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Journal of Film Preservation - FIAF

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The Color-Restoration <strong>of</strong> Faded<br />

Color <strong>Film</strong> Prints<br />

Restauration de films en couleurs<br />

La dégradation par effacement progressif de<br />

l’image des films en couleur, étant très<br />

répandue et rapide, est devenue une source<br />

majeure de soucis. Fabricants de pellicule,<br />

exploitants et conservateurs unissent leurs<br />

efforts de recherche pour l’amélioration de la<br />

stabilité des images en couleur. Les<br />

fabricants ont amélioré les procédés<br />

chimiques de tirage et de développement afin<br />

de retarder le processus de dégradation, les<br />

experts en conservation se concentrent sur<br />

les conditions de stockage et de préservation.<br />

Différentes méthodes tendant à corriger la<br />

couleur au moment du copiage ont été mises<br />

au point mais impliquent des procédés aux<br />

technologies complexes et coûteuses. Depuis<br />

les années 70, les auteurs de l’article<br />

développent un ensemble de mesures de<br />

restauration de la couleur. Il s’agit d’un<br />

traitement chimique approprié visant à<br />

atténuer ou intensifier de manière directe et<br />

sélective, les ombres subsistantes dans le but<br />

de restaurer les couleurs et d’en rétablir<br />

l’équilibre original. Les inventeurs de la<br />

méthode espèrent obtenir de bons résultats<br />

de ce procédé qu’ils estiment rapide, bon<br />

marché et fiable.<br />

Xu Jianhe and Ge Xiangbei<br />

The widespread and rapid fading <strong>of</strong> coupled developed color images has<br />

led to grave concern from those involved with the conservation <strong>of</strong><br />

photographic resources. For a long time, experts in the fields <strong>of</strong><br />

manufacturing, production and conservation <strong>of</strong> film have been searching<br />

for an effective means to improve the stability <strong>of</strong> color images. <strong>Film</strong><br />

manufacturers have concentrated on modifying the nature <strong>of</strong> the color<br />

coupling and developing agents in order to reduce the rate <strong>of</strong> color<br />

fading, while film preservation specialists have focused on the<br />

improvements in the storage environment in order to extend the effective<br />

life <strong>of</strong> film resources. Also, a number <strong>of</strong> remedial processes have been<br />

developed to address this problem. In cases <strong>of</strong> moderate fading, color<br />

retiming, or a process for three color separation (with contrast<br />

adjustment made in each <strong>of</strong> the three individual color records) and<br />

recombination has been successfully employed. In the late 1970s, Kodak<br />

developed a duplicate mask technology to restore faded color images.<br />

Nevertheless, all <strong>of</strong> these methods <strong>of</strong> color restoration are based on<br />

complex technology, and are slow and costly. Beginning in the mid-<br />

1970s, we worked out alternate methods for restoring color film.This<br />

method is a chemical treatment which directly and selectively intensifies<br />

the color in faded negative, which allows the restoration <strong>of</strong> original color<br />

balance. This method <strong>of</strong> color restoration had produced good results,<br />

and is characterized by high speed, very low cost, safety and reliability.<br />

1. The Process <strong>of</strong> Color Restoration<br />

The characteristic fading <strong>of</strong> color film that has been stored in darkness is<br />

mainly hydrolytic reductive fading. Reductive decomposition takes place<br />

when the cyan, magenta and yellow colors in the coupling-developed<br />

image are subjected to attack from hydrogen ions (H+), hydoxy ions<br />

(OH- ), acidic sulfite ions (HSO3-) and thiosulfate ion (S2O32-) etc.<br />

Also, a further reaction turns the dyes into leuco-compounds.<br />

The chemical products which are the result <strong>of</strong> the decomposition <strong>of</strong> the<br />

color-coupled dyes remain in the emulsion layer along with the<br />

remaining dyes, if the gelatin base has not degraded and dissolved. This<br />

provides the physical base for the process <strong>of</strong> restoration.<br />

It is understood that during the development process <strong>of</strong> color-coupled<br />

film, the developer is oxidized into quinone-diimine cation, which<br />

combines with a coupler which has been dissociated into an anion, to<br />

form a dye. If we can introduce an oxidation agent which can oxidize<br />

the developer from the decomposition <strong>of</strong> dye into the quinone-diimine<br />

cation, and let the coupler form an anion with the aid <strong>of</strong> the developing<br />

bath, then we have already theoretically accomplished the restoration <strong>of</strong><br />

40 <strong>Journal</strong> <strong>of</strong> <strong>Film</strong> <strong>Preservation</strong> / 58/59 / 1999

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