14.06.2013 Views

Metode de rezolvare a problemelor de calcul la chimia analitica

Metode de rezolvare a problemelor de calcul la chimia analitica

Metode de rezolvare a problemelor de calcul la chimia analitica

SHOW MORE
SHOW LESS

Create successful ePaper yourself

Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.

<strong>Meto<strong>de</strong></strong> <strong>de</strong> <strong>rezolvare</strong> a <strong>problemelor</strong> <strong>de</strong> <strong>calcul</strong> <strong>la</strong> <strong>chimia</strong> analitică<br />

Problema 3.<br />

[H + ] = 10 -1,85 = 1/10 1,85 = 1,41 . 10 -2 (mol/ℓ);<br />

[H + ] = 10 -3,58 = 1/10 3,58 = 2,63 . 10 -4 (mol/ℓ);<br />

[H + ] = 10 -9,43 = 1/10 9,43 = 3,72 . 10 -10 (mol/ℓ);<br />

[H + ] = 10 -11,69 = 1/10 11,69 = 2,04 . 10 -12 (mol/ℓ).<br />

Calcu<strong>la</strong>Ńi concentraŃia ionilor <strong>de</strong> hidrogen în soluŃia acidului acetic cu concentraŃia<br />

0,20 mol/ℓ dacă constanta <strong>de</strong> disociere a acidului acetic este egală cu 1,74 . 10 -5 .<br />

Rezolvare:<br />

Se scrie ecuaŃia reacŃiei <strong>de</strong> disociere a acidului acetic:<br />

CH3COOH ↔ CH3COO - + H + .<br />

Se scrie expresia matematică a constantei <strong>de</strong> disociere:<br />

- +<br />

[CH 3COO<br />

] [H ]<br />

K d = .<br />

[CH 3COOH]<br />

Din ecuaŃia reacŃiei <strong>de</strong> disociere se ve<strong>de</strong> că:<br />

[CH3COO - ] = [H + ].<br />

łinând cont că acidul acetic este un acid s<strong>la</strong>b (α

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!