¨69F!UFZ2hJ98DEGF -H6 ¨¢-HJB57A\2B0>AVJB5T24 5KFGFDA 17FhZ
FD8:EGF gn;KMeR-H8-H8D/ H0>/>-HF>AY69K0H8D-H6=2{n8D69/>-HFhZ
3.5
3.5
3
2.5
mit Katalysator
ohne Katalysator
3
2.5
(b) CO
mit Katalysator
ohne Katalysator
Fluss [mmol/min]
2
1.5
1
(a) CO 2
0
Fluss [mmol/min]
2
1.5
1
0.5
0.5
0
200 300 400 500 600 700 800
Temperatur [°C]
200 300 400 500 600 700 800
Temperatur [°C]
3.5
1.8
Fluss [mmol/min]
3
2.5
2
1.5
1
0.5
(c) C 2 H 4
0
mit Katalysator
ohne Katalysator
Fluss [mmol/min]
1.6
1.4
1.2
1
0.8
0.6
0.4
0.2
(d) C 2 H 2
mit Katalysator
ohne Katalysator
0
200 300 400 500 600 700 800
Temperatur [°C]
200 300 400 500 600 700 800
Temperatur [°C]
AW0gFD5T2B8:KU/>-H/VAV8:20>/3< KUF>/>- ©peR-H6&17EGF3-¨/>6=-‚5KIZ2B8:KU/>-H/ 8D/ jŠe>F 1T/gHU8mHKI7-¨8M2ŽDUKU/ JdHZ57/gH 2n8DJ=EGF>-¨/r^`8bZ
jŠeJe>8mF:0>/gH JN © ¢ 0-¨6dHMFD-H8DEGF?-H6`^2BKTLNAV-¨/gH7-¨/ !3J9J9-o57A
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2B-HA..-¨695T2B036*N
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I-H8
57/>/gH69EGFq8D-fIC5T2B5KF 298DJ9EGF3-Œ[r-¨5KIZ2B8DK7/ >0>A
n;-¨8M2B-H6rJ2B6=KUA5]e n 1762BJ`[-‚5KIZ2B8:KU/>-H/8:/
e.-¨8(-H6 ;8mFD/gH DUK7/Pa ©
03/>6B5703EGF12{n8D6=-fjle>J9EGF>/38:292r-H6969-H8DEGFZ2 n8D6=5t-HJ
¤-¨6 ¦8:/b0>J=J -¨6 ö57J>Fb57J=-¨/hZƒ[r-¨5KIZ2B8:KU/>-¨/ n8:69/>8M2920>/>-;J=KMFDEGF3-¨/ D7-¨6aHKFD-¨8:EGFZ2 ¨ jlege#N gN © 2N
8D/-[-‚5KIZ2BK769-¨/,AY8M2>IC5T2B5KF
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-H6q576B570hc H0>6#!>Ê I H0Jc"!>F>6=-¨/ 8DJ2u57J9Jq0>6=EGF 8:- - ¦`K72BF3-¨69AV--©peR-H6&17EGF3-¨/>6=-‚5KIZ2B8:KU/

!JHU-¨/>< 176=AY- c 69-¨8GHU-¨J=-H24H2 n8:69< 0>A 8:298D8D-H69-H/#N
HU-H/
57J=J9-H6iZ ¨¢57J\Z ¨fFD-¨8:EGFgHU-2n8DEGFZ2B-HJ?nI-H69-H/ 57J9J=-¨69J2BK7L~0>/38GFD-42WN
j¤0hckHU690>/36 ¤ 5 ¦`8DAW0>A e.-¨8 @-¨A7R-H6B5T290>69-H/ I1/b5¢!JeR-H6
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‹ aŠN &57/>57EGFJ=8D/>-H/8:F>/>-¨/(I!U/>/>-H/h6=EGF5T0Jc 2B6=-H2B-H/ 357J9J%8:-pe.-¨8N

¡ 3h¡&¤(¡&rr©¡¤ §I"
^ A eRKMF:- 0>/>8:-¨/ @N8:/gFs5TJ9Jae.-¨A©N
i ¨
100%
80%
O 2
C 2 H 6
Umsatz
60%
40%
20%
0%
200 300 400 500 600 700 800
Temperatur [°C]
100%
80%
CO 2
CO
C 2 H 4
C-Selektivität
60%
40%
20%
0%
200 300 400 500 600 700 800
Temperatur [°C]
jŠeJe>8mF:0>/gH gN ¢ 0-¨6dHMFD-H8DEGF />< ^-*FD-6IZ2B8GD8M2 1T29-¨/ 570>J. ¦.-¨6=8DAV-¨/Z2 # ¨§¢ (

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