5-4 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL ...

THERMODYNAMIC PROPERTIES AS A FUNCTION OF TEMPERATURE (continued)
J/K⋅mol kJ/mol
T/K C° p S° -(G°-H° (Tr))/T H°-H° (Tr) ΔfH° ΔfG° Log Kf 54. WATER H2O (g) (continued)
300 33.606 189.040 188.833 0.062 –241.844 –228.500 39.785
400 34.283 198.791 190.158 3.453 –242.845 –223.900 29.238
500 35.259 206.542 192.685 6.929 –243.822 –219.050 22.884
600 36.371 213.067 195.552 10.509 –244.751 –214.008 18.631
700 37.557 218.762 198.469 14.205 –245.620 –208.814 15.582
800 38.800 223.858 201.329 18.023 –246.424 –203.501 13.287
900 40.084 228.501 204.094 21.966 –247.158 –198.091 11.497
1000 41.385 232.792 206.752 26.040 –247.820 –192.603 10.060
1100 42.675 236.797 209.303 30.243 –248.410 –187.052 8.882
1200 43.932 240.565 211.753 34.574 –248.933 –181.450 7.898
1300 45.138 244.129 214.108 39.028 –249.392 –175.807 7.064
1400 46.281 247.516 216.374 43.599 –249.792 –170.132 6.348
1500 47.356 250.746 218.559 48.282 –250.139 –164.429 5.726
55. IODINE I (g)
298.15 20.786 180.787 180.787 0.000 106.760 70.172 –12.294
300 20.786 180.915 180.787 0.038 106.748 69.945 –12.178
400 20.786 186.895 181.602 2.117 97.974 58.060 –7.582
500 20.786 191.533 183.142 4.196 75.988 50.202 –5.244
600 20.786 195.323 184.866 6.274 76.190 45.025 –3.920
700 20.786 198.527 186.594 8.353 76.385 39.816 –2.971
800 20.787 201.303 188.263 10.432 76.574 34.579 –2.258
900 20.789 203.751 189.851 12.510 76.757 29.319 –1.702
1000 20.795 205.942 191.352 14.589 76.936 24.038 –1.256
1100 20.806 207.924 192.770 16.669 77.109 18.740 –0.890
1200 20.824 209.735 194.110 18.751 77.277 13.426 –0.584
1300 20.851 211.403 195.377 20.835 77.440 8.098 –0.325
1400 20.889 212.950 196.577 22.921 77.596 2.758 –0.103
1500 20.936 214.392 197.717 25.013 77.745 –2.592 0.090
56. DIIODINE I 2 (cr, l)
298.15 54.440 116.139 116.139 0.000 0.000 0.000 0.000
300 54.518 116.476 116.140 0.101 0.000 0.000 0.000
386.75 61.531 131.039 117.884 5.088 0.000 0.000 0.000
PHASE TRANSITION: Δ trs H = 15.665 kJ/mol, Δ trs S = 40.504 J/K⋅mol, cr–l
386.75 79.555 171.543 117.884 20.753 0.000 0.000 0.000
400 79.555 174.223 119.706 21.807 0.000 0.000 0.000
457.67 79.555 184.938 127.266 26.395 0.000 0.000 0.000
57. DIIODINE I 2 (g)
298.15 36.887 260.685 260.685 0.000 62.420 19.324 –3.385
300 36.897 260.913 260.685 0.068 62.387 19.056 –3.318
400 37.256 271.584 262.138 3.778 44.391 5.447 –0.711
457.67 37.385 276.610 263.652 5.931 pressure = 1 bar
500 37.464 279.921 264.891 7.515 0.000 0.000 0.000
600 37.613 286.765 267.983 11.269 0.000 0.000 0.000
700 37.735 292.573 271.092 15.037 0.000 0.000 0.000
800 37.847 297.619 274.099 18.816 0.000 0.000 0.000
900 37.956 302.083 276.965 22.606 0.000 0.000 0.000
1000 38.070 306.088 279.681 26.407 0.000 0.000 0.000
1100 38.196 309.722 282.249 30.220 0.000 0.000 0.000
1200 38.341 313.052 284.679 34.047 0.000 0.000 0.000
1300 38.514 316.127 286.981 37.890 0.000 0.000 0.000
1400 38.719 318.989 289.166 41.751 0.000 0.000 0.000
1500 38.959 321.668 291.245 45.635 0.000 0.000 0.000
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