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Minerals Report - International Seabed Authority

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sediment and to provide an indication of the presence of underlying free<br />

gas zone.<br />

c) Wave- form inversion<br />

It must be appreciated that AVO analysis alone is not sufficient to<br />

distinguish different structural models across the BSR, nor can the AVO<br />

technique define the upper and lower boundaries of the free gas zone 49,54 .<br />

Identification of the top and bottom of the low velocity zone underlying<br />

the BSR can provide information about the thickness and lateral extent of<br />

the free gas layer associated with the formation of gas hydrates. Waveform<br />

inversion of seismic reflection data can be used to distinguish the models<br />

and provide tight constraints on the thickness of a gaseous zone beneath<br />

the BSR. With the waveform inversion technique, a velocity model can be<br />

created such that the synthetic data over all offsets fits the real data at the<br />

BSR.<br />

5.2. Non-Geophysical Proxies<br />

It is not always possible to observe natural gas hydrates directly<br />

because they decompose during recovery of samples from the seafloor.<br />

There are four groups of proxies providing more or less reliable evidence<br />

of hydrate presence in cores. In order to study these proxies, surficial and<br />

shallow sub-surficial sediment samples are needed. Since the sediments<br />

and water samples are analysed for proxies for gas hydrates, they need to<br />

be stored under in situ conditions for later analyses in the laboratory.<br />

These sediment samples are normally collected using piston or gravity<br />

corers, techniques with limitations in maintaining the in situ<br />

characteristics. An advanced technique of sampling is through specially<br />

designed pressure core samplers (PCS). The core samples collected<br />

through piston/gravity corers are collected in transparent PVC core liners<br />

so that the presence of gas pockets in the sediments can be visually<br />

inspected. The gas bearing sections of samples should be stored either in<br />

liquid nitrogen containers or kept in Nalgene bottles prior to storing them<br />

at –80 degrees C for subsequent gas analysis.<br />

In sediments, methane occurs as dissolved gas in the pore fluids<br />

and to some extent, adsorbed on the surface of particulate matter. Thus<br />

improper thermal or mechanical handling or storage of the sample can<br />

INTERNATIONAL SEABED AUTHORITY 538

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