Derivati del morfinano - Appunti esami Farmacia e CTF
Derivati del morfinano - Appunti esami Farmacia e CTF
Derivati del morfinano - Appunti esami Farmacia e CTF
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Sintesi <strong>del</strong> levorfanolo<br />
O<br />
+<br />
HO<br />
O<br />
N<br />
CN<br />
COOH<br />
NH<br />
AcOH / AcONH 2<br />
AcONH 4<br />
Benzene<br />
(Cope)<br />
OCH 3<br />
OCH 3<br />
POCl 3<br />
o H 3 PO 4<br />
MeO<br />
COOH<br />
N<br />
CN<br />
O<br />
∆<br />
OCH 3<br />
Cl<br />
1) H 2 / Pd / BaSO 4<br />
2) HCHO / HCOOH<br />
+<br />
segue<br />
N<br />
CN<br />
H 2<br />
Ni Raney<br />
NH 2<br />
CH 3<br />
OCH
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