5-4 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL ...
5-4 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL ... 5-4 STANDARD THERMODYNAMIC PROPERTIES OF CHEMICAL ...
THERMODYNAMIC PROPERTIES AS A FUNCTION OF TEMPERATURE (continued) J/K⋅mol kJ/mol T/K C° p S° -(G°-H° (Tr))/T H°-H° (Tr) ΔfH° ΔfG° Log Kf 26. ACETONE C3H6O (g) (continued) 900 154.097 418.860 339.141 71.747 –237.149 –6.109 0.353 1000 162.046 435.513 347.950 87.563 –238.404 19.707 –1.030 1100 168.908 451.286 356.617 104.136 –239.283 45.396 –2.157 1200 174.891 466.265 365.155 121.332 –239.827 71.463 –3.110 1300 180.079 480.491 373.513 139.072 –240.120 97.362 –3.912 1400 184.556 493.963 381.596 157.314 –240.203 123.470 –4.607 1500 188.447 506.850 389.533 175.975 –240.120 149.369 –5.202 27. PHENOL C 6H 6O (g) 298.15 103.220 314.810 314.810 0.000 –96.400 –32.630 5.720 300 103.860 315.450 314.810 0.192 –96.490 –32.230 5.610 400 135.790 349.820 319.278 12.217 –100.870 –10.180 1.330 500 161.910 383.040 328.736 27.152 –104.240 12.970 –1.360 600 182.480 414.450 340.430 44.412 –106.810 36.650 –3.190 700 198.840 443.860 353.134 63.508 –108.800 60.750 –4.530 800 212.140 471.310 366.211 84.079 –110.300 85.020 –5.550 900 223.190 496.950 379.327 105.861 –111.370 109.590 –6.360 1000 232.490 520.960 392.302 128.658 –111.990 134.280 –7.010 1100 240.410 543.500 405.033 152.314 –112.280 158.620 –7.530 1200 247.200 564.720 417.468 176.703 –112.390 183.350 –7.980 1300 253.060 584.740 429.568 201.723 –112.330 208.070 –8.360 1400 258.120 603.680 441.331 227.288 –112.120 233.050 –8.700 1500 262.520 621.650 452.767 253.325 –111.780 257.540 –8.970 28. CARBON TETRAFLUORIDE CF 4 (g) 298.15 61.050 261.455 261.455 0.000 –933.200 –888.518 155.663 300 61.284 261.833 261.456 0.113 –933.219 –888.240 154.654 400 72.399 281.057 264.001 6.822 –933.986 –873.120 114.016 500 80.713 298.153 269.155 14.499 –934.372 –857.852 89.618 600 86.783 313.434 275.284 22.890 –934.490 –842.533 73.348 700 91.212 327.162 281.732 31.801 –934.431 –827.210 61.726 800 94.479 339.566 288.199 41.094 –934.261 –811.903 53.011 900 96.929 350.842 294.542 50.670 –934.024 –796.622 46.234 1000 98.798 361.156 300.695 60.460 –933.745 –781.369 40.814 1100 100.250 370.643 306.629 70.416 –933.442 –766.146 36.381 1200 101.396 379.417 312.334 80.500 –933.125 –750.952 32.688 1300 102.314 387.571 317.811 90.687 –932.800 –735.784 29.564 1400 103.059 395.181 323.069 100.957 –932.470 –720.641 26.887 1500 103.671 402.313 328.116 111.295 –932.137 –705.522 24.568 29. TRIFLUOROMETHANE CHF 3 (g) 298.15 51.069 259.675 259.675 0.000 –696.700 –662.237 116.020 300 51.258 259.991 259.676 0.095 –696.735 –662.023 115.267 400 61.148 276.113 261.807 5.722 –698.427 –650.186 84.905 500 69.631 290.700 266.149 12.275 –699.715 –637.969 66.647 600 76.453 304.022 271.368 19.593 –700.634 –625.528 54.456 700 81.868 316.230 276.917 27.519 –701.253 –612.957 45.739 800 86.201 327.455 282.542 35.930 –701.636 –600.315 39.196 900 89.719 337.818 288.116 44.732 –701.832 –587.636 34.105 1000 92.617 347.426 293.572 53.854 –701.879 –574.944 30.032 1100 95.038 356.370 298.879 63.240 –701.805 –562.253 26.699 1200 97.084 364.730 304.022 72.849 –701.629 –549.574 23.922 1300 98.833 372.571 308.997 82.647 –701.368 –536.913 21.573 1400 100.344 379.952 313.804 92.607 –701.033 –524.274 19.561 1500 101.660 386.921 318.449 102.709 –700.635 –511.662 17.817 5-69 TeamLRN
THERMODYNAMIC PROPERTIES AS A FUNCTION OF TEMPERATURE (continued) J/K⋅mol kJ/mol T/K C° p S° -(G°-H° (Tr))/T H°-H° (Tr) ΔfH° ΔfG° Log Kf 30. CHLOROTRIFLUOROMETHANE CClF 3 (g) 298.15 66.886 285.419 285.419 0.000 –707.800 –667.238 116.896 300 67.111 285.834 285.421 0.124 –707.810 –666.986 116.131 400 77.528 306.646 288.187 7.383 –708.153 –653.316 85.313 500 85.013 324.797 293.734 15.532 –708.170 –639.599 66.818 600 90.329 340.794 300.271 24.314 –707.975 –625.901 54.489 700 94.132 355.020 307.096 33.547 –707.654 –612.246 45.686 800 96.899 367.780 313.897 43.106 –707.264 –598.642 39.087 900 98.951 379.317 320.536 52.903 –706.837 –585.090 33.957 1000 100.507 389.827 326.947 62.880 –706.396 –571.586 29.856 1100 101.708 399.465 333.108 72.993 –705.950 –558.126 26.503 1200 102.651 408.357 339.013 83.213 –705.505 –544.707 23.710 1300 103.404 416.604 344.668 93.517 –705.064 –531.326 21.349 1400 104.012 424.290 350.084 103.889 –704.628 –517.977 19.326 1500 104.512 431.484 355.273 114.316 –704.196 –504.660 17.574 31. DICHLORODIFLUOROMETHANE CCl 2F 2 (g) 298.15 72.476 300.903 300.903 0.000 –486.000 –447.030 78.317 300 72.691 301.352 300.905 0.134 –486.002 –446.788 77.792 400 82.408 323.682 303.883 7.919 –485.945 –433.716 56.637 500 89.063 342.833 309.804 16.514 –485.618 –420.692 43.949 600 93.635 359.500 316.729 25.663 –485.136 –407.751 35.497 700 96.832 374.189 323.909 35.196 –484.576 –394.897 29.467 800 99.121 387.276 331.027 44.999 –483.984 –382.126 24.950 900 100.801 399.053 337.942 55.000 –483.388 –369.429 21.441 1000 102.062 409.742 344.596 65.146 –482.800 –356.799 18.637 1100 103.030 419.517 350.969 75.402 –482.226 –344.227 16.346 1200 103.786 428.515 357.061 85.745 –481.667 –331.706 14.439 1300 104.388 436.847 362.882 96.154 –481.121 –319.232 12.827 1400 104.874 444.602 368.445 106.618 –480.588 –306.799 11.447 1500 105.270 451.851 373.767 117.126 –480.065 –294.404 10.252 32. CHLORODIFLUOROMETHANE CHClF 2 (g) 298.15 55.853 280.915 280.915 0.000 –475.000 –443.845 77.759 300 56.039 281.261 280.916 0.104 –475.028 –443.652 77.246 400 65.395 298.701 283.231 6.188 –476.390 –432.978 56.540 500 73.008 314.145 287.898 13.123 –477.398 –422.001 44.086 600 78.940 328.003 293.448 20.733 –478.103 –410.851 35.767 700 83.551 340.533 299.294 28.867 –478.574 –399.603 29.818 800 87.185 351.936 305.172 37.411 –478.870 –388.299 25.353 900 90.100 362.379 310.956 46.280 –479.031 –376.967 21.878 1000 92.475 371.999 316.586 55.413 –479.090 –365.622 19.098 1100 94.433 380.908 322.033 64.761 –479.068 –354.276 16.823 1200 96.066 389.196 327.289 74.289 –478.982 –342.935 14.927 1300 97.438 396.941 332.352 83.966 –478.843 –331.603 13.324 1400 98.601 404.206 337.228 93.769 –478.661 –320.283 11.950 1500 99.593 411.044 341.923 103.681 –478.443 –308.978 10.759 33. METHYLAMINE CH 5N (g) 298.15 50.053 242.881 242.881 0.000 –22.529 32.734 –5.735 300 50.227 243.196 242.893 0.091 –22.614 33.077 –5.759 400 60.171 258.986 244.975 5.604 –26.846 52.294 –6.829 500 70.057 273.486 249.244 12.121 –30.431 72.510 –7.575 600 78.929 287.063 254.431 19.579 –33.364 93.382 –8.129 700 86.711 299.826 260.008 27.873 –35.712 114.702 –8.559 800 93.545 311.865 265.749 36.893 –37.548 136.316 –8.900 5-70
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<strong>THERMODYNAMIC</strong> <strong>PROPERTIES</strong> AS A FUNCTION <strong>OF</strong> TEMPERATURE (continued)<br />
J/K⋅mol kJ/mol<br />
T/K C° p S° -(G°-H° (Tr))/T H°-H° (Tr) ΔfH° ΔfG° Log Kf 26. ACETONE C3H6O (g) (continued)<br />
900 154.097 418.860 339.141 71.747 –237.149 –6.109 0.353<br />
1000 162.046 435.513 347.950 87.563 –238.404 19.707 –1.030<br />
1100 168.908 451.286 356.617 104.136 –239.283 45.396 –2.157<br />
1200 174.891 466.265 365.155 121.332 –239.827 71.463 –3.110<br />
1300 180.079 480.491 373.513 139.072 –240.120 97.362 –3.912<br />
1400 184.556 493.963 381.596 157.314 –240.203 123.470 –4.607<br />
1500 188.447 506.850 389.533 175.975 –240.120 149.369 –5.202<br />
27. PHENOL C 6H 6O (g)<br />
298.15 103.220 314.810 314.810 0.000 –96.400 –32.630 5.720<br />
300 103.860 315.450 314.810 0.192 –96.490 –32.230 5.610<br />
400 135.790 349.820 319.278 12.217 –100.870 –10.180 1.330<br />
500 161.910 383.040 328.736 27.152 –104.240 12.970 –1.360<br />
600 182.480 414.450 340.430 44.412 –106.810 36.650 –3.190<br />
700 198.840 443.860 353.134 63.508 –108.800 60.750 –4.530<br />
800 212.140 471.310 366.211 84.079 –110.300 85.020 –5.550<br />
900 223.190 496.950 379.327 105.861 –111.370 109.590 –6.360<br />
1000 232.490 520.960 392.302 128.658 –111.990 134.280 –7.010<br />
1100 240.410 543.500 405.033 152.314 –112.280 158.620 –7.530<br />
1200 247.200 564.720 417.468 176.703 –112.390 183.350 –7.980<br />
1300 253.060 584.740 429.568 201.723 –112.330 208.070 –8.360<br />
1400 258.120 603.680 441.331 227.288 –112.120 233.050 –8.700<br />
1500 262.520 621.650 452.767 253.325 –111.780 257.540 –8.970<br />
28. CARBON TETRAFLUORIDE CF 4 (g)<br />
298.15 61.050 261.455 261.455 0.000 –933.200 –888.518 155.663<br />
300 61.284 261.833 261.456 0.113 –933.219 –888.240 154.654<br />
400 72.399 281.057 264.001 6.822 –933.986 –873.120 114.016<br />
500 80.713 298.153 269.155 14.499 –934.372 –857.852 89.618<br />
600 86.783 313.434 275.284 22.890 –934.490 –842.533 73.348<br />
700 91.212 327.162 281.732 31.801 –934.431 –827.210 61.726<br />
800 94.479 339.566 288.199 41.094 –934.261 –811.903 53.011<br />
900 96.929 350.842 294.542 50.670 –934.024 –796.622 46.234<br />
1000 98.798 361.156 300.695 60.460 –933.745 –781.369 40.814<br />
1100 100.250 370.643 306.629 70.416 –933.442 –766.146 36.381<br />
1200 101.396 379.417 312.334 80.500 –933.125 –750.952 32.688<br />
1300 102.314 387.571 317.811 90.687 –932.800 –735.784 29.564<br />
1400 103.059 395.181 323.069 100.957 –932.470 –720.641 26.887<br />
1500 103.671 402.313 328.116 111.295 –932.137 –705.522 24.568<br />
29. TRIFLUOROMETHANE CHF 3 (g)<br />
298.15 51.069 259.675 259.675 0.000 –696.700 –662.237 116.020<br />
300 51.258 259.991 259.676 0.095 –696.735 –662.023 115.267<br />
400 61.148 276.113 261.807 5.722 –698.427 –650.186 84.905<br />
500 69.631 290.700 266.149 12.275 –699.715 –637.969 66.647<br />
600 76.453 304.022 271.368 19.593 –700.634 –625.528 54.456<br />
700 81.868 316.230 276.917 27.519 –701.253 –612.957 45.739<br />
800 86.201 327.455 282.542 35.930 –701.636 –600.315 39.196<br />
900 89.719 337.818 288.116 44.732 –701.832 –587.636 34.105<br />
1000 92.617 347.426 293.572 53.854 –701.879 –574.944 30.032<br />
1100 95.038 356.370 298.879 63.240 –701.805 –562.253 26.699<br />
1200 97.084 364.730 304.022 72.849 –701.629 –549.574 23.922<br />
1300 98.833 372.571 308.997 82.647 –701.368 –536.913 21.573<br />
1400 100.344 379.952 313.804 92.607 –701.033 –524.274 19.561<br />
1500 101.660 386.921 318.449 102.709 –700.635 –511.662 17.817<br />
5-69<br />
TeamLRN
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