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Traitement et analyse de séries chronologiques continues de ...

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Annexes<br />

Table 1. Pre-validation param<strong>et</strong>ers for Tests 2, 3 and 5<br />

Test 2 Test 3 Test 5 (median)<br />

WWF DWF WWF DWF<br />

Param<strong>et</strong>ers Min Max Min Max Min Max Min Max Min Max<br />

Conductivity<br />

(µS cm -1 ) 0 2500 10 2000 300 2000 0.01 100 0.01 50<br />

Water level<br />

(m)<br />

pH (pH unit)<br />

0 2 0.05 0.9 0.001 0.2 0.001 0.003 0.001 0.015<br />

0 14 3 12 3 12 10e-6 0.25 10e-6 0.25<br />

Temperature<br />

(° C)<br />

0 100 2 30 2 30 10e-6 0.3 10e-6 0.3<br />

Turbidity<br />

(NTU)<br />

0 4000 5 2000 5 500 0.01 50 0.01 50<br />

Note: WWF =w<strong>et</strong> weather flow; DWF = dry weather flow<br />

Examples of results are given in Figure 2. The data validation graphical user interface is shown in<br />

Figure 2a for a 20 day period in January 2008. Colours indicate the various marks given by the<br />

automatic pre-validation algorithms. Some doubtful and non valid data appear for both the water level<br />

(two abnormal short peaks on 9 and 11 January 2008) and turbidity (incorrect negative values and<br />

constant zeros values appearing in red). In the future, new functions will be ad<strong>de</strong>d to fill gaps in time<br />

series by applying algorithms which are currently un<strong>de</strong>r evaluation for gaps ranging from a few<br />

minutes to periods as long as one day or more.<br />

Figures 2b and 2c shows respectively the Turbidity-TSS (left figure) and Turbidity-COD (right figure)<br />

correlation functions for w<strong>et</strong> weather conditions. Both are second or<strong>de</strong>r polynomial functions<br />

d<strong>et</strong>ermined by means of Williamson regression to account for uncertainties in both variables (turbidity<br />

and TSS or COD). Grey areas correspond to 95 % confi<strong>de</strong>nce intervals in estimated TSS or COD<br />

concentrations. It is important to note that both functions have been established with samples collected<br />

during various storm events covering a large measurement range (respectively 0 - 680 NTU<br />

corresponding to 0 - 1000 mg/L of TSS and 0 - 800 NTU corresponding to 0 - 800 mg/L of COD).<br />

This is important to ensure that the correlation functions are applicable for various conditions and<br />

without undue extrapolation.

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