magdalena urbaniak analiza porównawcza zawartości dioksyn i ...

4
58-65 min
5
65-75 min
401,8559
403,8529
M+2
M+4
13 35 37
C12H2 Cl5 ClO2
13 35 37
C12H2 Cl4 Cl2O2
3
HxCDD
3
HxCDD
430,9729
445,7555
QC
M+4
C9F17
C12H2
PFK
35 Cl6 37 407,7818 M+2
Cl2O
C12H
OCDPE
35 Cl6 37 409,7789 M+4
ClO
C12H
PCDF
35 Cl5 37 417,8253
419,8220
423,7766
M
M+2
M+2
Cl2O
13 35
C12H Cl7O
13 35 37
C12H Cl6 ClO
C12H
PCDF
3
HpCDF
3
HpCDF 35 Cl6 37 425,7737 M+4
ClO2
C12H
PCDD
35 Cl5 37 Cl2O2 HpCDD
430,9729
435,8169
437,8140
479,7165
Lock
M+2
M+4
M+4
C9F17
13 35 37
C12H Cl6 ClO2
13 35 37
C12H Cl5 Cl2O2
C12H
PFK
3
HpCDD
3
HpCDD 35 Cl7 37 441,7428 M+2
Cl2O
C12
NCDPE
35 Cl7 37 ClO OCDF
442,9728
443,7399
Lock
M+4
C10F17
C12
PFK
35 Cl6 37 457,7377 M+2
Cl2O
C12
OCDF
35 Cl7 37 459,7348 M+4
ClO2
C12
OCDD
35 Cl6 37 469,7779
471,7750
513,6775
M+2
M+4
M+4
Cl2O2
13 35 37
C12 Cl7 ClO2
13 35 37
C12 Cl6 Cl2O2
C12
OCDD
3
OCDD
3
OCDD 35 Cl8 37 Cl2O DCDPE
ZAŁĄCZNIKI
Załącznik 26. Stężenie PCDD i PCDF w roztworach kalibracyjnych i roztworach
sprawdzenia kalibracji (każdy roztwór rozcieńczano 5-krotnie przed nastrzykiem).
Kongenery PCDD I PCDF CS1
CS2
CS3
CS4
CS5
(ng/ml) (ng/ml) (ng/ml) (ng/ml) (ng/ml)
2,3,7,8-TCDD 0,5 2 10 40 200
2,3,7,8-TCDF 0,5 2 10 40 200
1,2,3,7,8-PeCDD 2,5 10 50 200 1000
1,2,3,7,8-PeCDF 2,5 10 50 200 1000
2,3,4,7,8-PeCDF 2,5 10 50 200 1000
1,2,3,4,7,8-HxCDD 2,5 10 50 200 1000
1,2,3,6,7,8-HxCDD 2,5 10 50 200 1000
1,2,3,7,8,9-HxCDD 2,5 10 50 200 1000
1,2,3,4,7,8-HxCDF 2,5 10 50 200 1000
1,2,3,6,7,8-HxCDF 2,5 10 50 200 1000
1,2,3,7,8,9-HxCDF 2,5 10 50 200 1000
2,3,4,6,7,8-HxCDF 2,5 10 50 200 1000
1,2,3,4,6,7,8-HpCDD 2,5 10 50 200 1000
1,2,3,4,6,7,8-HpCDF 2,5 10 50 200 1000
1,2,3,4,7,8,9-HpCDF 2,5 10 50 200 1000
OCDD 5,0 20 100 400 2000
OCDF 5,0 20 100 400 2000
13
C12-2,3,7,8-TCDD 100 100 100 100 100
13
C12-2,3,7,8-TCDF 100 100 100 100 100
13
C12-1,2,3,7,8-PeCDD 100 100 100 100 100
13
C12-PeCDF 100 100 100 100 100
13
C12-2,3,4,7,8-PeCDF 100 100 100 100 100
13
C12-1,2,3,4,7,8-HxCDD 100 100 100 100 100
13
C12-1,2,3,6,7,8-HxCDD 100 100 100 100 100
13
C12-1,2,3,4,7,8-HxCDF 100 100 100 100 100
13
C12-1,2,3,6,7,8-HxCDF 100 100 100 100 100
13
C12-1,2,3,7,8,9-HxCDF 100 100 100 100 100
13
C12-1,2,3,4,6,7,8-HpCDD 100 100 100 100 100
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