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Environmental Health Criteria 214

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HUMAN EXPOSURE ASSESSMENT<br />

field would underestimate the amount of total dust collected when<br />

final weights are obtained, which would in turn overestimate the<br />

calculated mass concentration results. Because of water loss or gain,<br />

changes in humidity may also significantly affect the before and after<br />

weights of the samples. These potential sources of error must be<br />

carefully controlled to make the results from preweighed wipe methods<br />

reliable.<br />

A specially designed preweighed wipe sampling method has been<br />

developed to minimize the potential sources of error mentioned above.<br />

This method, known as the Lioy-Weisel-Wainman (LWW) method, was<br />

developed to quantitatively measure the toxicant concentration (mg/g)<br />

and surface loading (mg/m 2 ) of dust on flat surfaces (Lioy et al.,<br />

1993). The sampling device is not made from common materials and is at<br />

this time only available from the research group that developed it.<br />

8.2.2.2 Vacuum methods<br />

Many researchers have collected samples from commercial household<br />

vacuum cleaners, which are often referred to in the refereed<br />

literature as research dust samplers. Some researchers state that they<br />

sampled only the fine dust that settled to the bottom of the bag.<br />

(Kaye et al., 1987; Moffat, 1989; Davies et al., 1990; Thornton et<br />

al., 1990; Jensen, 1992). Other researchers modified their vacuum<br />

cleaners to hold filters (Diemel et al., 1981; Watt et al., 1983).<br />

A settled dust vacuum method, commonly called the DVM, is<br />

constructed from conventional industrial hygiene sampling materials<br />

that are likely to be available to researchers worldwide (Que Hee et<br />

al., 1985). The sampler consists of a common personal air-monitoring<br />

pump, usually operated at 2.5-3.0 litres/min. Sampling areas with this<br />

method are typically 25 cm × 25 cm, and often take more than 5 min to<br />

sample completely. A three-sided template is sometimes used on bare<br />

floors to vacuum dust that has migrated to the walls. Sampling areas<br />

are covered three times with overlapping passes in the horizontal and<br />

vertical directions. Que Hee et al. (1985) state that the sampler was<br />

designed to collect only small dust particles that would most likely<br />

stick to a child's hands, not total lead on a surface. Therefore, the<br />

amount of dust collected by this method from a given surface is<br />

usually less than collected by other methods. This sampler has been<br />

used in numerous studies in the USA and elsewhere, and its use has<br />

provided considerable information linking lead in settled dust to lead<br />

in children (e.g., Bornschein et al., 1985).<br />

Researchers have also used laboratory rotary vane vacuum pumps<br />

connected to the same three-piece filter cassettes as used with the<br />

DVM described above, but with a much higher flow rate. The filter<br />

cassette is often used openface or with a wide diameter nozzle so<br />

sampling areas can be covered in fewer passes than required for the<br />

DVM, thus reducing the time spent collecting samples (Solomon &<br />

Hartford, 1976).<br />

Prpic-Majic et al. (1992) described another vacuum pump sampling<br />

method that used a prescreen at its nozzle entrance to prevent coarse<br />

particles and small objects from being collected on the membrane<br />

filter that served as the sampling surface. Total dust measurement was<br />

obtained from the dust particles that reached the membrane filter.<br />

There was no mention of potential loss of fine dust trapped in the<br />

prescreen, especially after it was loaded with fibres and debris.<br />

http://www.inchem.org/documents/ehc/ehc/ehc<strong>214</strong>.htm<br />

Page 141 of 284<br />

6/1/2007

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