Abstracts with Programs - Geological Society of America
Abstracts with Programs - Geological Society of America
Abstracts with Programs - Geological Society of America
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32-3 16:50 Manning, Andrew H.<br />
POTENTIAL EFFECTS OF CLIMATE CHANGE ON WATER QUALITY IN MINERALIZED<br />
WATERSHEDS<br />
MANNING, Andrew H. 1 , TODD, Andrew S. 2 , and VERPLANCK, Philip L. 1 , (1) U.S.<br />
<strong>Geological</strong> Survey, P.O. Box 25046, Mail Stop 973, Denver, CO 80225-0046, amanning@<br />
usgs.gov, (2) U.S. <strong>Geological</strong> Survey, P.O. Box 25046, Mail Stop 964, Denver, CO 80225<br />
A unique long-term water chemistry dataset has been compiled for Upper Snake Creek, a<br />
stream draining a mineralized alpine watershed in the Front Range <strong>of</strong> Colorado, USA. Trace<br />
metal (mainly zinc) and sulfate concentrations in stream water at baseflow have increased by<br />
a factor <strong>of</strong> two to three over the past three decades. Although small mines are located in the<br />
watershed, they are abandoned and no mining or mine-remediation activities have occurred<br />
during this period. A similar increase in sulfate concentration has been observed in another<br />
part <strong>of</strong> the Colorado Rockies in lakes <strong>with</strong>in mineralized watersheds also free <strong>of</strong> recent mining<br />
activity. These trends are concerning because mineralized watersheds are common throughout<br />
the mountains <strong>of</strong> the western US, and further water quality degradation could negatively impact<br />
downstream drinking water resources and aquatic ecosystems. Climate change is a potential<br />
cause, but specific links between climate and the natural production <strong>of</strong> low-pH, metal-rich<br />
ground and surface water (acid-rock drainage) in mineralized watersheds is poorly understood.<br />
In this study, we employ the code TOUGHREACT to perform schematic numerical flow and<br />
reactive transport simulations to evaluate the relative importance <strong>of</strong> different climatic and<br />
hydrologic variables in the oxidation <strong>of</strong> sulfides in the subsurface in unmined settings. Inverse<br />
modeling techniques are used to quantify the sensitivity <strong>of</strong> acid-rock drainage production rates<br />
to various parameters. Preliminary results suggest that water-table depth, recharge rate, and<br />
the magnitude <strong>of</strong> seasonal water-table fluctuations are <strong>of</strong> primary importance. Climate change<br />
scenarios involving increasing temperature and decreasing snowpack, as predicted for much<br />
<strong>of</strong> the western US, may thus portend further water quality degradation in many mineralized<br />
watersheds due to decreasing groundwater recharge and falling water tables.<br />
32-4 17:10 Knappett, Peter S.K.<br />
TRANSPORT OF FECAL BACTERIA FROM PONDS TO AQUIFERS IN RURAL<br />
BANGLADESH: THE ROLE OF ADJACENT SEDIMENT GRAIN SIZE<br />
KNAPPETT, Peter S.K., Institute for Groundwater Ecology, Helmholtz Center for<br />
Environmental Health, Ingolstaedter Landstr. 1, Neuherberg, 85764, Germany, peter.<br />
knappett@helmholtz-muenchen.de, MCKAY, Larry, Department <strong>of</strong> Earth and Planetary<br />
Sciences, The University <strong>of</strong> Tennessee, 1412 Circle Drive, Knoxville, TN 37996-1410,<br />
LAYTON, Alice C., Center for Environmental Biotechnology, University <strong>of</strong> Tennessee,<br />
Knoxville, TN 37996, WILLIAMS, Daniel E., Center for Environmental Biotechnology,<br />
University <strong>of</strong> Tennessee, 676 Dabeny-Beuhler Hall, 1416 Circle Dr, Knoxville, TN<br />
37931, AHMED, K.M., Department <strong>of</strong> Geology, University <strong>of</strong> Dhaka, Ramna, Dhaka,<br />
1000, Bangladesh, CULLIGAN, Patricia J., Civil Engineering & Engineering Mechanics,<br />
Columbia University, Room 626, 500 W. 120th Street, New York, NY 10027, MAILLOUX,<br />
Brian, Environmental Sciences, Barnard College, 3009 Broadway, 404 Altschul, New<br />
York, NC 10027, EMCH, Michael, Department <strong>of</strong> Geography, University <strong>of</strong> North Carolina<br />
at Chapel Hill, Saunders 308, Chapel Hill, NC 27599, SERRE, Marc L., Department <strong>of</strong><br />
Environmental Sciences and Engineering, University <strong>of</strong> North Carolina at Chapel Hill,<br />
Chapel Hill, NC 27599-3220, and VAN GEEN, A., Lamont-Doherty Earth Observatory <strong>of</strong><br />
Columbia Univ, 61 Rte. 9W, Palisades, NY 10964<br />
Widespread fecal contamination observed in shallow aquifers in Bangladesh is suspected to<br />
contribute to high rates <strong>of</strong> diarrheal disease. In Bangladesh and other developing countries,<br />
ponds that receive untreated latrine effluent represent potential point sources <strong>of</strong> fecal<br />
contamination to drinking water wells emplaced <strong>with</strong>in shallow aquifers. This may be especially<br />
important during the monsoon when ponds tend to rapidly fill <strong>with</strong> contaminated run<strong>of</strong>f water<br />
and then drain into the ground. To test the hypotheses that ponds are sources <strong>of</strong> fecal bacteria<br />
to groundwater, nine transects <strong>of</strong> monitoring wells radiating away from four ponds were<br />
installed in a shallow sandy aquifer underlying a village in rural Bangladesh. Sediment coring<br />
revealed that two <strong>of</strong> these ponds were emplaced <strong>with</strong>in fine-grained sand, one was in fine,<br />
silty sand and one was in silt. Eight <strong>of</strong> the nine transects were sampled monthly for cultured<br />
E. coli from September 2008 through October 2009. E. coli was detected only at very low<br />
concentrations (800 MPN/100 mL) and molecular E.<br />
coli and Bacteroidales (>100,000 copies/100 mL) were found in monitoring wells in the aquifer<br />
adjacent to the two ponds emplaced <strong>with</strong>in clean sand. In June <strong>of</strong> 2009, water levels in all four<br />
ponds were artificially raised by 16 to 63 cm to simulate early monsoon flooding conditions<br />
and fecal indicator bacteria (FIB) were monitored at least once a week in four transects, one<br />
adjacent to each pond. Increases in FIB concentrations up to 7 meters away from two ponds<br />
were accompanied by increases in lateral hydraulic gradient. This only occurred adjacent to<br />
ponds emplaced <strong>with</strong>in clean sand, whereas FIB concentrations were very low or not-detected<br />
next to ponds emplaced <strong>with</strong>in silty sand or silt. Thus, whether ponds are point sources <strong>of</strong> fecal<br />
contamination depends sensitively on the grain size <strong>of</strong> sediments immediately adjacent to<br />
the ponds.<br />
32-5 17:25 Kipry, Judith<br />
BACTERIALLY INDUCED FERRIC MINERAL PRECIPITATION IN ACID MINE WATERS<br />
KIPRY, Judith1 , GÖTZ, Andreas2 , WIACEK, Claudia1 , SCHMAHL, Wolfgang2 , and<br />
SCHLÖMANN, Michael1 , (1) TU Bergakademie Freiberg, Institute <strong>of</strong> Bioscience,<br />
Environmental Microbiology, Leipziger Straße 29, Freiberg, 09599, Germany, judith.kipry@<br />
ioez.tu-freiberg.de, (2) LMU München, Department <strong>of</strong> Earth and Environmental Sciences,<br />
Section <strong>of</strong> Applied Crystallography and Material Science, Theresienstraße 41/II, München,<br />
80333, Germany<br />
Ferric minerals are typically found in acid mine waters. These waters are characterized by low<br />
pH and high concentration <strong>of</strong> heavy metals e.g. iron. Acidophilic bacteria play an important role<br />
during mineral precipitation since chemical iron oxidation is negligible under acidic conditions.<br />
In addition to the supply <strong>of</strong> ferric ions for mineral precipitation iron oxidizing bacteria might<br />
function actively in mineral precipitation.<br />
We investigated two different species <strong>of</strong> iron oxidizing bacteria: first the acidophilic iron<br />
oxidizer Leptospirillum ferrooxidans, and second the moderately acidophilic iron oxidizer<br />
Thiomonas sp. and we analyzed their role during ferric mineral precipitation in acid mine<br />
waters. Both species differ in their way <strong>of</strong> iron oxidation and mineral precipitation. The analyses<br />
<strong>of</strong> chemical parameters during cultivation experiments <strong>of</strong> acidophilic and moderately acidophilic<br />
iron oxidizing bacteria suggested that iron oxidation and mineral formation occurred nearly<br />
simultaneously in Leptospirillum ferrooxidans and consecutively in Thiomonas sp.. Electron<br />
microscopic investigations revealed no direct interactions between Leptospirillum ferrooxidans<br />
cells and the precipitated mineral, whereas a partial incrustation <strong>of</strong> Thiomonas sp. cells could<br />
be observed. XRD indicated that goethite and lepidocrocite were produced in presence <strong>of</strong><br />
Thiomonas sp.. The precipitated mineral in experiments <strong>with</strong> Leptospirillum ferrooxidans was<br />
mainly composed <strong>of</strong> schwertmannite, a secondary metastable iron(III)-oxyhydroxysulfate <strong>with</strong><br />
a hedgehog like structure. Schwertmannite hedgehogs were <strong>of</strong>ten found in environmental<br />
samples. So far we suggested that the hedgehogs are incrusted bacteria cells. The present<br />
data demonstrate that the hedgehog like structure is the result <strong>of</strong> the oxidation rate and<br />
consequently <strong>of</strong> the supply <strong>of</strong> ferric ion and independent from the presence <strong>of</strong> bacterial cells.<br />
SESSION NO. 33<br />
SESSION NO. 33, 14:00<br />
Tuesday, 6 September 2011<br />
T3B. The Challenge <strong>of</strong> Understanding Continental<br />
Intraplate Earthquakes<br />
Ludwig-Maximilians-Universität München, A 016<br />
33-1 14:00 Nasir, Asma<br />
HOW COMPLETE ARE HISTORICAL EARTHQUAKE RECORDS IN CENTRAL EUROPE?<br />
NASIR, Asma1 , LENHARDT, Wolfgang A. 2 , HINTERSBERGER, Esther1 , and DECKER,<br />
Kurt3 , (1) Department <strong>of</strong> Geodynamics and Sedimentology, University <strong>of</strong> Vienna,<br />
Althanstrasse 14, Vienna, 1090, Austria, asma.nasir@univie.ac.at, (2) Geophysics, ZAMG,<br />
Hohe Warte 38, Vienna, 1190, Austria, (3) Center for Earth Sciences, University <strong>of</strong> Vienna,<br />
Althanstrasse 14, Vienna, 1090, Austria<br />
In Central Europe, a long settlement history provides the advantage <strong>of</strong> a long record <strong>of</strong><br />
historical seismic catalogues in a region characterized by low to medium seismicity. However,<br />
uncertainties <strong>with</strong> respect to intensity, reliability, homogeneity, and location accuracy provide<br />
a major challenge to prepare those catalogues for usage in seismic hazard assessment.<br />
Especially the incompleteness <strong>of</strong> historical records affects the determination <strong>of</strong> a and b<br />
parameters <strong>of</strong> Gutenberg-Richter (GR) relation which are crucial elements for earthquake<br />
recurrence interval estimations.<br />
Mainly two different approaches have been proposed for checking completeness <strong>of</strong> seismic<br />
catalogues: Temporal course <strong>of</strong> earthquake frequency (TCEF), generally used in Europe, and<br />
the completeness method proposed by Stepp (1972), based on statistical analysis <strong>of</strong> mean<br />
earthquake recurrence interval for varying time windows. We compared systematically the<br />
effects <strong>of</strong> those different methods on the GR relation, as well as the influence <strong>of</strong> removing foreand<br />
aftershocks.<br />
For this purpose, we created a new composite catalogue for Austria and the Vienna Basin,<br />
based on four different earthquake catalogues <strong>of</strong> different record length. The new composite<br />
catalogue includes data from surrounding regions such as the Vienna Basin outside Austria<br />
and a buffer region 100km outside the boundary <strong>of</strong> the Austria and Vienna basin. The<br />
composite catalogue covers data between 1048 - 2009AD. This newly compiled composite<br />
catalogue has been declustered manually using magnitude-dependent space and time<br />
windows.<br />
The derived a and b-parameters depend strongly on the completeness method we used.<br />
To avoid the ambiguities related to different local intensity magnitude conversions, the<br />
completeness checks are made for intensity. Stepp method seems to be more reliable because<br />
it does not include the highest intensity (I = X), because the observation period is too short for<br />
constraining a stable recurrence interval. On the other hand TCEF includes higher intensity<br />
classes for estimation <strong>of</strong> a and b-parameters <strong>of</strong> GR relation. Both completeness methods<br />
have been applied also on Vienna Basin source zone, a subset <strong>of</strong> the composite catalogue.<br />
Comparison shows that completeness <strong>of</strong> the entire dataset is apparently overestimated,<br />
especially for smaller intensities.<br />
33-2 14:15 Hintersberger, Esther<br />
AN UPDATED APPROACH FOR ESTIMATING PALEO-EARTHQUAKE MAGNITUDES FROM<br />
MULTIPLE TRENCH OBSERVATIONS<br />
HINTERSBERGER, Esther, Department <strong>of</strong> Geodynamics and Sedimentology, University<br />
<strong>of</strong> Vienna, Althanstrasse 14, Vienna, 1090, Austria, esther.hintersberger@univie.ac.at<br />
and DECKER, Kurt, Center for Earth Sciences, University <strong>of</strong> Vienna, Althanstrasse 14,<br />
Vienna, 1090, Austria<br />
One <strong>of</strong> the major contributions <strong>of</strong> paleoseismology to seismic hazard assessment are<br />
paleoearthquake magnitudes. Especially in regions <strong>with</strong> low or moderate seismicity,<br />
paleomagnitudes are normally much larger than those <strong>of</strong> historical earthquakes. Biasi &<br />
Weldon (2006) proposed a probabilistic magnitude estimate given one observed displacement,<br />
taking into account the natural variability <strong>of</strong> surface displacement along a fault. However, in<br />
case <strong>of</strong> more observation points (i.e. trench sites) per fault, single-event displacements at<br />
different locations can be correlated and result in a larger set <strong>of</strong> observed displacements for<br />
each earthquake. This can be used to narrow down the possible magnitude range associated<br />
<strong>with</strong> the generating earthquake. Extrapolating the approach <strong>of</strong> Biasi and Weldon (2006),<br />
the single-observation probability density functions (PDF) are assumed to be independent<br />
<strong>of</strong> each other, since observations <strong>of</strong> each trench do not depend on the findings <strong>of</strong> other<br />
trenches. Following this line, the common PDF for all observed displacements generated<br />
by one earthquake is the product <strong>of</strong> all single-displacement PDFs. In order to test this idea<br />
to practicability, we used the results <strong>of</strong> a paleoseismological investigation <strong>with</strong>in the Vienna<br />
Pull-Apart Basin (Austria), where 3 trenches were opened along the normal Markgrafneusiedl<br />
Fault (MGNSF). Even if the Vienna Basin is characterized by low to medium seismicity (Mmax<br />
= 5.3/Imax = 8), there is no historical seismicity recorded along the MGNSF. However, our<br />
studies provide evidence for at least 5 major earthquakes <strong>with</strong> M > 6.0 along the MGNSF<br />
during the last ~ 100 ka. Using events that are observed <strong>with</strong>in all 3 trench sites, we derived<br />
common magnitude PDFs for each set <strong>of</strong> observed displacements related to a single event.<br />
As expected, the final magnitude PDFs are narrower than those <strong>of</strong> the single-event magnitude<br />
PDFs. In addition, they are dominated by the largest observed displacement, especially <strong>with</strong><br />
respect to the lowest magnitude that could have generated all observed displacements. In total,<br />
this approach seems to be a suitable method to combine observations from different locations<br />
to one magnitude value accounting for the natural variances <strong>of</strong> observed along-strike surface<br />
displacement. Reference: Biasi & Weldon (2006), BSSA 96, pp. 1612-1623.<br />
33-3 14:30 Berberich, Gabriele<br />
GEOBIOSCIENCE: RED WOOD ANT MOUNDS AS BIOLOGICAL INDICATORS FOR<br />
NEOTECTONIC EARTHQUAKE-BEARING FAULT SYSTEMS<br />
BERBERICH, Gabriele, Department <strong>of</strong> Geology, University <strong>of</strong> Duisburg-Essen,<br />
Universitaetsstr. 5, Essen, 45141, Germany, gabriele.berberich@uni-due.de and<br />
SCHREIBER, Ulrich, Faculty <strong>of</strong> Biology, <strong>Geological</strong> Section, University <strong>of</strong> Duisburg-Essen,<br />
Universitätsstraße 5, Essen, 45141, Germany<br />
The volcanic West Eifel (Germany) is part <strong>of</strong> the Variscan folded Rhenoherzynikum that was<br />
tectonically sheared in Mesozoic and Cenozoic times according to multiple changes <strong>of</strong> principal<br />
stress directions. The current stress field <strong>with</strong> a NW-SE-trending main stress direction opens<br />
pathways for geogenic gases. At the same time, Variscan faults that are part <strong>of</strong> a conjugated<br />
shear system, are reactivated. In the 1990s, equidistant neotectonic W-E-trending strike-slip<br />
fault systems were identified in coalmines <strong>of</strong> the Ruhr Carboniferous. The question was if<br />
it is possible to identify these fault systems also in areas <strong>with</strong>out any mines or outcrops by<br />
bioindicators as red wood ants (RWA, genus Formica).<br />
RWA have a strong affinity for gas-permeable earthquake-bearing neotectonic fault systems.<br />
There are first indications, that geogenic gases ascending from faults play a decisive role.<br />
Munich, Germany A47<br />
Tuesday