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DAFS - Universidad de Zaragoza

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Grazing inci<strong>de</strong>nce anomalous diffraction : As K-edge (11867 eV)<br />

GI<strong>DAFS</strong> spectra of the correlation satellites (-1) (BM2-D2AM-ESRF)<br />

Intensity (a.u.)<br />

(440)<br />

Energy<br />

(420)<br />

In-plane reflections<br />

The GI<strong>DAFS</strong> oscillations :<br />

a) As local atomic environment<br />

b) QWrs strain accomodation<br />

c) QWrs composition<br />

- ∆φ=φ T-φ A, |F As |/(f 0As x|F T |) : give S D (E<strong>DAFS</strong> normalisation factor)<br />

and ∆ψ=φ 0-φ A (crystallographic phase shift)<br />

- One assume one equivalent crystallographic site (Zinc-Blen<strong>de</strong>)<br />

24/50

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