DAFS - Universidad de Zaragoza

DAFS - Universidad de Zaragoza DAFS - Universidad de Zaragoza

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X-ray absorption at the As K-edge (EXAFS) P : next nearest neighbors In As/P In : first nearest neighbors contribution II I II Abs. I I Abs. II I χ(k) 0.05 0 -0.05 -0.1 3 5 7 9 11 13 15 k (Å -1 ) k(Å-1 ) résiduel 20/50

As-O As K-edge EXAFS (BM8-ESRF) Intensité Normalisée | FT(k 2 χ(k)) | 0.02 0.01 0 2 1.5 1 0.5 0.026 0.02 0.014 11860 11880 11900 11920 11940 11800 12000 12200 12400 12600 12800 Energie (eV) energy Radial distribution 0 0 1 2 3 4 5 R(Å) R(Å) χ(k) 0.08 0.04 0 -0.04 -0.08 EXAFS -0.12 2 4 6 8 10 12 14 k(Å -1 ) k(Å-1 ) absence of 2 cd shell ! Various As sites, needs of spatial selectivity résiduel 21/50

X-ray absorption at the As K-edge (EXAFS)<br />

P : next nearest neighbors<br />

In As/P In : first nearest neighbors<br />

contribution<br />

II<br />

I<br />

II<br />

Abs.<br />

I<br />

I<br />

Abs.<br />

II<br />

I<br />

χ(k)<br />

0.05<br />

0<br />

-0.05<br />

-0.1<br />

3 5 7 9 11 13 15<br />

k (Å -1 )<br />

k(Å-1 )<br />

résiduel<br />

20/50

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