5-4 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL ...
5-4 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL ...
5-4 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL ...
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<strong>THERMODYNAMIC</strong> <strong>PROPERTIES</strong> AS A FUNCTION <strong>OF</strong> TEMPERATURE (continued)<br />
J/K⋅mol kJ/mol<br />
T/K C° p S° -(G°-H° (Tr))/T H°-H° (Tr) ΔfH° ΔfG° Log Kf 70. OXYGEN O (g) (continued)<br />
1400 20.853 193.815 177.236 23.212 253.908 161.463 –6.024<br />
1500 20.845 195.254 178.389 25.296 254.171 154.851 –5.392<br />
71. DIOXYGEN O 2 (g)<br />
298.15 29.378 205.148 205.148 0.000 0.000 0.000 0.000<br />
300 29.387 205.330 205.148 0.054 0.000 0.000 0.000<br />
400 30.109 213.873 206.308 3.026 0.000 0.000 0.000<br />
500 31.094 220.695 208.525 6.085 0.000 0.000 0.000<br />
600 32.095 226.454 211.045 9.245 0.000 0.000 0.000<br />
700 32.987 231.470 213.612 12.500 0.000 0.000 0.000<br />
800 33.741 235.925 216.128 15.838 0.000 0.000 0.000<br />
900 34.365 239.937 218.554 19.244 0.000 0.000 0.000<br />
1000 34.881 243.585 220.878 22.707 0.000 0.000 0.000<br />
1100 35.314 246.930 223.096 26.217 0.000 0.000 0.000<br />
1200 35.683 250.019 225.213 29.768 0.000 0.000 0.000<br />
1300 36.006 252.888 227.233 33.352 0.000 0.000 0.000<br />
1400 36.297 255.568 229.162 36.968 0.000 0.000 0.000<br />
1500 36.567 258.081 231.007 40.611 0.000 0.000 0.000<br />
72. SULFUR S (cr, l)<br />
298.15 22.690 32.070 32.070 0.000 0.000 0.000 0.000<br />
300 22.737 32.210 32.070 0.042 0.000 0.000 0.000<br />
368.3 24.237 37.030 32.554 1.649 0.000 0.000 0.000<br />
PHASE TRANSITION: Δ trs H = 0.401 kJ/mol, Δ trs S = 1.089 J/K⋅mol, crII–crI<br />
368.3 24.773 38.119 32.553 2.050 0.000 0.000 0.000<br />
388.36 25.180 39.444 32.875 2.551 0.000 0.000 0.000<br />
PHASE TRANSITION: Δ trs H = 1.722 kJ/mol, Δ trs S = 4.431 J/K⋅mol, crI–l<br />
388.36 31.710 43.875 32.872 4.273 0.000 0.000 0.000<br />
400 32.369 44.824 33.206 4.647 0.000 0.000 0.000<br />
500 38.026 53.578 36.411 8.584 0.000 0.000 0.000<br />
600 34.371 60.116 39.842 12.164 0.000 0.000 0.000<br />
700 32.451 65.278 43.120 15.511 0.000 0.000 0.000<br />
800 32.000 69.557 46.163 18.715 0.000 0.000 0.000<br />
882.38 32.000 72.693 48.496 21.351 0.000 0.000 0.000<br />
73. SULFUR S (g)<br />
298.15 23.673 167.828 167.828 0.000 277.180 236.704 –41.469<br />
300 23.669 167.974 167.828 0.044 277.182 236.453 –41.170<br />
400 23.233 174.730 168.752 2.391 274.924 222.962 –29.115<br />
500 22.741 179.860 170.482 4.689 273.286 210.145 –21.953<br />
600 22.338 183.969 172.398 6.942 271.958 197.646 –17.206<br />
700 22.031 187.388 174.302 9.160 270.829 185.352 –13.831<br />
800 21.800 190.314 176.125 11.351 269.816 173.210 –11.309<br />
900 21.624 192.871 177.847 13.522 215.723 162.258 –9.417<br />
1000 21.489 195.142 179.465 15.677 216.018 156.301 –8.164<br />
1100 21.386 197.185 180.985 17.821 216.284 150.317 –7.138<br />
1200 21.307 199.043 182.413 19.955 216.525 144.309 –6.282<br />
1300 21.249 200.746 183.759 22.083 216.743 138.282 –5.556<br />
1400 21.209 202.319 185.029 24.206 216.940 132.239 –4.934<br />
1500 21.186 203.781 186.231 26.325 217.119 126.182 –4.394<br />
74. DISULFUR S 2 (g)<br />
298.15 32.505 228.165 228.165 0.000 128.600 79.696 –13.962<br />
300 32.540 228.366 228.165 0.060 128.576 79.393 –13.823<br />
400 34.108 237.956 229.462 3.398 122.703 63.380 –8.276<br />
500 35.133 245.686 231.959 6.863 118.296 49.031 –5.122<br />
5-82
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