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Air Quality Criteria for Lead Volume II of II - (NEPIS)(EPA) - US ...

Air Quality Criteria for Lead Volume II of II - (NEPIS)(EPA) - US ...

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lakes in the United Kingdom the distribution <strong>of</strong> sediment-bound trace elements (including Pb)<br />

have been affected by <strong>for</strong>estry activities and catchment erosion (Yang and Rose, 2005). Yang<br />

and Rose (2005) believe that more contaminated soil in-wash could increase sediment heavy<br />

metal concentrations while less contaminated soil in-wash could dilute sediment heavy metal<br />

levels.<br />

Climate Change<br />

Atmospheric Pb is not likely to contribute significantly to global climate change. <strong>Lead</strong><br />

compounds have relatively short residence times in the atmosphere, making it unlikely that they<br />

will reach the stratosphere. Also, Pb compounds are not known to absorb infrared radiation and,<br />

there<strong>for</strong>e, are unlikely to contribute to stratospheric ozone depletion or global warming.<br />

Climate change does, however, represent a disturbance to terrestrial ecosystems.<br />

Un<strong>for</strong>tunately, the potential linkages between climate-related stress and Pb cycling are poorly<br />

understood. As in the previous examples, effects related to alterations in organic matter cycling<br />

may influence Pb migration. For example, an increase in temperature leading to increased rates<br />

<strong>of</strong> organic matter decomposition could lead to temporary increases in DOM concentrations and<br />

smaller steady-state pools <strong>of</strong> soil organic matter. Either <strong>of</strong> these factors could result in increased<br />

concentrations <strong>of</strong> Pb in waters draining terrestrial ecosystems.<br />

Climate change may also affect the fluctuations <strong>of</strong> temperature and/or precipitation in<br />

terrestrial ecosystems. For example, there is some evidence <strong>for</strong> recent increases in the frequency<br />

<strong>of</strong> soil freezing events in the northeastern United States (Mitchell et al., 1996). Soil freezing<br />

occurs when soils have little or no snow cover to insulate them from cold temperatures and<br />

results in an increased release <strong>of</strong> nitrate and DOC from the O horizons <strong>of</strong> <strong>for</strong>est soils (Mitchell<br />

et al., 1996; Fitzhugh et al., 2001). Increased DOC losses from O horizons subjected to freezing<br />

may also increase Pb mobilization.<br />

Increased fluctuations in precipitation may induce more frequent flooding, with<br />

potentially significant consequences <strong>for</strong> Pb contamination <strong>of</strong> floodplain ecosystems. Soils<br />

collected from the floodplain <strong>of</strong> the Elbe River, in Germany, contained elevated concentrations<br />

<strong>of</strong> Pb and other trace metals (Krηger and Grongr<strong>of</strong>t, 2003). Tissues <strong>of</strong> plants from floodplain<br />

sites did not, however, contain higher Pb concentrations than control sites. More frequent<br />

AX7-94

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