SESSION NO. 31 the case <strong>of</strong> minerals containing the calcium ion, like gypsum or calcite, their dissolution rate is also crucial in the investigation <strong>of</strong> the geological storage <strong>of</strong> CO 2 . In standard dissolution experiments (batch, rotating disk, …), the mineral is dissolving in stirred water. So the dissolution kinetics is mixed <strong>with</strong> diffusive and convective contributions. For hard minerals, dissolution is so slow that it drives the whole kinetics. But for s<strong>of</strong>ter minerals, dissolution, diffusion and convection timescales are <strong>of</strong> the same order <strong>of</strong> magnitude and their respective contributions can be difficult to disciminate. As an example, we have collected dissolution rates <strong>of</strong> gypsum in water measured by various methods found in the literature. The deduced dissolution rate constants span over several decades. Therefore we have analysed the hydrodynamics <strong>of</strong> the experimental setups, eliminated the diffusive and convective contributions and deduced from them the pure surface reaction rate constant <strong>of</strong> gypsum in water. It appears to be much smaller than expected from the literature results. An holographic interferometry experiment, performed in still water, is carried out and enables to measure directly this rate constant. Both values agree <strong>with</strong>in experimental uncertainty, which confirms the unexpected small value <strong>of</strong> the dissolution rate constant <strong>of</strong> gypsum, and give clues to understand the discrepancy between the reported values <strong>of</strong> calcite dissolution rate. 31-2 BTH 8 Maldini, Faldo OBLIGATORY TECHNOLOGY TRANSFER TO MAXIMIZE THE USING OF ENERGY RESOURCES IN DEVELOPMENT COUNTRY. STUDY CASE: GEOTHERMAL IN INDONESIA MALDINI, Faldo, University <strong>of</strong> Indonesia, Depok 12620 Indonesia, faldo.maldini@gmail.com Today the world faces a serious problem about energy. Energy that usually created from fossil like oil is decreased day by day. It also gives impact to the environment because <strong>of</strong> the emission. Many countries agree that they will make green energy system that will be used in each country. It is also happened in Indonesia. From now, the world needs a renewable energy that also clean and friendly for the environment. Indonesia has abundant natural resources. One <strong>of</strong> renewable energy that Indonesia has is geothermal energy. Indonesia has 40% resource if we compare it <strong>with</strong> the other country resource around the world. It is equal to 27500 Mwe for electricity power. Geothermal also become friendly to the environment because the emission is small. Now, Indonesia’s Government has vision “25/25” for geothermal energy. It means that the energy mix for Indonesia for the year 2025 is 25%. In fact, the geothermal still use for 3% for today. Then, the use <strong>of</strong> geothermal energy system is still not independently builds from Indonesia. Indonesia still joins the other company from abroad to produce geothermal energy. There is potential problem that will be happened because the bad system <strong>of</strong> geothermal management. We should learn from oil management. Indonesian has gotten from this natural resources is very limited. Now, the production <strong>of</strong> geothermal is on the move. We see that the companies from abroad are still take part to produce geothermal energy system <strong>with</strong> Indonesia’s company, PT Pertamina Geothermal Energy. We can classify the threats which are coming from the existence condition in two categories: (1) the problems that rise from the imperfectness policy; (2) The problems that rise from system technically used: engineering, processing, and producing the geothermal energy today and for the future. . To prevent and deal <strong>with</strong> the problems, there are three classifications <strong>of</strong> solutions that should be done: (1) The application <strong>of</strong> transfer technology <strong>with</strong> four types that will be clearly inform in the fourth chapter <strong>of</strong> this paper; (2) Improvement the education quality and capability to use technology that support Indonesia’s student; (3) The support and believe from the government <strong>with</strong> this country capability. 31-3 BTH 9 Obst, Karsten POTENTIAL ECONOMIC USE OF MIDDLE BUNTSANDSTEIN SALINE AQUIFERS IN MECKLENBURG-WESTERN POMERANIA (NE GERMANY) OBST, Karsten and BRANDES, Juliane, Geologischer Dienst, LUNG M-V, Goldberger Str. 12, Güstrow, D-18273, Germany, karsten.obst@lung.mv-regierung.de Clastic sediments <strong>of</strong> the Middle Buntsandstein are widely distributed in the eastern part <strong>of</strong> the North German Basin. Several sandstone horizons are intercalated <strong>with</strong> silt- and claystones. They form a multi-layered system <strong>of</strong> saline aquifers (Detfurth formation to Solling formation). The potential <strong>of</strong> these aquifers for geothermal heat production and geological storage <strong>of</strong> natural gas or carbon dioxide varies regionally. The sandstones <strong>of</strong> the Middle Buntsandstein are fine- to medium-grained <strong>with</strong> clay content higher than 10 % in average. They show good reservoir properties at the north-eastern margin <strong>of</strong> the basin, e.g. porosities between 15-30 % and mean permeabilities <strong>of</strong> about 500 mD. Towards the central basin areas in the SW, the porosities <strong>of</strong> the sandstones are reduced either due to higher silt and clay content or by secondary cementation <strong>of</strong> the pore space. Changing facies conditions and burial effects led to rather low permeabilities
them an erosive deposition <strong>of</strong> mesozoic shales and sandstones alternancy <strong>of</strong> 8 kilometers in extention; tertiary and quaternary sedimentary prism are almost 10 Km in thickness. The age <strong>of</strong> uplift <strong>of</strong> the ridge is eocene andine orogeny, the mechanism is astenospheric domming in the Guyana Craton NW border. In a former fieldtrip the author caracterized the oil productive basin <strong>of</strong> Middle Magdalena Basin, in Bolivar State, Cantagallo Town, recently destroyed by floods in Magdalena river basin. The camp in a known oil reservoir since the 1920´s decade by Texas Oil Co. An study on the soil sand horizon composition shown an important presence in gold mineral (Sylvanite, an AuAgTe4 mineral probably oxidized) and Platinum, in a mixture <strong>with</strong> Quartz and K-Ba Rich Muscovite. Those minerals where evaluated in powder in the d X-Ray difractometer. In the evaluation <strong>of</strong> the material the metallic brigthness were the most important clue for identification. In the X-Ray Diphractometry analysis the material were compared <strong>with</strong> other minerals pattern like mica, oxides, carbonates and some other, but the dimensions <strong>of</strong> the chrystalline cell match <strong>with</strong> platinum pattern and sylvanite one time the quartz signal were eliminated in the background filter and the mean mica K-Ba Muscovite were identified. The dimensions measured <strong>of</strong> the chrystaline shell <strong>of</strong> Platinum, Pt in A (Armstrongs) are 2.28034 A; 1.97123 A; 1.39476 A (until 1.37113 A). 31-8 BTH 14 Lutz, Rüdiger PETROLEUM SYSTEMS MODELING IN THE GERMAN NORTH SEA LUTZ, Rüdiger1 , KURKOW, Alexej1 , BERNER, Ulrich2 , and FRANKE, Dieter1 , (1) Bundesanstalt für Geowissenschaften und Rohst<strong>of</strong>fe (BGR), Hannover, 30655, Germany, Ruediger.Lutz@bgr.de, (2) Geochemistry <strong>of</strong> Petroleum and Coal, Federal Inst. for Geosciences and Natural Ressources, Stilleweg 2, Hannover, D-30655, Germany Germanys North Sea sector (German Exclusive Economic Zone EEZ) covers an area <strong>of</strong> around 35,000 km2 . Despite about 80 exploration wells which were drilled since 1964 oil and gas is produced from only two fields: The Mittelplate oil field in the Wadden Sea and the gas field A6/B4 in the northwestern part <strong>of</strong> the German Exclusive Economic Zone (EEZ) at the Danish Border, respectively. At BGR we are currently mapping the northwestern area, the so-called “Entenschnabel”. Once finished it will be included in the 3D model <strong>of</strong> the central German North Sea forming one homogenous geological model <strong>of</strong> the German EEZ. This model serves as a structural input for various 1D, 2D and 3D petroleum system models, which investigate the evolution <strong>of</strong> the German North Sea and the key petroleum system elements. We will present the present status <strong>of</strong> the project including 1D models and 2D models <strong>of</strong> the central German North Sea.The final 3D model will be publically available and can be used by industry and academia for investigations <strong>of</strong> e.g. license areas supplemented by proprietary data or tests <strong>of</strong> new kinetic data sets in a geological model. This work is carried out <strong>with</strong>in the framework <strong>of</strong> the GPDN project (Geopotenzial Deutsche Nordsee), a joint project <strong>of</strong> the Federal Institute for Geosciences and Natural Resources (BGR), the State Authority for Mining, Energy and Geology (Lower Saxony, LBEG) and the Federal Maritime and Hydrographic Agency <strong>of</strong> Germany (BSH) together <strong>with</strong> industry and academic partners. 31-9 BTH 15 Gast, Sascha GROUNDWATER PROTECTION IN THE NORTH GERMAN BASIN FROM THE OTHER SIDE OF VIEW - THE RUPELIAN CLAY FORMATION AS THE UNDERLAYING SEAL GAST, Sascha, WIRTH, Holger, FISCHER, Marina, and KUHLMANN, Gesa, Federal Institute for Geosciences and Natural Resources, Branch <strong>of</strong>fice Berlin, Wilhelmstr. 25-30, Berlin, 13593, Germany, sascha.gast@bgr.de In northern Germany, the Palaeogene clay formation is the most important geological seal horizon between the under laying saltwater aquifers and the overlaying occupied ground-water aquifers. In context <strong>of</strong> utilisation <strong>of</strong> the deeper underground, the expanse <strong>of</strong> the Rupelian clay formation is described and the reprocessed isobath map <strong>of</strong> the “Base Rupelian as effective seal” is displayed. Exemplarily the correlation between the distribution <strong>of</strong> the clay formations and the Groundwater salinisation will be shown. The influence <strong>of</strong> salt tectonics and Quaternary erosion on the distribution and thickness <strong>of</strong> the Rupelian is discussed and revised. 31-10 BTH 16 Gast, Sascha MINERALOGICAL INVESTIGATIONS ON LOWER TRIASSIC CLASTIC SEDIMENTS. OUTCROP STUDIES AS A TOOL TO REFINE THE SEAL CHARACTERISTICS GAST, Sascha1 , KUHLMANN, Gesa1 , SCHMIDT, Michael2 , and PÖLLMANN, Herbert2 , (1) Federal Institute for Geosciences and Natural Resources, Branch <strong>of</strong>fice Berlin, Wilhelmstr. 25-30, Berlin, 13593, Germany, sascha.gast@bgr.de, (2) Martin-Luther- University Halle-Wittenberg, Institute <strong>of</strong> Geosciences, Von Seckendorff-Platz 3, Halle, 06124, Germany The uppermost part <strong>of</strong> the lower Triassic „Buntsandstein“ is termed Röt–Folge. The Karsdorf- Quarry located in north-eastern Germany is the type-section <strong>of</strong> the Karsdorf-subformation <strong>with</strong>in the Röt interval. Since the Röt-Folge can be regarded as a potential seal-formation in CCS technology, we aim to refine the knowledge <strong>of</strong> the Röt lithology and its petrophysical properties. Therefore sediments taken 9 samples from the Karsdorf Quarry have been investigated for their mineralogy, grain size distribution as well as their petrophysical parameters. The finely grained clastic sediments are mostly reddish to brownish in colour. The majority <strong>of</strong> the 40 m thick succession is thin bedded and in the lower part <strong>of</strong> the Quarry the beds are irregular cut by gypsum layers. The so called “Doppelquarzit” bed as the most significant bed has been used to reconstruct the stratigraphic position <strong>of</strong> the whole succession and the two prominent calcareous sandstone-beds therein are the coarsest beds in the section. To investigate the interaction between potential seal-rocks and a CO2-rich fluid, the selected rocks will be altered under simulated “in-situ” conditions in a laboratory autoclave system. For these experiments synthetic formation brine has been used. Due to the high temperature in the autoclave CO will be in supercritical state throughout the experiment. The fluids and rock 2 samples remain in the autoclave system for about two weeks and are investigated thereafter for possible changes due to the exposure to CO and brine. 2 Here we show first results on rock behaviour from the analyses <strong>of</strong> the mostly clayey and siltey sediments together <strong>with</strong> the results on (clay) mineralogy, XRF analyses as well as grain size analysis that has been used to determine the petrophysical parameters besides direct measurements before and after treatment. Initial porosities range between 0.94 and 15.01 % . <strong>with</strong> a carbonate content between 1.8 and 41.3 % by weight. 31-11 BTH 17 Pletsch, Thomas FLUID ENTRAPMENT AND RELEASE FROM SEDIMENTS INTRUDED BY VOLCANIC SILLS, NEWFOUNDLAND MARGIN PLETSCH, Thomas1 , KUS, Jolanta1 , PETSCHICK, Rainer2 , and CRAMER, Bernhard1 , (1) Federal Institute for Geosciences and Natural Resources (BGR), Stilleweg 2, Hannover, 30655, Germany, thomas.pletsch@bgr.de, (2) Institute <strong>of</strong> Geoscience, Goethe- Universität Frankfurt, Altenhöferallee 1, Frankfurt am Main, 60438, Germany Ocean Drilling Program Hole 1276A, at the toe <strong>of</strong> the SE facing Newfoundland Margin, provided access to more than 600 m <strong>of</strong> mid-Cretaceous, deep-marine, organic-rich mudstones <strong>with</strong> two intercalated volcanic sills near the base <strong>of</strong> the hole. A 10 m basaltic SESSION NO. 31 sill, dated as 105 Ma, was recovered at 1612 m below seafloor. Another sill, at least 17 m thick and recovered some 100 m deeper in the section, is 8 M.y. younger than the upper sill. Undercompacted, plastic, high-porosity sediments recovered from between the two sills yielded elevated concentrations <strong>of</strong> gaseous hydrocarbons. Metamorphic minerals and textures characterise the narrow contact zones between sills and host sediment. Further away from the narrow metamorphic contact zones, the thermal aureole <strong>of</strong> the sills is recorded by unusual gradients in the alteration <strong>of</strong> organic and mineral components. In the poorly compacted, gas-bearing interval, however, organic maturity indicators reach a minimum where clay mineral assemblages indicate substantial alteration This discrepancy may be related to the unusually elevated porosity: Whereas overlying sediment was compacted to a porosity around 20%, porosity values up to 44% were retained in the gas-bearing interval. Pore-water overpressure may have delayed the maturation <strong>of</strong> organic matter whereas mineral transformation was probably favoured by ion supply from alteration near the underlying sill through the open pore framework. Elevated concentrations <strong>of</strong> gaseous hydrocarbons were likely generated at the lower sill contact or in the underlying sedimentary section. Numerical simulation suggests that pore pressure build-up beneath the upper sill is strong enough to overcome its tensile strength. Mineralised veins <strong>with</strong>in the metamorphic contact zone are thought to have precipitated from fluids that escaped from the compartment between the sills when pressure exceeded the strength <strong>of</strong> the overlying seal. The intercalation <strong>of</strong> undercompacted sediments <strong>with</strong> sills creates a high-amplitude seismic reflector that covers much <strong>of</strong> the proximal Newfoundland Basin. We expect that sills and adjacent, normally compacted shales, created extensive, vertically stacked fluid barriers. Where pressure build-up was sufficient, fracturing <strong>of</strong> the sills allowed for intermittent fluid release, wheras other sills may remain unbreached. 31-12 BTH 18 Özer, Cigdem PETROLEUM POTENTIAL OF THE ARGENTINE CONTINENTAL MARGIN – DATA COMPILATION AND PSEUDO-WELL SIMULATION ÖZER, Cigdem1 , PLETSCH, Thomas1 , LUTZ, Rüdiger1 , FRANKE, Dieter1 , and BRANDES, Christian2 , (1) Federal Institute for Geosciences and Natural Resources (BGR), Stilleweg 2, Hannover, 30655, cigdem.oezer@bgr.de, (2) Institute <strong>of</strong> Geology, University <strong>of</strong> Hannover, Callinstraße 30, Hannover, 30176, Germany The undrilled and underexplored passive continental margin <strong>of</strong>f Argentina and Uruguay is characterised by seaward-dipping reflector (SDR) sequences which are interpreted to be dominantly effusive volcanics. Early Cretaceous rifting and breakup <strong>of</strong> the southern South Atlantic were accompanied, on its western side, by short-term, but widespread emplacement <strong>of</strong> 60-120 km wide SDR wedges along the continent-ocean boundary. These voluminous bodies may have had an influence on regional petroleum systems through the dissipation <strong>of</strong> their heat, their impact on the subsidence <strong>of</strong> adjacent basins, their potential sealing capacities, or through their characteristic internal geometry and the intercalation <strong>of</strong> potential reservoir facies. The structural similarity <strong>of</strong> the Argentine margin <strong>with</strong> hydrocarbon-producing volcanic rifted margins, such as those <strong>of</strong>fshore Norway or Namibia, has stimulated comparisons regarding their resource potential. This study is part <strong>of</strong> a project that aims at providing quantitative estimates <strong>of</strong> the in-place petroleum (oil and gas) volumes along the Argentine Margin. Ideally, this should procede via the calculation <strong>of</strong> potentially generated, migrated and trapped petroleum volumes and via a statistical evaluation <strong>of</strong> the certainties involved. For this purpose, quantitative input data are required. Gross volumes <strong>of</strong> potential source rock and reservoir lithologies are drawn from own seismic data, but other data (e.g. TOC, HI, maturity, porosity, seal integrity) are unknown from the target area. Consequently, this study relies heavily on indications from basins that are taken to be analogous <strong>with</strong> respect to the subsidence, sedimentary and paloceanographic evolution <strong>of</strong> the Argentine margin. Source rock data from adjacent and remote basins <strong>with</strong> supposedly analogous depositional and thermal histories were compiled and used to simulate pseudo-wells along the Argentine margin. Preliminary results point to the existence <strong>of</strong> viable petroleum systems related to source rocks from pre-rift and early post-rift sequences known from adjacent basins. 31-13 BTH 19 Scheck-Wenderoth, Magdalena COUPLED TRANSPORT OF HEAT AND FLUID IN FAULTED POROUS MEDIA CACACE, Mauro1 , SCHECK-WENDEROTH, Magdalena2 , KAISER, Björn Onno1 , CHERUBINI, Yvonne1 , NOACK, Vera2 , and LEWERENZ, Björn2 , (1) University <strong>of</strong> Potsdam, am Neuen Palais 10, Potsdam, 14469, Germany, (2) Section 4.4 Basin Analysis, Helmholtz Centre Potsdam GFZ German Research Centre for Geosciences, Telegrafenberg C4, Potsdam, 14473, Germany, leni@gfz-potsdam.de Sedimentary basins host a significant portion <strong>of</strong> the world’s economic mineral and energy resources. Formation <strong>of</strong> these resources involves the interaction <strong>of</strong> different and likely coupled processes including groundwater flow, mechanical deformation, mass and energy transfer. Understanding the dynamics <strong>of</strong> flows and related physical processes in sedimentary basins is essential for a correct assessment <strong>of</strong> their geothermal potential. The major challenge is to understand the coupling between processes occurring in a common geological framework but having inherent different spatial and temporal scales. Numerical (mathematical) models provide useful tools to analyse all these aspects and to be predictive for a correct assessment <strong>of</strong> geothermal resources especially in areas where data acquisition is demanding. An integrated approach is presented which combines geological and geophysical observations <strong>with</strong> numerical techniques to unravel these challenges and to investigate the thermal field and fluid flow system in the Northeast German Basin (NEGB). 31-14 BTH 20 Kunkel, Cindy VARIATIONS IN AQUIFER CHARACTERISTICS AND -EVOLUTION OF THE GERMAN BUNTSANDSTEIN FACIES OF THE THURINGIAN BASIN, EAST GERMANY KUNKEL, Cindy, BEYER, Daniel, HILSE, Ulrike, AEHNELT, Michaela, VOIGT, Thomas, PUDLO, Dieter, and GAUPP, Reinhard, Friedrich-Schiller-University, Institute for Geoscience, Jena, 07749, Germany, Cindy.Kunkel@uni-jena.de The Lower Triassic Buntsandstein is a major aquifer in Thuringia and adjacent areas in central Germany. In the Thuringian Basin the investigation <strong>of</strong> its reservoir characteristics is part <strong>of</strong> a BMBF sponsored project on integrated fluid dynamics in sediment basins (INFLUINS). The aquifer sediments are composed <strong>of</strong> fluvial, eolian and lacustrine facies which exhibit differences in reservoir quality. These differences are linked <strong>with</strong> facial and mineralogical controls causing regional to small scale variations <strong>of</strong> reservoir properties. In order to understand reservoir property differences and their linkage to fluid flow pattern an investigation <strong>of</strong> facies and diagenesis <strong>of</strong> the sandstones was undertaken comparing infiltration areas in outcropping Buntsandstein at the north-western basin margin (Eichsfeld) and subsurface Buntsandstein in wells in the basin center (area <strong>of</strong> Erfurt). In the basin center the Lower Buntsandstein is dominated by lacustrine deposits, the Middle Buntsandstein by fluvial sediments <strong>with</strong> some eolian sandstones in the lower part and massive fluvial channel and sandflat sandstones in the upper part. At basin margins a strong increase <strong>of</strong> eolian deposits occurs as well as thickness reductions and erosion in the Middle Buntsandstein, but increasing thickness in the lowermost Lower Buntsandstein and the highest Middle Buntsandstein. Preferential pathways <strong>of</strong> fluid migration occur in intervals dominated by Munich, Germany A45 Tuesday
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Geologische Vereinigung e.V. Hosted
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RISIKEN ERKENNEN LÖSUNGEN ERARBEIT
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