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Chapitre I.<br />

I.1. Réactifs <strong>et</strong> solvants<br />

L’origine <strong>de</strong>s réactifs <strong>et</strong> <strong>de</strong>s solvants utilisés est présentée dans le tableau suivant <strong>et</strong> il<br />

convient <strong>de</strong> préciser qu’ils sont utilisés sans purification supplémentaire :<br />

Réactifs CAS [Reg. Num.] Pur<strong>et</strong>é Fournisseur<br />

Acétate <strong>de</strong> manganèse [638-38-0] 98% VWR<br />

Acétate <strong>de</strong> sodium [127-09-3] 99% Acros<br />

Aci<strong>de</strong> acétique [64-19-7] 99-100 % Acros<br />

Aci<strong>de</strong> chlorhydrique [7647-01-1] 37% Fisher Labosi<br />

Aci<strong>de</strong> formique [64-18-6] 99-100% VWR<br />

Aci<strong>de</strong> gallique [5995-86-8] 98% Aldrich<br />

Aci<strong>de</strong> glucuronique [6556-12-3] 97+% Fluka<br />

Aci<strong>de</strong> 4-sulfophtalique [89-08-7] 50% Acros<br />

Aci<strong>de</strong> sulfurique [7664-93-9] 95-98 % VWR<br />

Ammoniaque [1336-21-6] 28% VWR<br />

Anhydri<strong>de</strong> acétique [108-24-7] 99% Aldrich<br />

BSTFA [25561-30-2] 98% Alltech<br />

Butanol [71-36-3] 99,5% Acros<br />

Chlorite <strong>de</strong> sodium [7758-19-2] 80% Acros<br />

Chloroforme [67-66-3] 99,95% SDS<br />

Chlorure d’acétyle [75-36-5] 98% Acros<br />

Chlorure d'aluminium [7446-70-0] 99% VWR<br />

Chlorure d'ammonium [12125-02-9] p.a Acros<br />

Chlorure <strong>de</strong> fer [13478-10-9] 98% Alfa Aesar<br />

Chlorure <strong>de</strong> nickel [7791-20-0] 98% Sigma<br />

Chlorure <strong>de</strong> zinc [7646-85-7] 98% Acros<br />

D2O [7789-20-8] 100% SDS<br />

Dioxanne [123-91-1] 100% SDS<br />

DMSO [67-68-5] 99,8% Acros<br />

Ethanol [64-17-5] 99,99% Carlos Erba<br />

Ethylène diamine [107-15-3] 99% Acros<br />

Heptane [142-82-5] 99% Sigma<br />

Hydrogénophosphate <strong>de</strong><br />

potassium<br />

[7778-77-0] 99% Sigma<br />

Hydrogénophosphate <strong>de</strong> sodium [10039-32-4] 98% VWR<br />

HOBt [2592-95-2] 95% Aldrich<br />

Hydroxy<strong>de</strong> <strong>de</strong> potassium [1310-58-3] p.a Acros<br />

Hydroxy<strong>de</strong> <strong>de</strong> sodium [1310-73-2] p.a Acros<br />

Iodure <strong>de</strong> potassium [7681-11-0] 99% Acros<br />

Laccase [80498-15-3] 1,1U/mg Fluka<br />

MeOH [67-56-1] 99,8% Acros<br />

155

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