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Air Quality Criteria for Lead Volume II of II - (NEPIS)(EPA) - US ...

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Figure AX7-1.1.5. Bulk lead versus single species modality. Shaded area represents<br />

typical soil-lead concentrations found at remediation sites in the<br />

western United States.<br />

Particle-Bound Metal<br />

Direct Approaches<br />

Over the past decade, numerous advances in materials science have led to the<br />

development <strong>of</strong> a wide range in analytical tools <strong>for</strong> the determination <strong>of</strong> metal concentration,<br />

bonding, and valance <strong>of</strong> individual particles on a scale that can be considered useful <strong>for</strong> the<br />

speciation <strong>of</strong> environmentally important materials (i.e., soils, wastes, sediments, and dust).<br />

This review will provide the reader with a brief description <strong>of</strong> these techniques, including their<br />

benefits, limitations (cost, availability, sample preparation, resolution), and usability as well as<br />

references to current applications. Although most <strong>of</strong> these tools are scientifically sound and<br />

<strong>of</strong>fer important in<strong>for</strong>mation on the mechanistic understanding <strong>of</strong> metal occurrence and behavior,<br />

only a few currently provide useful in<strong>for</strong>mation on metal bioavailability at a “site” level.<br />

However, one may still find other techniques essential to a detailed characterization <strong>of</strong> a selected<br />

AX7-12

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