FTIR Series Accessories - Shimadzu Scientific Instruments
FTIR Series Accessories - Shimadzu Scientific Instruments
FTIR Series Accessories - Shimadzu Scientific Instruments
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<strong>FTIR</strong> <strong>Series</strong><br />
<strong>Accessories</strong><br />
<strong>Shimadzu</strong><br />
Fourier Transform<br />
Infrared Spectrophotometers<br />
C103-E005H
2<br />
<strong>FTIR</strong> <strong>Accessories</strong> Overview<br />
Selection of Optional <strong>Accessories</strong><br />
<strong>Shimadzu</strong>'s <strong>FTIR</strong> instruments have simple optics to give an<br />
attachment having complicated optics its full play. In <strong>FTIR</strong>, which<br />
ensures exceptionally high wavenumber accuracy, even a singlebeam<br />
instrument provides satisfactory spectra, which means that the<br />
reference sample and the unknown sample can be measured<br />
individually; the net result is that, in <strong>FTIR</strong>, only one piece of<br />
attachment or accessory is useful enough. In dispersive IR, by<br />
contrast, attachments and accessories must be used as a pair. This<br />
is a great advantage from an economic viewpoint.<br />
Most of the attachments and accessories are designed so that<br />
samples may be measured without preparation.<br />
Shown to the right is a flow chart for selecting attachments and<br />
accessories. The results of <strong>FTIR</strong> analysis depend greatly<br />
on the type of attachment and accessory used in analysis.<br />
IRPrestige-21<br />
IRAffinity-1<br />
Type of<br />
Sample<br />
Solids<br />
Liquids<br />
Gases<br />
Micro/trace<br />
samples<br />
Rubbers<br />
Powders<br />
Paper, cloth, yarns<br />
Films, plastics<br />
Coating films<br />
on metals<br />
Coating films<br />
on resins<br />
Semiconductors<br />
Oil content measurement<br />
Nonvolatile organic<br />
solvents<br />
Volatile organic<br />
solvents<br />
Aqueous solutions<br />
Extract solutions<br />
Concentration<br />
Liquids<br />
Solids
Pyrolysis<br />
Thicker than 100μm<br />
Thinner than 100μm<br />
Dissolve in solvent<br />
Grind<br />
Thicker than 1 μm<br />
Mix with<br />
KBr powder<br />
Thinner than 1 μm<br />
Film holder<br />
Surface measurement Total reflectance method<br />
Total reflectance method<br />
Above 10% in concentration<br />
Below 10% in concentration<br />
Difference spectrometry<br />
Evaporate solvent<br />
% order<br />
ppm order<br />
μR order<br />
Below several handreds of μm<br />
Above several hundreds of μm<br />
Total reflectance method<br />
Liquid film method<br />
Nujol method<br />
KBr pellet method<br />
Total reflectance method Single-reflection ATR<br />
Diffuse reflectance method<br />
Total reflectance method<br />
Total reflectance method ATR-8000A, ATR-8200HA, Single-reflection ATR, etc.<br />
Transmission method<br />
Film method<br />
SiC sampler DRS-8000A, SiC sampler<br />
Specular reflectance method<br />
Total reflectance method<br />
Reflection absorption<br />
spectrometry<br />
KBr pellet method<br />
Diffuse reflectance method<br />
Total reflectance method<br />
Specular reflectance method<br />
Liquid film method<br />
Rapid measurement<br />
Solution method<br />
Liquid film method<br />
Total reflectance method<br />
Solution method<br />
Diffuse reflectance method<br />
Total reflectance method<br />
Transmission method<br />
Total reflectance method Single-reflection ATR<br />
Infrared microscopy<br />
Demountable cell<br />
Fixed thickness cell, sealed liquid cell<br />
Total reflectance method Single-reflection ATR<br />
ATR-8000A, ATR-8200HA, Single-reflection ATR, etc. (Black rubbers requires Ge prism)<br />
Demountable cell<br />
Demountable cell<br />
KBr die + hydraulic press + vacuum pump or mini hand press<br />
DRS-8000A ............ Mix with KBr powder<br />
ATR-8000A, ATR-8200HA, Single-reflection ATR, etc.<br />
Film holder .............. Use grid polarizer for study of molecular orientation<br />
Demountable cell .... Evaporate the solvent to obtain the film<br />
SRM-8000A, VeeMAX2A<br />
ATR-8200HA, .......... Measurement to a depth of 1/5 of the wavelength with<br />
Single-reflection ATR a KRS-5 prism and to 1/10 with a Ge prism<br />
RAS-8000A, ............ Use of a grid polarizer enhances sensitivity about two times<br />
VeeMAX2A<br />
KBr die + hydraulic press + vacuum pump (or mini hand press)<br />
DRS-8000A<br />
ATR-8200HA, .......... Measurement to a depth of 1/5 of the wavelength with a<br />
Single-reflection ATR KRS-5 prism and to 1/10 with a Ge prism<br />
SRM-8000A, ............ Convert a reflection spectrum into the absorption<br />
VeeMAX2A spectrum by the Kramers-Kronig method<br />
ATR-8200HA, Single-reflection ATR (Ge prism)<br />
Quartz cell .............. Detection limit is 1ppm level with 10 mm optical path<br />
Demountable cell with KRS-5 or ZnSe window<br />
ATR-8200HA, Single-reflection ATR<br />
Fixed thickness cell<br />
DRS-8000A ............. The sample solution is supplied dropwise on KBr powder<br />
and measured after evaporating the solvent<br />
ATR-8200HA, Single-reflectionATR ............ The sample solution is supplied<br />
dropwise on prism and measured<br />
after evaporating the solvent<br />
5cm/10cm gas cell<br />
Gas cell with long pathlength<br />
Micro cell<br />
AIM-8800 ................ Applicable to transmission, reflection, and ATR methods<br />
3
4<br />
<strong>Shimadzu</strong> Accessory Line-up<br />
1. Options from <strong>Shimadzu</strong><br />
Attenuated Total Reflectance Measurement<br />
Reflectance Measurement<br />
Diffuse Reflectance Measurement<br />
Micro Sample Measurement<br />
<strong>Accessories</strong> for Automated Measurement<br />
Purge Control Kit<br />
External Detector / Optional Detector<br />
Transmission Measurement<br />
Pellet Measurement<br />
Cells for Liquid Samples<br />
Others<br />
NIR Measurement<br />
Optional Software<br />
Attenuated Total Reflection Attachment<br />
Horizontal Type Attenuated Total Reflection Attachment<br />
Single-Reflection Horizontal Attenuated Total<br />
Reflection Attachment<br />
Single-Reflection Horizontal Attenuated<br />
Total Reflection Attachment<br />
Specular Reflectance Attachment<br />
Reflection Absorption Spectrometry Attachment<br />
Grid Polarizer<br />
Variable Incident Angle Reflectance Attachment<br />
Diffuse Reflectance Attachment<br />
SiC Sampler<br />
Automatic Diffuse Reflectance Attachment<br />
Reflection-Type Beam Condenser<br />
Automatic Infrared Microscope AIM-8800<br />
ATR Objective Mirror<br />
Sampling Kit<br />
Diamond Cell C<br />
Diamond Cell B<br />
Micro Magnetic Sample Holder<br />
Micro Vise Holder<br />
Automatic Sampler Diffuse Reflectance Attachment<br />
Auto Sampler for Transmission Measurement<br />
Sample Switcher 21<br />
Purge Control Kit<br />
Dry Air Supply Unit<br />
External light Beam Switching Kit<br />
MCT Kit<br />
Second Sample Compartment (with MCT detector)<br />
Second Sample Compartment<br />
MCT Detector<br />
Cassette (Sample Holder)<br />
Magnetic-Type Film Sample Holder<br />
Universal Clip Holder<br />
EZ-Clip 13<br />
EZ-Clip 25<br />
5cm Gas Cell<br />
10cm Gas Cell<br />
Gas Cell<br />
Mini Hand Press<br />
Evacuable Die for KBr Pellets<br />
Micro Die for 2mm dia. KBr Pellets<br />
Micro Die for 5mm dia. KBr Pellets<br />
Hydraulic Press<br />
Vacuum Pump<br />
Magnetic-Type Pellet Holder<br />
Agate Mortar and Pestle<br />
KBr Crystal (100g)<br />
Demountable Cell<br />
Sealed Liquid Cell<br />
Fixed Thickness Cell<br />
Sample Cell for Oil Content Determination<br />
Crystal Polishing Kit<br />
Far Infrared Kit<br />
NIR Set<br />
Upload Type Diffuse Reflectance Attachment<br />
NIR Integrating Sphere<br />
Fiber Coupler<br />
Reflective Fiber Probe<br />
Heating Transmission Cell<br />
Infrared Microscope<br />
IRsolution Agent<br />
Mapping Program<br />
Macro Platform<br />
3D Display Program<br />
PLS Quantitation Software<br />
Curvefitting (Peak split) Software<br />
Description P/N Remarks Page<br />
ATR-8000A<br />
ATR-8000<br />
ATR-8200HA<br />
ATR-8200H<br />
MIRacleA<br />
MIRacle<br />
MIRacleA<br />
MIRacle<br />
DuraSampllR2 (Diamond ATR)<br />
DuraScope<br />
SRM-8000A<br />
SRM-8000<br />
RAS-8000A<br />
RAS-8000<br />
GPR-8000<br />
VeeMAX2A<br />
VeeMAX2<br />
DRS-8000A<br />
DRS-8000<br />
DRS-8010ASC<br />
RBC-8000<br />
Type 1<br />
Type 2<br />
ATR-8800M<br />
DRS-8010ASC<br />
ASC-8000T<br />
PCK-8000<br />
PCK-8730<br />
PCK-8940<br />
PCK-8941<br />
PCK-21<br />
50Hz<br />
60Hz<br />
SSU-8000MCT<br />
SSU-8000<br />
MCTD-8000<br />
Long Pathlength Gas Cell<br />
MHP-1<br />
SSP-10A<br />
SA18-3M<br />
UpIR A<br />
IntegratIR A<br />
AIM-8800<br />
206-62303-91<br />
206-62303<br />
208-97240-91<br />
208-97240<br />
208-97247-95<br />
208-97247-91<br />
208-97247-96<br />
208-97247-92<br />
See page 9<br />
208-92184<br />
208-92207<br />
206-62304-91<br />
206-62304<br />
206-62302-91<br />
206-62302<br />
206-61550<br />
208-977284-91<br />
208-97284-92<br />
206-62301-91<br />
206-62301<br />
200-66750<br />
206-62308<br />
206-62305<br />
206-72500-92<br />
206-72500-96<br />
206-70450-91<br />
208-92171<br />
208-92236<br />
200-66752<br />
208-97206<br />
208-97202<br />
206-62308<br />
206-63900<br />
206-63663-92<br />
206-62309<br />
206-70170-91<br />
206-71122-91<br />
206-73512<br />
206-72352-91<br />
200-64185-01<br />
200-64185-02<br />
206-70125-92<br />
206-72017-91<br />
206-62306-01<br />
206-62306<br />
206-62307<br />
206-17384<br />
200-66754-11<br />
208-97207<br />
208-97208<br />
208-97209<br />
202-32006-<br />
202-32007-<br />
—<br />
200-66747-91<br />
202-32010<br />
202-32011<br />
202-32012<br />
200-64175<br />
261-79017<br />
200-66753-11<br />
200-93508<br />
202-34141<br />
202-32000-<br />
202-32001-<br />
202-32002-<br />
See page 32<br />
202-32024<br />
206-72016-91<br />
206-72015-91<br />
208-97271-91<br />
208-97272-91<br />
206-72751-91<br />
206-72760-91<br />
206-72716-91<br />
206-73700-<br />
206-21600-92<br />
206-73738-91<br />
206-72330-91<br />
206-73737-91<br />
206-72331-91<br />
206-72333-91<br />
with KRS-5 prism<br />
with ZnSe prism<br />
with ZnSe prism<br />
with Ge prism<br />
with Diamond prism<br />
Incident Angle:<br />
10°C<br />
Incident Angle:<br />
70 to 75 °C<br />
Incident Angle:<br />
30 to 80 °C<br />
with Ge prism<br />
6<br />
7<br />
8<br />
9<br />
10<br />
12<br />
13<br />
14<br />
15<br />
17<br />
18<br />
19<br />
21<br />
22<br />
23<br />
24<br />
25<br />
27<br />
28<br />
28<br />
29<br />
30<br />
31<br />
32<br />
33<br />
34<br />
35<br />
36<br />
38<br />
39<br />
40<br />
42<br />
43<br />
44<br />
45<br />
46
Attenuated Total Reflectance Measurement<br />
Attenuated Total Reflection Method<br />
The Attenuated Total Reflection (ATR) method, also called Multiple Internal Reflectance (MIR) method, is a versatile and powerful technique<br />
for infrared absorption spectrophotometry. This method is popular not only in <strong>FTIR</strong> but also in conventional dispersive IR, because it is not<br />
necessary to chemically treat, or machine, the samples. Measurement is made without destroying the samples.<br />
<strong>FTIR</strong> instruments, which ensure far higher sensitivity than dispersive lR instruments, dramatically widen the scope of application scope of the<br />
attenuated total reflection method; hence, a wide variety of attachments have been developed for this application.<br />
<strong>Shimadzu</strong> also provides a variety of ATR attachments.<br />
Principle<br />
The sample is held in contact with a prism made of highly refractive<br />
material, which transmits infrared rays; infrared rays are made<br />
incident on this sample at an angle larger than the critical angle<br />
(angle that induces total reflection). The light that is totally reflected<br />
by the interface between the sample and the prism is measured to<br />
obtain an infrared spectrum.<br />
Though it is called "total reflection", the light travels through the thin<br />
surface layer of the sample, as shown in the figure below, and<br />
therefore, the spectrum obtained is similar to that obtained from a<br />
very thin slice of the same sample.<br />
Requirements for Measurements by the ATR Method<br />
The sample must be placed in close contact<br />
with the surface of the prism.<br />
The prism has a higher refractive index<br />
than the sample.<br />
Penetration Depth of IR Light (Sample thickness)<br />
Infrared light can penetrate<br />
to a depth expressed<br />
by the next equation:<br />
Example of Penetration Depth<br />
Sample refractive index of 1.5<br />
Material<br />
Refractive index (1,000 cm-1 )<br />
Incident angle<br />
Penetration<br />
depth<br />
4,000 cm-1 2,000 cm-1 1,000 cm-1 400 cm-1 Material<br />
Refractive index (1,000 cm -1 )<br />
Incident angle<br />
Penetration<br />
depth<br />
4,000 cm-1 2,000 cm-1 1,000 cm-1 400 cm-1 1.2μm<br />
2.4μm<br />
4.8μm<br />
12.0μm<br />
λ<br />
dp=<br />
2π(sin2θ-n21 2 1<br />
) 2<br />
ZnSe/KRS-5/Diamond<br />
2.4<br />
45° 60°<br />
1.2μm<br />
2.4μm<br />
4.8μm<br />
12.0μm<br />
Germanium<br />
4<br />
45°<br />
0.7μm<br />
1.3μm<br />
2.7μm<br />
6.6μm<br />
0.7μm<br />
1.3μm<br />
2.7μm<br />
6.6μm<br />
30° 60°<br />
Prism<br />
Prism<br />
Sample<br />
Sample<br />
Sample<br />
lnfrared rays<br />
This method is applicable to soft rubber or plastic samples,<br />
solid samples with a flat surface, liquid samples, and powder samples.<br />
lt is necessary to use a prism having an appropriate refractive index.<br />
0.5μm<br />
1.0μm<br />
2.0μm<br />
5.1μm<br />
where, θ : lncident angle<br />
n21: (Refractive index of sample) /<br />
(Refractive index of prism)<br />
λ : Wavelength<br />
When θ= 45° and n21 = 0.5, therefore, 10μm (1000 cm-1) dp<br />
corresponds to 3.18μm and 5μm dp (2000 cm-1 ) to 1.6μm.<br />
The ATR method provides spectra of surface layers without actually<br />
slicing them.<br />
Since the measurable depth (thickness) differs with the wavelength<br />
of the light, the ATR method give spectra of a little different shape<br />
though the peak wavenumbers are the same.<br />
The software program for correcting for penetration depth,<br />
incorporated in the IRPrestige-21, IRAffinity-1, <strong>FTIR</strong>-8000 <strong>Series</strong><br />
further widens the application field of the ATR method.<br />
5
6<br />
Attenuated Reflectance Measurement<br />
Attenuated Total Reflection Attachment<br />
ATR-8000A (P/N 206-62303-91)<br />
ATR-8000 (P/N 206-62303)<br />
In the ATR-8000 series, the incident angle is changeable in three<br />
steps of 30°, 45°, and 60°, so that measurement can be made to<br />
different depths. Combined with the program to correct for the<br />
penetrating depth of the infrared rays (which is a weak point of the<br />
ATR method because it differs depending on the wavenumber), this<br />
feature provides spectra that are highly comparable to those given by<br />
another method. QuickStart ATR-8000A includes the automatic<br />
accessory recognition function.<br />
Features<br />
It is not necessary to adjust the position of the prism when a new<br />
sample is set.<br />
The sample holder is held at one point; hence, the prism is under<br />
minimized force.<br />
45 times reflection (with an incident angle of 45°) ensures high<br />
sensitivity.<br />
Standard software includes a program to correct for penetration<br />
depth.<br />
Maximum sample size: 40mm x 15mm, 10mm thick<br />
Standard Content<br />
Attenuated Total Reflection Attachment<br />
ATR prism (KRS-5)<br />
Sample holder<br />
Hex key wrench<br />
PhiIlips screwdriver<br />
Prisms<br />
Material Refractive Index<br />
(1000cm -1 )<br />
KRS-5<br />
Ge<br />
Note: Prisms without a holder are recommended as supplies, while those with a<br />
holder are recommended when prisms of different materials are purchased.<br />
45°<br />
Description Quantity<br />
2.37<br />
4.0<br />
206-61560-01<br />
206-61560-02<br />
(52)<br />
(48)<br />
50<br />
With holder<br />
(P/N)<br />
Dimensions of Prism<br />
2<br />
20<br />
1<br />
1<br />
1 set<br />
1<br />
1<br />
Without holder<br />
(P/N)<br />
200-66125-01<br />
200-66125-02<br />
to detector<br />
Optics of ATR-8000<br />
ATR-8000<br />
Prism<br />
ATR Spectrum of PET (KRS-5 prism)<br />
60°<br />
45°<br />
ATR Spectrum of PET, corrected for Penetration Depth<br />
30°
Horizontal Type Attenuated Total Reflection Attachment<br />
ATR-8200HA (P/N 208-97240-91)<br />
ATR-8200H (P/N 208-97240)<br />
The principle is the same as the ATR-8000. Since the prism can be<br />
placed horizontally, powder or liquid samples, which cannot be<br />
analyzed with the ordinary ATR attachment, can be readily<br />
measured. QuickStart ATR-8200HA includes the automatic<br />
accessory recognition function.<br />
Features<br />
Prisms for liquid samples and for solid samples are provided as<br />
standard.<br />
The prism is mounted and dismounted by one-touch operation,<br />
which ensures easy exchange of samples.<br />
ZnSe prisms are very chemically stable and ensure high<br />
mechanical strength.<br />
Standard Content<br />
1<br />
2<br />
3<br />
4<br />
Horizontal Type Attenuated Total Reflection<br />
Attachment<br />
ZnSe prism for solid samples, 45° incident angle<br />
ZnSe prism for liquid samples, 45° incident angle<br />
Gripper (P/N 208-97240-25)<br />
The prism for liquid samples is fixed in the groove, as shown in the<br />
figure, so that liquid, powder, or gel samples may be easily<br />
measured.<br />
The dent to accept a sample is accessible from above to ensure<br />
ease when replacing samples and cleaning the prism.<br />
Spectrum of Edible Oil<br />
Description Quantity<br />
The prism for liquid samples is fixed in the bottom of a boat-shaped groove, as shown in the<br />
above figure, so that liquid, powder or gel samples can be easily measured.<br />
The indentation to accept the sample is accessible from above to ensure ease when replacing<br />
samples and cleaning the prism.<br />
The prism for solid samples permits easy measurement of film type<br />
and other solid samples, the operation being the same as that for the<br />
ATR-8000.<br />
A plate is fixed with screws to put the sample in close contact with<br />
the prism surface, which ensures high reliability of the spectra.<br />
Spectrum of PVDC Sheet<br />
The prism for solid samples permits easy measurement of film and other solid samples, with<br />
operation being the same as that for the regular ATR.<br />
A gripper is fixed to hold the sample in close contact with the prism surface, which enables highly<br />
reliable spectra.<br />
Prisms<br />
Description P/N<br />
ZnSe prism for solid samples, 45° incident angle 208-97240-03<br />
ZnSe prism for liquid samples, 45° incident angle 208-97240-01<br />
Ge prism for solid samples, 45° incident angle 208-97240-13<br />
Ge prism for liquid samples, 45° incident angle 208-97240-10<br />
1<br />
1<br />
1<br />
1<br />
to detector<br />
Prism<br />
Optics of ATR-8200H<br />
ATR-8200H<br />
Sample<br />
<strong>FTIR</strong> Spectrum of Oil<br />
<strong>FTIR</strong> Spectrum of PVDC Sheet<br />
7
8<br />
Attenuated Total Reflectance Measurement<br />
Single-Reflection Horizontal Attenuated<br />
Total Reflection Attachment<br />
MIRacleA ZnSe prism model (P/N 208-97247-95)<br />
MIRacle ZnSe prism model (P/N 208-97247-91)<br />
MIRacleA Ge prism model (P/N 208-97247-96)<br />
MIRacle Ge prism model (P/N 208-97247-92)<br />
MIRacle is a single-reflection horizontal attenuated total reflection<br />
attachment which uses a 2 mm prism in diameter. Since the prism is<br />
placed horizontally, solid samples, such as plastics, fibers, films and<br />
powders, and liquid samples can be measured. QuickStart MIRacleA<br />
includes the automatic accessory recognition function.<br />
Features<br />
Since the small prism is mounted, small solid samples and a bit of<br />
a liquid sample can be measured.<br />
The ZnSe prism can measure the wavenumber range from 5000<br />
cm-1 to 650 cm-1. The Ge prism can measure the wavenumber range from 5000 cm-1 to 700 cm-1 and can be used for the measurement of high<br />
refractive index samples such as black rubber samples.<br />
Standard Content<br />
Prisms<br />
Description Quantity<br />
Single-Reflection Horizontal Attenuated Total<br />
Reflection Attachment<br />
Single-Reflection HATR UniversaI plate<br />
(Selected prism, ZnSe prism or Ge prism)<br />
Pressure clamp<br />
Trough Insert<br />
Description P/N<br />
Single-Reflection HATR Universal Plate, ZnSe prism 208-97247-93<br />
Single-Reflection HATR Universal Plate, Ge prism 208-97247-94<br />
1<br />
1<br />
1<br />
1<br />
to detector<br />
Thumb screw<br />
Trough Insert<br />
Optics of MIRacle<br />
MIRacle<br />
ZnSe Prism Plate<br />
Prism<br />
Spectrum of EVA (Ethylene Vinyl Acetate) pellet
DuraSamplIR2 (Diamond ATR)<br />
This is a single-reflection ATR system that presses an approximately<br />
2 mm diameter diamond prism tightly against the sample. The<br />
diamond prism allows the analysis of hard samples. The fit between<br />
the sample and prism is extremely good, making it convenient for<br />
liquids, solids, powders, fibers and film samples. With System I<br />
(High-Pressure Device type), the sample is pressed tightly against<br />
the prism by the clamper accessory while adjusting the clamping<br />
pressure. With System H (ViewIR type), the sample can be observed<br />
as it is being clamped. System I is also available with a pressure<br />
sensor included.<br />
ZnSe and KRS-5 support elements are available to support the<br />
diamond prism. The measurement wavenumber range is up to 650<br />
cm-1 for ZnSe and 400 cm-1 for KRS-5.<br />
The pressure sensor cannot be added later. If it will be needed,<br />
please include it when purchasing the system.<br />
DuraSamplIR2 Part Names and P/N<br />
Description P/N<br />
DuraSamplIR2A System I<br />
(ZnSe support element)<br />
208-92143-11<br />
DuraSamplIR2A System I<br />
(ZnSe support element, with pressure sensor)<br />
208-92144-11<br />
DuraSamplIR2A System I<br />
(KRS-5 support element)<br />
208-92143-12<br />
DuraSamplIR2A System I<br />
(KRS-5 support element, with pressure sensor)<br />
208-92144-12<br />
DuraSamplIR2A System H<br />
(ZnSe support element)<br />
208-92145-11<br />
DuraSamplIR2A System H<br />
(KRS-5 support element)<br />
208-92145-12<br />
The systems above include an automatic accessory detection feature.<br />
Description P/N<br />
DuraSamplIR2 System I<br />
(ZnSe support element)<br />
208-92143-01<br />
DuraSamplIR2 System I<br />
(ZnSe support element, with pressure sensor)<br />
208-92144-01<br />
DuraSamplIR2 System I<br />
(KRS-5 support element)<br />
208-92143-02<br />
DuraSamplIR2 System I<br />
(KRS-5 support element, with pressure sensor)<br />
208-92144-02<br />
DuraSamplIR2 System H<br />
(ZnSe support element)<br />
208-92145-01<br />
DuraSamplIR2 System H<br />
(KRS-5 support element)<br />
208-92145-02<br />
Optional and Standard Parts<br />
Description P/N<br />
DuraDisk (ZnSe support element)<br />
208-92147<br />
DuraDisk (KRS-5 support element)<br />
208-92148<br />
DuraDisk (Ge/Ge)<br />
208-92238<br />
The DuraDisk is the section where the diamond prism and the<br />
support element are joined together (the cylindrical metal section<br />
shown in the photo of the System I exterior). DuraDisks can be<br />
replaced by the customer.<br />
Metal Plate<br />
Diamond Prism<br />
Infrared Light ZnSe or KRS-5 Support Element<br />
DuraSamplIR2 Optics<br />
Exterior of System I (High-Pressure Device Type)<br />
Exterior of System I (with pressure sensor)<br />
Exterior of System H (ViewIR Type)<br />
9
10<br />
Attenuated Total Reflectance Measurement<br />
DuraScope (P/N 208-92184)<br />
As with the DuraSamplIR, this is a single-reflection diamond ATR,<br />
where measurements are conducted by pressing the sample against<br />
the approximately 2 mm diameter diamond prism. A micro CCD<br />
camera is provided directly below the diamond prism to allow the<br />
observation of the contact status between the sample and prism on a<br />
video monitor. The built-in pressure sensor indicates the pressure<br />
being applied to the prism. Apart from solid samples such as plastics,<br />
film or powders, liquid samples can be also analyzed by being<br />
dropped onto the prism surface.<br />
Description P/N<br />
DuraScope<br />
(ZnSe support element)<br />
208-92184<br />
DuraScope<br />
(KRS-5 support element)<br />
208-92207<br />
Options for DuraSampllR II and DuraScope<br />
Description P/N<br />
DuraDisk<br />
(ZnSe support element)<br />
208-92144<br />
DuraDisk<br />
(KRS-5 support element)<br />
208-92148<br />
DuraDisk (Ge/Ge)<br />
208-92238<br />
The DuraDisk is the section where the diamond prism and the support element<br />
are joined together. A DuraDisk for the Ge prism for measuring high refractive<br />
index samples also is available. DuraDisks can be replaced by the customer.<br />
DuraScope<br />
Video Monitor
Reflectance Measurement<br />
Specular Reflectance Method<br />
<strong>FTIR</strong> measurement by the specular reflectance method provides three types of information shown below:<br />
1The incident light passes through the 2The incident light is reflected by the surface 3The<br />
above mentioned two types of<br />
sample layer and is reflected by the<br />
of the sample: the reflection spectrum is<br />
information are mixed: the spectrum given is<br />
substrate: the spectrum given is similar to obtained, which can be converted into<br />
the sum of the transmission spectrum and the<br />
that obtained by the transmission method. absorption spectrum through the use of the reflection spectrum. When the sample has a<br />
Measurement of thin film on a metal plate Kramers-Kronig analysis method.<br />
uniform thickness, the two reflection light<br />
is a typical<br />
Metal substratum Transmitted<br />
beams interfere with each other, and the<br />
example of this<br />
light cannot be<br />
sample thickness can be obtained from the<br />
method.<br />
Thin film<br />
detected.<br />
Sample<br />
interference pattern.<br />
The measurement of<br />
a epitaxiaI layer of a<br />
Metal substratum<br />
IR rays<br />
IR rays<br />
semi-conductor<br />
sample is a typical<br />
application of this<br />
Thin film<br />
1.Reflection Absorption Spectroscopy<br />
The Reflection Absorption Spectroscopy (RAS) method permits highsensitivity<br />
measurement of a thin film sample on a metal substrate.<br />
method.<br />
IR rays<br />
This method has recently come to be applied to the measurement of<br />
very thin (a few tens of angstroms thick) samples, e.g. organic LB<br />
films (Langmuir-Brodgett's Iayers), and to the determination of<br />
molecular orientation.<br />
When a polarized Iight beam is made incident on a metal substrate,<br />
as shown below, it is changed in phase when reflected by the metal<br />
surface.<br />
1. In vertical polarization, the vectors of the polarized light are<br />
opposite to each other. Therefore, no stationary waves are<br />
produced on the substrate, and interaction with the film material is<br />
not detected.<br />
2. ln parallel polarization, the vectors of the polarized Iight meet at a<br />
point to produce stationary waves, which interact with the film and<br />
are absorbed. The intensity of this absorption is dependent on the<br />
incident angle: the larger the incident angle, the higher the<br />
intensity of absorption. The optimum incident angle is different<br />
with the type of sample and the wavelength of the peak under<br />
Vertical polarization Parallel polarization<br />
study. In many cases, an incident angle between 70° and 80° is<br />
Metal plate Metal plate<br />
used.<br />
Reflection of Light on MetaI Substratum<br />
2.Conversion of Reflection Spectra into Absorption Spectra<br />
A reflection spectrum, which provides information on the optical<br />
properties of the sample, must be converted into the absorption<br />
spectrum to be informative about the chemical structure of the<br />
sample. The Kramers-Kronig analysis method is quite convenient in<br />
that it is useful to convert a reflection spectrum into an absorption<br />
spectrum: it is not necessary to shave or slice the sample. In the<br />
example (2) shown below, when the ø is sufficiently small, each<br />
element of the complex refractive index of a material may be<br />
expressed as:<br />
1-R<br />
Reflectance value n= (1)<br />
1+R-2√Rcosθ<br />
Absorption coefficient<br />
-2√Rsinθ<br />
k= 1+R-2√Rcosθ<br />
Examples of Applications<br />
(2)<br />
where, R: Reflectance value<br />
θ: phase shift when the light is reflected.<br />
The θ for the wavenumber vg may be calculated from the following<br />
Kramers-Kronig equation:<br />
θ(νg)= dν<br />
ν2−νg2 2νg ∞<br />
In√R(ν)<br />
π ∫ 0<br />
The θ can be obtained from the reflectance value R, and substituting<br />
that θ in the equation (2) gives the absorption coefficient k.<br />
Performing this calculation for all the wavenumbers will give the<br />
absorption spectrum.<br />
Since a reflection spectrum can be converted into the absorption spectrum through Kramers-Kronig analysis,<br />
1Absorption spectrum can be obtained without shaving or slicing the sample, provided that the sample has a smooth surface. lt is not<br />
necessary to use an ATR prism or a costly attachment.<br />
2Kramers-Kronig analysis method is especially effective for infrared microscopy, where it is virtually impossible to slice the sample.<br />
(3)<br />
11
12<br />
Reflectance Measurement<br />
Specular Reflectance Attachment<br />
SRM-8000A (P/N 206-62304-91)<br />
SRM-8000 (P/N 206-62304)<br />
The specular reflectance measurement method is an old method to<br />
obtain reflection lR spectra.<br />
The SRM-8000 series permits not only measurement of reflection<br />
spectra, but also measurement of absorption spectra through the<br />
combined use of the Kramers-Kronig analysis method. This<br />
attachment provides absorption spectra of solids, such as high<br />
polymers, without using a prism, which is required in the ATR<br />
method. QuickStart SRM-8000A includes the automatic accessory<br />
recognition function.<br />
Features<br />
Easy sample setting.<br />
Kramers-Kronig conversion software provides IR spectra without<br />
sample preparation.<br />
Description P/N<br />
Quantity<br />
Specular reflectance attachment<br />
1<br />
Standard mirror, 30 x 30 mm 200-66123<br />
1<br />
Sample mask, 15 mm dia. 206-18752-02 1<br />
Hex key wrench<br />
1<br />
Phillips screwdriver<br />
1<br />
to detector<br />
Optics of SRM-8000<br />
SRM-8000<br />
Sample<br />
Specular Reflectance Spectrum of the Inner Wall of Aluminum Can<br />
Specular Reflectance Spectrum of PMMA after<br />
Kramers-Kronig Conversion
Reflection Absorption Spectrometry<br />
Attachment<br />
RAS-8000A (P/N 206-62302-91)<br />
RAS-8000 (P/N 206-62302)<br />
The reflection absorption spectrometry method is used only in <strong>FTIR</strong>.<br />
When a vertically polarized light and a horizontally polarized light are<br />
made incident on a metal substrate, the lights are changed in the<br />
respective phase.<br />
In the case of vertically polarized light, the phase change<br />
is about π,<br />
irrespective of the incident angle, and, hence,<br />
the vectors of the reflected light interact destructively with<br />
each other; the stationary waves produced have almost<br />
zero amplitude - no absorption of the sample is detected.<br />
In the case of horizontally polarized light, the amount of<br />
phase change varies continuously from zero (for 0° incident angle) to<br />
π<br />
(for 90°). The amplitude of the stationary waves produced also<br />
changes with the incident angle: when a high incident angle is<br />
selected, the stationary waves will have a high amplitude and the<br />
interaction of the light beam and the sample will be high, resulting in<br />
a high detecting sensitivity. This method permits high-sensitivity<br />
measurement of thin films on metals having a high reflectance.<br />
Combined use of a grid polarizer further enhances the sensitivity.<br />
A grid polarizer (P/N 206-61550) is not included in the standard<br />
content of the RAS-8000 series but is available as an option.<br />
QuickStart RAS-8000A includes the automatic accessory recognition<br />
function.<br />
Features<br />
Easy sample setting.<br />
The incident angle is selectable between 70° and 75°.<br />
Standard Content<br />
Description P/N Quantity<br />
Reflection absorption spectrometry attachment<br />
Standard mirror<br />
Sample mask, 8 mm dia.<br />
Sample mask, 15 mm dia.<br />
Sample mask, 25 mm dia.<br />
Light beam mask, 3 x 3 mm<br />
Light beam mask, 5 x 5 mm<br />
Light shielding plate*<br />
Hex key wrench<br />
PhiIIips screwdriver<br />
200-66123<br />
206-18752-01<br />
206-18752-02<br />
206-18752-03<br />
206-18608-01<br />
206-18608-02<br />
* Attaching the light shielding plate raises the mean incident angle of the light<br />
beam from 70° to 75°.<br />
1<br />
1<br />
1<br />
1<br />
1<br />
1<br />
1<br />
1<br />
1<br />
1<br />
Incident<br />
light<br />
Reflected<br />
light<br />
Vertical polarization Parallel polarization<br />
Principle of Reflection Absorption Spectrometry<br />
Sample<br />
20°<br />
Light shield<br />
plate<br />
Optics of RAS-8000<br />
RAS-8000<br />
Stationary wave<br />
Mask (at wedge)<br />
Relationship Between Spectrum of Fluorine Film on Hard Disk,<br />
Peak Area and Film Thickness (calibration curve)<br />
13
14<br />
Reflectance Measurement<br />
Grid Polarizer<br />
GPR-8000 (P/N 206-61550)<br />
A grid is precisely produced on the substrate by the photographic<br />
technique. The grid polarizer enhances the sensitivity of the RAS-<br />
8000 Reflection Absorption Spectroscopy Attachment.<br />
Degree of polarization: 99% (at 10 μm), 95% (at 3 μm)<br />
Quenching ratio: 148: 1 (at 10 μm), 23:1 (at 3 μm)<br />
Effective area: 25 mm dia.<br />
Angle scale: 360°, 10° increments<br />
Material of substrate: KRS-5, 2 mm thick<br />
Measurement wavelength range: 5,000 to 350 cm-1 Note<br />
This grid polarizer cannot be used with the VeeMax II <strong>Series</strong>.<br />
GPR-8000<br />
Spectrum of Elongated Polyethylene Film<br />
Red: Parallel polarization<br />
Black: Vertical polarization<br />
Spectrum of Elongated Polyethylene Film (Enlarged)<br />
Red: Parallel polarization<br />
Black: Vertical polarization
Variable Incident Angle Reflectance<br />
Attachment<br />
VeeMAX 2 A (P/N 208-977284-91)<br />
VeeMAX 2 (P/N 208-97284-92)<br />
On this attachment, the incident angle can be varied within the range<br />
30 to 80°.<br />
Large samples can be measured as they are since the measurement<br />
position exits the sample compartment.<br />
An optional ATR prism and polarizer can be attached.<br />
VeeMAX II A is equipped with an accessory recognition function.<br />
Features<br />
Incident angle can be varied within the range 30 to 80°.<br />
Measurement is possible by merely placing the measurement<br />
surface of the sample face down.<br />
A polarizer can be used to perform high-sensitivity measurement of<br />
thin films and measure the orientation of polarized light.<br />
A single-reflection ATR prism can also be attached.<br />
Measurable Samples<br />
Coatings on flat metal surfaces<br />
Flat plastic sheet<br />
Attaching the optional ATR prism allows measurement of the<br />
following samples:<br />
Film, paper, rubber, plastic, fluid, gel samples<br />
Standard Content<br />
VeeMAX 2<br />
Sample mask set<br />
Gold-coated mirror<br />
Options<br />
Description P/N Quantity<br />
1<br />
208-97284-11<br />
208-97271-13<br />
Description P/N<br />
ZnSe prism plate for solid samples, 45° incident angle 208-97284-21<br />
Ge prism plate for solid samples, 45° incident angle 208-97284-24<br />
Sample clamp for VeeMAX<br />
208-97284-14<br />
KRS-5 polarizer for VeeMAX<br />
208-97300-12<br />
Liquid sample retainer for VeeMAX<br />
208-97300-28<br />
System Combinations<br />
Reflectance measurement in the range 30 to 80° can be handled<br />
on the VeeMAX II <strong>Series</strong>.<br />
When performing high-sensitivity reflectance measurement using a<br />
polarizer, purchase a VeeMAX II <strong>Series</strong> main unit and KRS-5<br />
polarizer for the VeeMAX. The GPR-8000 cannot be used.<br />
When performing ATR measurement of solid and film samples,<br />
purchase a VeeMAX II <strong>Series</strong> main unit, prism plate (45°) for solid<br />
samples for VeeMAX, and sample clamp for VeeMAX.<br />
When performing ATR measurement of liquid samples, purchase a<br />
VeeMAX II <strong>Series</strong> main unit, prism plate (45°) for solid samples for<br />
VeeMAX, and liquid retainer for VeeMAX.<br />
1<br />
1<br />
Exterior of VeeMAX 2 and Optional Polarizer<br />
VeeMAX 2 Optical System<br />
High-Sensitivity Reflection Spectrum of Hydroxylapatatite on Gold Plate<br />
and Fibrinogen Laminated Thin Film<br />
15
16<br />
Diffuse Reflectance Measurement<br />
Diffuse Reflectance Spectroscopy<br />
In measurement of powder samples by the dispersive IR method, the<br />
KBr pellet method is often used. The powder sample is mixed with<br />
alkali halide powder, such as KBr, and briquetted into a pellet, which<br />
is then measured by the transmission method. This KBr pellet<br />
method is also used in <strong>FTIR</strong>, but the diffuse reflection spectroscopic<br />
method is easier to perform.<br />
As shown in the figure below, when a light beam is made incident on<br />
a powder sample, some part of the light is specularly reflected by the<br />
surface of the powder. The other part penetrates into the sample and<br />
is transmitted and reflected repeatedly, and then emerges out of the<br />
sample as a diffuse reflected (scattered) light. This diffuse reflected<br />
light is informative of the IR spectrum of the powder sample.<br />
Diffuse<br />
reflected light<br />
Applications<br />
Specularly<br />
reflected light<br />
Reflection Within Powder Sample<br />
Incident light<br />
The diffuse reflectance spectroscopic method is applicable to any<br />
sample that can be pulverized. It also permits using, as the diluting<br />
substance, diamond powder or the like, which is not applicable to the<br />
KBr pellet method.<br />
This method is also applicable to detection of substances dissolved<br />
in a volatile solvent, such as fractions of liquid chromatography. LC<br />
effluent is made to drop on KBr powder, the mobile phase is<br />
removed by evaporation, and then the fraction is analyzed with the<br />
<strong>FTIR</strong> instrument equipped with a diffuse reflectance attachment.<br />
Diffuse reflected light, which has been repeatedly transmitted within<br />
the powder sample, gives a spectrum similar to ordinary transmission<br />
spectrum. The spectral intensity is not completely proportional to the<br />
concentration of the compounds under study: those components<br />
which are detected as rather low intensity absorption bands are<br />
detected at higher intensity because the light beam is transmitted<br />
repeatedly in the sample. It is necessary, therefore, to compare<br />
diffuse reflected spectra with ordinary transmission spectra or to<br />
convert them with the Kubelka-Munk equation.<br />
f= (1-R) 2 /2R = K/S<br />
where, K: absorption coefficient<br />
S: scattering coefficient<br />
R: reflection index<br />
(sample power spectrum/dilution power spectrum)<br />
Since it is very difficult to measure absolute reflection indices, diffuse<br />
reflection indices, which are the values relative to the reflection of<br />
KBr or KCI powder having no absorption in the IR region, are<br />
generally used.<br />
The spectra thus obtained are Kubelka-Munk converted to have<br />
intensities proportional to concentration. The result is spectra useful<br />
for quantitative determination. The <strong>FTIR</strong>-8000 <strong>Series</strong> / IRPrestige-21<br />
incorporates the Kubelka-Munk conversion function as a standard<br />
feature.<br />
HPLC<br />
fraction<br />
KBr powder<br />
Remove mobile phase<br />
through evaporation<br />
Detector<br />
<strong>FTIR</strong> Analysis of HPLC Fractions<br />
Diffuse reflectance attachment<br />
<strong>FTIR</strong><br />
Interferometer
Diffuse Reflectance Attachment<br />
DRS-8000A (P/N 206-62301-91)<br />
DRS-8000 (P/N 206-62301)<br />
The method of diffuse reflectance spectrometry is one of the most<br />
popular <strong>FTIR</strong> application methods of application of <strong>FTIR</strong>. lt features<br />
high-energy throughput and simple operation.<br />
The <strong>Shimadzu</strong> <strong>FTIR</strong> <strong>Series</strong> incorporates, as standard, the Kubelka-<br />
Munk conversion functions, essential to diffuse reflectance<br />
spectrometry for correcting the light scattering by the KBr powder.<br />
QuickStart DRS-8000A includes the automatic accessory recognition<br />
function.<br />
Features<br />
The small measuring light beam (1.8 x 1.8mm) ensures reliable<br />
analysis of small samples.<br />
The attachment is a drawer type, which ensures easy replacing.<br />
The standard data processing functions include the Kubelka-Munk<br />
conversion functions as standard.<br />
Standard Content<br />
Description P/N Quantity<br />
Diffuse reflectance attachment<br />
1<br />
Sample holder 2 mm ID cup<br />
1<br />
Sample holder 4 mm ID cup<br />
1<br />
Aluminum cup holder*<br />
1<br />
Standard mirror<br />
206-61184-01 1<br />
Ground glass mirror<br />
206-61184-02 1<br />
Sample holding rod<br />
1<br />
Hex key wrench<br />
1<br />
Phillips screwdriver<br />
1<br />
* Holder for disposable sample cup. Disposable sample cups are available as<br />
extra.<br />
Options<br />
Description P/N<br />
Sample cup, 50 pieces per set,<br />
aluminum, 6 dia. x 1.5 deep (mm)<br />
201-52943<br />
Sample die for aluminum cup<br />
206-63950<br />
SiC sampler<br />
200-66750<br />
to detector<br />
Sample<br />
Optics of DRS-8000<br />
DRS-8000<br />
Diffuse Reflectance Spectrum of Lactose<br />
Diffuse Reflectance Spectrum of Lactose After Kubelka-Munk Conversion<br />
17
18<br />
Diffuse Reflectance Measurement<br />
SiC Sampler (P/N 200-66750)<br />
In diffuse reflectance spectrometry, it is necessary to pulverize the<br />
sample and mix the powder with KBr powder.<br />
When the SiC sampler is used, the operation is simplified as follows:<br />
Diluent such as KBr powder is not required.<br />
The solid sample is ground with SiC emery paper and the sample<br />
powder on the emery paper is directly analyzed with the DRS-<br />
8000. (The SiC has a hardness of 9.0 and is quite chemically<br />
stable.)<br />
New emery paper is used as reference.<br />
Standard Content<br />
Description P/N<br />
Quantity<br />
Holding rod<br />
Sample holder<br />
SiC emery paper (#320)<br />
SiC emery paper (#400)<br />
208-92176<br />
1<br />
2<br />
100 sheets<br />
100 sheets<br />
Supplies<br />
Description P/N<br />
SiC emery paper (#320), 100 sheets<br />
200-66751-01<br />
SiC emery paper (#400), 100 sheets<br />
200-66751-02<br />
Sample holder that can be<br />
directly installed to<br />
the DRS-8000<br />
Construction of SiC Sample<br />
SiC Sampler<br />
Sticker type SiC<br />
emery paper<br />
Solid<br />
sample<br />
Diffuse Reflectance Spectrum of Plastic Products Obtained<br />
with SiC Sampler
Automatic Diffuse Reflectance Attachment<br />
DRS-8010ASC (P/N 206-62308)<br />
Having the same optics as the DRS-8000, the DRS-8010ASC<br />
accepts 24 samples to permit automated measurement.<br />
Features<br />
One-touch connection to the <strong>FTIR</strong> <strong>Series</strong>, which has the control<br />
capability as standard.<br />
With no external control unit required, the DRS-8010ASC is very<br />
compact.<br />
Controlled by the auto program incorporated as standard in the<br />
<strong>FTIR</strong> <strong>Series</strong>. The program is user-definable.<br />
Manual control to reduce the frequency of opening the lid of the<br />
sample compartment is possible, resulting in higher analytical<br />
productivity.<br />
Use of the disposable sample cups ensures easy exchange of<br />
samples.<br />
Notes<br />
When this attachment is used on IRAffinity-1, the ASC cable (P/N<br />
206-73433-91) is required.<br />
The BASIC software is required separately for the HYPER-IR<br />
model.<br />
Standard Content<br />
Description Quantity<br />
Automatic diffuse reflectance attachment<br />
Sample holder, 24-sample type<br />
Standard mirror<br />
Sample cup<br />
Die<br />
Tweezers<br />
Sample handling rod<br />
Hex key wrench<br />
Phillips screwdriver<br />
Supplies<br />
1<br />
2<br />
1 set<br />
200<br />
1<br />
1 pair<br />
1<br />
1<br />
1<br />
Description P/N<br />
Sample holder, 24-sample type<br />
206-65234<br />
Sample cup, aluminum, 6 dia. x 1.5 deep (mm) 201-52943<br />
For connection with <strong>FTIR</strong> main body,<br />
a cable is required.<br />
Description P/N<br />
Cable for IRPrestige-21, IRAffinity-1<br />
206-73433-91<br />
Cable for <strong>FTIR</strong>-8400S<br />
208-94914-02<br />
to detector<br />
Sample<br />
Optical Diagram of DRS-8010ASC<br />
DRS-8010ASC<br />
Sample stage<br />
19
20<br />
Micro Sample Measurement<br />
Measurement of Micro Samples<br />
<strong>FTIR</strong> ensures such a high sensitivity as to<br />
permit reliable measurement of micro<br />
samples.<br />
There are two popular devices to measure<br />
micro samples: beam condenser and infrared<br />
microscope. The objects of measurement are<br />
classified as the selected small part of the<br />
sample and a small part of a sample of<br />
uniform composition; measurement is made in<br />
either the reflection mode or transmission<br />
mode. These may be tabulated as follows:<br />
Transmission mode<br />
As shown in the figures, both in the beam condenser and the IR microscope, the<br />
IR light beam from the interferometer is condensed by the optics and made<br />
incident on the sample. The light beam from the sample is expanded to the original<br />
size and condensed on the detector, and then measured with the detector.<br />
The measurement principle of measurement is the same as that of ordinary<br />
samples, but in the case of micro samples, it is important to take the sample<br />
thickness into due consideration.<br />
In measurement of 50 μm thick yarn samples, for example, if measurement is<br />
made without reducing the thickness, the detector signal will be saturated-resulting<br />
in deformed absorption bands. It is necessary to compress the sample using a<br />
diamond cell or the like.<br />
Ordinary glass lenses are used for visual observation, while reflection mirrors must<br />
be used for lR measurement.<br />
Reflection mode<br />
Infrared microscopy is effectively used in reflection mode. As shown in the figure,<br />
the IR light from the interferometer is condensed by the reflecting objective and<br />
made incident on the sample, and the reflected light travels back to the same<br />
objective to be sensed by the detector. The paths for the incident light beam and<br />
the reflected light beam are switched by the wedge mirror.<br />
Though the measurement principle is the same as that of the samples of ordinary<br />
sizes, since the measurement is made on a very small area, specular reflection<br />
often occurs, resulting in abnormal peaks. The optics for visual observation and for<br />
lR rays are the same as that for the transmission mode.<br />
ATR mode microscopy<br />
Measurement mode<br />
Selection of the<br />
part to be measured<br />
Minimum<br />
measurable size<br />
Detector<br />
Installation<br />
The Attenuated Total Reflection (ATR) method is effectively used for<br />
samples that are opaque to IR rays, as well as for IR microscopy. It<br />
is especially effective for analysis of foreign materials on the resin<br />
surface and measurement of samples with curved surfaces.<br />
As shown in the figure, a semicircular prism is placed at the focus of<br />
the reflecting objective, and the light totally reflected by the interface<br />
of the sample and prism is measured to obtain the IR spectrum.<br />
Reflection-type beam<br />
condenser<br />
Transmission only<br />
Not possible<br />
About 200 μm<br />
Detector of the <strong>FTIR</strong><br />
Sample compartment of the <strong>FTIR</strong><br />
to detector<br />
X-Y-Z<br />
stage<br />
Sample<br />
Beam Condenser<br />
Infrared Microscope<br />
(Reflection mode)<br />
lR microscope<br />
Transmission/reflection/ATR<br />
Selection by aperture<br />
after observation in visual mode<br />
About 10μm<br />
Dedicated MCT detector<br />
(Measurement wavenumber<br />
range is limited by the MCT<br />
detector.)<br />
External installation<br />
IR light from interferometer<br />
Aperture<br />
Reflecting<br />
objective<br />
Autome<br />
sample<br />
Condenser<br />
mirror<br />
IR beam<br />
ATR (Ge) prism<br />
Sample<br />
MCT detector<br />
Entrance for IR<br />
beam from the<br />
<strong>FTIR</strong> main<br />
Infrared Microscope<br />
(Transmission mode)<br />
Schwarzchild<br />
reflecting objective mirrors.
Reflection-Type Beam Condenser<br />
RBC-8000 (P/N 206-62305)<br />
This beam condenser is especially useful for transmittance<br />
measurement of micro samples.<br />
Features<br />
Since no lenses are used, measurement can be made over the<br />
entire wavenumber region of the <strong>FTIR</strong> instrument.<br />
Combined use with an ultramicro cell, 0.05 mm optical path,<br />
permits transmission measurement of 2 to 3 μL of liquid samples.<br />
The light beam is reduced to 1/5 (about 1.8 x 1.8mm).<br />
Standard Content<br />
Description Quantity<br />
RBC-8000 reflection-type beam condenser<br />
Sample holder, with X-Y-Z stage<br />
Pellet sample holder<br />
Hex key wrench<br />
Phillips screwdriver<br />
1<br />
1<br />
1<br />
1<br />
1<br />
W-Y-Z<br />
stage<br />
Sample<br />
Optical Diagram of RBC-8000<br />
RBC-8000<br />
21
22<br />
Micro Sample Measurement<br />
Automatic Infrared Microscope<br />
AIM-8800<br />
Type 1 (P/N 206-72500-92 for 120V, -93 for 220V, -94 for 240V, -34 for CE, 230V)<br />
Type 2 (P/N 206-72500-96 for 120V, -97 for 220V, -98 for 240V, -35 for CE, 230V)<br />
The AIM-8800 is used with the <strong>FTIR</strong> <strong>Series</strong>, and is installed to the right<br />
of the instrument. This infrared microscope features ideal, bright optics<br />
and a state-of-the-art MCT detector, enabling high-sensitivity detection<br />
of micro samples to enhance the full potential of the <strong>FTIR</strong>. In addition,<br />
the numerous advanced functions, such as auto aperture setting and<br />
auto focusing, greatly simplify the analysis of micro samples.<br />
The microscope may remain attached to the instrument during ordinary<br />
measurement, so switching to microscopic measurement from ordinary<br />
measurement is no more than a touch away. (Note: The AIM-8800<br />
cannot be installed on the <strong>FTIR</strong>-8100.)<br />
Features<br />
Ideal optical system, employing a state-of-the-art MCT detector<br />
for high-sensitivity analysis.<br />
Auto aperture, auto centering and auto X-Y stage functions simplify<br />
determination of the analysis location.<br />
Auto focus brings image in clear focus with one mouse-click.<br />
Up to 10 samples and 2 background measurement sites can be<br />
stored in memory.<br />
Stage movement, aperture setting and focusing, as well as<br />
switching between transmission / reflection and measurement /<br />
observation modes are all performed via the PC screen.<br />
Control is also possible using the microscope's key-board.<br />
Specifications<br />
Optics<br />
MCT detector<br />
(Glass dewar type)<br />
Signal-to-noise ratio<br />
15 x Cassegrain objective<br />
15 x Cassegrain condenser mirrors<br />
Wavelength range :<br />
Type 1 : 5000-720cm-1 Type 2 : 5000-650cm-1 Transmission mode, aperture size 50 μm, 8cm-1 Wavelength range (near-infrared) (Note 1)<br />
10,000 to 3,800 cm-1 With liquid nitrogen monitoring system<br />
60 repeat scans<br />
2600: 1 or higher (Type 1), 2000: 1 or higher (Type 2)<br />
Electrically activated XYθ directional drive. Setting of XY direction<br />
aperture<br />
increments is 1 μm over Sample surface, and 1° increments in<br />
θ direction (numerical entry possible).<br />
Minimum setting value : 3 μm<br />
Motor-driven X-Y Positioning range : X axis : 70mm; Y axis : 30mm<br />
sample stage Resolution. 1 μm pitch<br />
Sample thickness : Reflection mode :<br />
Microscope keyboard<br />
Operation<br />
PC control<br />
< = 40mm<br />
Transmission mode : < = 10mm<br />
Measuring mode selection /<br />
XY stage operation (speed variable in 4 steps) / manual focusing /<br />
illumination control<br />
Measuring mode selection / XY stage operation /auto centering /<br />
manual focusing / auto focusing / illumination control /<br />
aperture setting / aperture preview /<br />
measurement position and aperture setting recording<br />
(10 sample positions, 2 background positions)<br />
(Note 1) Near-infrared measurement is possible only when the NIR Set is mounted<br />
on IRPrestige-21.<br />
Remarks:<br />
1) When connecting to a PC-type <strong>FTIR</strong>-8000 <strong>Series</strong>, IRAffinity-1 and IRPrestige-21,<br />
the PC for operating the <strong>FTIR</strong> main unit is also used for operating the AIM-8800.<br />
When connecting to a non-PC-type <strong>FTIR</strong>-8000 <strong>Series</strong>, the PC must be purchased<br />
separately.<br />
2) Contact us for details on parts required for connecting the <strong>FTIR</strong> to the AIM-8800.<br />
300<br />
450<br />
Printer<br />
340<br />
150<br />
Key Board<br />
450<br />
340<br />
PC<br />
CRT<br />
Spectrum of Adhesive on Metal<br />
948<br />
Relative Positioning of IRAffinity-1 and Microscope Monitor<br />
IRAffinity-1 Infrared Microscope System<br />
Adhesive on Metal (measurement of part enclosed in blue in photo on right)<br />
700<br />
mm
ATR Objective Mirror<br />
ATR-8800M (P/N 206-70450-91)<br />
A semicircular prism made of ZnSe is used. x 15 magnification; 30°<br />
incident angle, and single reflection.<br />
The prism is a slide type and permits switching between visual<br />
observation mode and IR measurement mode.<br />
Features<br />
Small prism enables focusing and measurement of even small<br />
samples.<br />
Measurement range of 5,000 to 700 cm-1 Maintenance Parts<br />
Other Optional for Microscope<br />
Description P/N<br />
Remarks<br />
Aluminum reference mirror<br />
KBr window plate<br />
CaF2 window plate<br />
Visible light objective lens (x10)<br />
Visible light objective lens (x20)<br />
Infrared polarizer (Infrared polarizer<br />
and holder are required.)<br />
Visible light polarizer<br />
Sampling Kit (P/N 208-92171)<br />
This kit is for pretreating samples for microscope measurement.<br />
It comprises a set of tweezers, roller knife, needles, scissors,<br />
replacement blades and replacement needles.<br />
Standard Content<br />
Description P/N<br />
Replacement Ge prism<br />
206-70451-91<br />
Tweezers (straight)<br />
Tweezers (curved)<br />
Roller knife<br />
Needle (straight)<br />
Needle (bent)<br />
Needle holder<br />
Scissors<br />
Replacement blades (pack of 5)<br />
Replacement needles (pack of 5)<br />
Exclusive case<br />
206-90104<br />
200-66752-04<br />
200-66752-02<br />
208-92180-01<br />
208-92180-02<br />
206-81524<br />
208-92014<br />
13 mm dia.<br />
13 mm dia. x 2 mm thick<br />
13 mm dia. x 2 mm thick<br />
Manufactured by<br />
Kyowa Optical Co., Ltd.<br />
Infrared polarizer holder<br />
Infrared polarizer (STJ-1001)<br />
Please contact us for details.<br />
Description Quantity<br />
1<br />
1<br />
1<br />
1<br />
1<br />
1<br />
1<br />
1<br />
1<br />
1<br />
ATR-8800M ATR Objective Mirror<br />
Spectrum of Adhesive on Fiber<br />
Sampling Kit<br />
23
24<br />
Micro Sample Measurement<br />
Diamond Cell<br />
This pressurized cell thinly compresses samples with a certain degree<br />
of thickness or minute samples placed on a microscope's stage to<br />
perform transmission measurement as they are. This cell is applicable<br />
to a variety of samples including drugs, rubber and plastic.<br />
Two types of cells are available, Diamond Cell C using an artificial<br />
diamond and Diamond Cell B using a natural diamond.<br />
Notes • Diamonds exhibit slight absorption in the range 3,000 to 1,500 cm -1 .<br />
• Diamonds are hard but brittle and may crack depending on the<br />
sample and method of use.<br />
Diamond Cell C (P/N 208-92236)<br />
A pressurized cell-enabling microscopic measurement of minute, thinly<br />
compressed samples as they are. Applicable for analysis of drugs, rubbers,<br />
plastics, polymers, etc.<br />
The Diamond Cell B noted above employs a natural diamond, and is<br />
therefore relatively expensive. This Diamond Cell, on the other hand, uses<br />
an artificial diamond, so is less expensive and, further, employs a thinner<br />
and larger diameter window (1.6 mm). Although its strength is slightly inferior<br />
to the natural diamond, it is adequate for compressing nearly all samples.<br />
Features<br />
Large-size diamond provides 1.6mm diameter window<br />
Large diameter window allows measurement even when placed in<br />
standard sample compartment<br />
Measurement possible by merely placing on infrared microscope stage<br />
Standard Content<br />
C plate<br />
C screws<br />
Holder with diamond window for C<br />
Case<br />
Hex key wrench<br />
Diamond Cell B (P/N 200-66752)<br />
This attachment is used to compress a micro sample into a thin plate,<br />
which is then directly measured by infrared microscopy.<br />
This method is applicable to various types of samples, such as<br />
pharmaceuticals, rubbers, plastics, and polymers.<br />
Features<br />
Use of the Type II diamond cell allows measurement to be made over<br />
the entire wavenumber range.<br />
Even thick samples can be measured in the transmission mode, with a<br />
high sensitivity.<br />
Micro samples are made flat, so that high sensitivity is obtained during<br />
measurement.<br />
Measurement is made with the diamond cell placed on the stage as it is.<br />
Adjustment for sample thickness is made with a precision screw.<br />
Cells with a cell plate of lower-cost material are also applicable.<br />
Combined use with an infrared microscope is recommended.<br />
Standard Content Options and Supplies<br />
Diamond cell<br />
Holder with compression cap<br />
O ring<br />
Description Quantity<br />
1<br />
3<br />
2<br />
1<br />
1<br />
Description Quantity<br />
1 pair<br />
1<br />
1 set<br />
Diamond Cell C<br />
Spectrum of Single Fiber<br />
Red: Diamond cell used<br />
Black: Diamond cell not used<br />
Options and Maintenance Parts<br />
Description P/N<br />
C plate<br />
208-92172-01<br />
C screws (pack of 3)<br />
208-92172-02<br />
Holder with diamond window for C<br />
208-92236-01<br />
Diamond Cell B<br />
Description P/N<br />
Diamond cell for spare<br />
200-66752-01<br />
CaF2 window, a pair<br />
200-66752-02<br />
KBr window, a pair<br />
200-66752-04
Micro Magnetic Sample Holder<br />
(P/N 208-97206)<br />
This is exclusively used for IR microscopy.<br />
This holder allows samples to be held by a magnetic cover and<br />
loaded by one-touch operation without being dirtied. Samples are<br />
held between magnet sheets and placed on the microscope's stage.<br />
The sample slide is made of stainless steel, and has three holes, 5<br />
mm dia., 13 mm dia. x 1 mm and 13 mm dia. x 2 mm. Samples of<br />
thickness up to 0.5 mm can be held.<br />
Features<br />
Fiber samples are easily loaded.<br />
Applicable to both reflection and transmission measurement<br />
modes.<br />
Provided with a micro scale (10 μm square grid).<br />
Standard Content<br />
Description Quantity<br />
Stainless steel sample slide<br />
1<br />
Magnetic cover (5 mm dia. hole)<br />
1<br />
Magnetic cover (13 mm dia. hole)<br />
1<br />
Magnetic cover (with micro 10 μm scale)<br />
1<br />
Micro Vise Holder (P/N 208-97202)<br />
This holds various types of samples for microscopy. It ensures positive<br />
holding of samples of a difficult shape or measurement of a sample at a<br />
user-selectable angle.<br />
Measurement with a polarizer, with the sample under tensile load,<br />
provides information on the molecular orientation.<br />
Sizes of Holdable Samples<br />
Tensile load Within approx. width of 20 mm<br />
Film of length 14 to 54 mm (excluding grip allowance)<br />
Gripped load Max. approx. length 40 mm<br />
Approx. width 40 mm<br />
Standard Content<br />
Micro vise holder<br />
Holding fixture<br />
Description Quantity<br />
1<br />
2<br />
Magnetic covers<br />
13mm dia. and 5mm dia.<br />
are available for selective<br />
use<br />
Sample slide, made of stainless steel<br />
Silver mirror<br />
Same reflectivity as gold and<br />
harder than gold or aluminm.<br />
Magnetic cover with micro<br />
scale (10 μm square)<br />
Convenient for measurement<br />
and positioning of samples<br />
Hole, 5mm dia.<br />
Micro Vise Holder<br />
Hole, 13mm dia. and<br />
2mm thick<br />
Used for refelctometry<br />
or to accept a diamond<br />
window<br />
Hole, 13mm dia. and<br />
1mm thick<br />
Used for measurement of small samples<br />
Slit for fiber sample<br />
Used for measurement of monofilament<br />
samples, for example<br />
25
26<br />
<strong>Accessories</strong> for Automated Measurement<br />
Automating the Operation<br />
The technique of Fourier Transform Infrared Spectrophotometry (<strong>FTIR</strong>)<br />
is now extensively used in various fields for R&D and industrial<br />
purposes.<br />
Since samples measured by infrared spectrophotometry are mostly<br />
chemically stable and can be measured without pretreatment, it is fairly<br />
easy to automate the measurement of many samples.<br />
Automating the measurement saves labor and ensures high analytical<br />
productivity.<br />
Automating the <strong>FTIR</strong> Measurement<br />
One of the most important methods to automate the operation of the<br />
<strong>FTIR</strong> main is to utilize a computer system.<br />
Combination of a computer and the program, described below, provides<br />
automation of sample loading and unloading, measurement, data<br />
processing, and presentation of the analytical results.<br />
The photo to the right shows the ASC connector (supplied as standard),<br />
which is used to export the control signals to an automatic sample<br />
changer. The software incorporated in the <strong>FTIR</strong> can control the<br />
automatic sample changer via a pair of the ASC connectors.<br />
Operation by Automated Sequence<br />
The operation must be carried out in the sequence programmed to be<br />
most appropriate for the particular type of samples under study.<br />
The <strong>Shimadzu</strong> <strong>FTIR</strong>-8000 <strong>Series</strong> instruments (except <strong>FTIR</strong>-8000PC<br />
<strong>Series</strong>) incorporate, as standard, the SPECTROMACRO software,<br />
which permits flexible programming through simple procedures.<br />
As for the <strong>FTIR</strong>-8000PC <strong>Series</strong>, the optional BASIC software has the<br />
same functions as SPECTROMACRO.<br />
IRPrestige-21, IRAffinity-1 and <strong>FTIR</strong>-8400S (IRsolution model) can be<br />
controlled from the IRsolution software.<br />
ASC Connector
Automatic Diffuse Reflectance Attachment<br />
DRS-8010ASC (P/N 206-62308)<br />
This attachment automates measurement of up to 24 samples.<br />
For details, refer to page 19.<br />
Notes<br />
When this attachment is used on IRAffinity-1, the ASC cable (P/N 206-73433-91) is required.<br />
The BASIC software is required separately for the HYPER-IR model.<br />
Auto Sampler for Transmission Measurement<br />
ASC-8000T (P/N 206-63900)<br />
This attachment accepts up to 18 samples for measurement in the<br />
transmission mode.<br />
Features<br />
The control is made by the standard control signals from the <strong>FTIR</strong><br />
main, meaning no external controller is required.<br />
The attachment is easily installed in the standard sample compartment.<br />
A holder for a 13 mm dia. pellet is provided.<br />
Use of the window-plate option enables measurement in the Nujol method.<br />
Notes<br />
When this attachment is used on IRAffinity-1, the ASC cable (P/N 206-73433-91) is required.<br />
The BASIC software is required separately for the HYPER-IR model.<br />
Standard Content<br />
Description P/N<br />
Quantity<br />
ASC-8000T main<br />
1<br />
Pellet holder<br />
206-63917 20<br />
Fixing spring<br />
206-63951-01 20<br />
Tweezers<br />
Options<br />
1 pair<br />
Description P/N<br />
KRS-Window set (with a set of window holder) 206-66699<br />
Film holder (9 pcs. as a set)<br />
206-81522<br />
For connection with <strong>FTIR</strong> main body,<br />
a cable is required.<br />
Description P/N<br />
Cable for IRAffinity-1<br />
206-73433-91<br />
Sample Switcher 21 (P/N 206-63663-92)<br />
All the <strong>Shimadzu</strong> <strong>FTIR</strong> <strong>Series</strong> spectrophotometers are single-beam type.<br />
This attachment allows any one of them to be operated in the "quasi<br />
double-beam mode" by switching two samples during measurement.<br />
Features<br />
Two cassettes for liquid cells or pellet holders are provided.<br />
In the case of the <strong>FTIR</strong> <strong>Series</strong>, the optional BASIC software is<br />
necessary for the "quasi double-beam mode” (except <strong>FTIR</strong>-8200PC /<br />
8300 / 8400 / 8400S / 8700 / 8900, IRAffinity-1, IRPrestige-21).<br />
<strong>Accessories</strong> That Can Be Used<br />
Evacuable die for KBr pellets<br />
Sealed liquid cell<br />
Magnetic pellet holder<br />
Diamond cell<br />
Sample holder for MHP-1 Mini Hand Press<br />
Fixed thickness cell<br />
Magnetic film holder<br />
10 cm gas cell<br />
<strong>Accessories</strong> That Cannot Be Used<br />
5 cm gas cell<br />
Notes<br />
When this attachment is used on IRAffinity-1, the ASC cable (P/N 206-73433-91) is required.<br />
The BASIC software is required separately for the HYPER-IR model.<br />
DRS-8010ASC<br />
ASC-8000T<br />
Sample Switcher 21<br />
For connection with <strong>FTIR</strong> main body,<br />
a cable is required.<br />
Description P/N<br />
Cable for IRAffinity-1<br />
206-73433-91<br />
27
28<br />
Purge Control Kit<br />
Purge Control Kit<br />
PCK-8000 (P/N 206-62309) for <strong>FTIR</strong>-8100/8200/8600 <strong>Series</strong><br />
PCK-8730 (P/N 206-70170-91) for <strong>FTIR</strong>-8300/8700 <strong>Series</strong><br />
PCK-8940 (P/N 206-71122-91) for <strong>FTIR</strong>-8400/8400S/8900 <strong>Series</strong><br />
PCK-8941 (P/N 206-73512-91) for IRAffinity-1, <strong>FTIR</strong>-8400/8400S/8900 <strong>Series</strong><br />
PCK-21 (P/N 206-72352-91) for IRPrestige-21<br />
The <strong>FTIR</strong> <strong>Series</strong> uses a sealed interferometer to ensure high<br />
sensitivity and stability during measurement without using dry air. To<br />
eliminate the interference of carbon dioxide and water vapor, it is<br />
recommended to purge the interferometer, the sample compartment,<br />
the second sample compartment, etc. through a combined use of the<br />
purge control unit and the dry air supply unit or nitrogen gas.<br />
This kit is for adjusting the piping between the <strong>FTIR</strong> and purge gas<br />
source, piping sections along which purge gas flows and the purge<br />
gas flow rate.<br />
This kit contains the following parts:<br />
Flow path and flow rate controller<br />
Purge tube (10 m, 7 mm I.D., 10 mm O.D.)<br />
Exhaust parts<br />
Notes<br />
The purge control kit cannot be used with the DBX-8000.<br />
Ventilate the site when purging with nitrogen gas.<br />
Dry Air Supply Unit<br />
(P/N 200-64185-01 for 50 Hz line, 100 VAC)<br />
(P/N 200-64185-02 for 60 Hz line, 100 VAC)<br />
This unit is very easy to install: all you have to do is to connect pipes<br />
to the inlet and outlet of the unit. Also, the unit is quite compact and<br />
provided with casters so that it can be easily carried around. The<br />
noise of the air compressor is minimized by the use of soundproofing<br />
materials.<br />
Dimensions: 400W x 610D x 610H Note<br />
mm<br />
Dry air supply capacity: 10 to 20L / min.<br />
Dry air: -17°C or lower in dew point.<br />
PCK-8730
External Detector / Optional Detector<br />
External Detector / Optional Detector<br />
A DLATGS detector or LiTaO3 detector is mounted as standard on<br />
the IRPrestige-21, IRAffinity-1 and <strong>FTIR</strong>-8000 <strong>Series</strong>. Some<br />
applications require use of a high-sensitivity MCT detector or<br />
external installation of a special optical system.<br />
External Light Beam<br />
Switching Kit (P/N 206-70125-92)<br />
This kit extracts infrared light from the right side of the IRPrestige-21,<br />
IRAffinity-1 and <strong>FTIR</strong>-8000 <strong>Series</strong>, and switches the light to<br />
externally installed accessories such as an infrared microscope.<br />
Also attached is a polystyrene film about 50 μm thick so that<br />
instrument validation can be filly automated based upon Japanese<br />
Pharmacopoeia, European Pharmacopoeia or ASTM. Note, however,<br />
that a separate standard sample must be prepared if traceability is<br />
required.<br />
This kit can be used on the <strong>FTIR</strong>-8300/8400/8400S/8700/8900,<br />
IRAffinity-1 and IRPrestige-21.<br />
Standard Content<br />
Description Quantity<br />
Switching mirror (with polystyrene film)<br />
1<br />
External input signal connector<br />
1set<br />
Notes<br />
Traceability is not provided for the polystyrene film.<br />
This kit cannot be used on the<br />
<strong>FTIR</strong>-8100/8100M/8100A/8200/8200D/8200A/8500/8600 and<br />
<strong>FTIR</strong>-8200PC/8600PC.<br />
MCT Kit (P/N 206-72017-91)<br />
A high-sensitivity MCT detector is used when analyzing minute or<br />
dark samples, or performing measurement using a long pathlength<br />
gas cell. This kit is an MCT detector unit installed on the IRPrestige-<br />
21 for switching between the standard DLATGS detector.<br />
Switching of detectors is performed automatically from IRsolution.<br />
It has a built-in liquid nitrogen monitor to cut off current flow when the<br />
detector element is not being cooled, thus protecting the MCT<br />
detector. The liquid nitrogen dewar is made of glass and does not<br />
require reevacuation.<br />
Required Parts<br />
IRPrestige-21<br />
IRAffinity-1<br />
<strong>FTIR</strong>-8000 <strong>Series</strong> 1)<br />
When Using the<br />
MCT Detector<br />
MCT Kit<br />
-<br />
Second sample<br />
compartment<br />
1) Cannot be used on the <strong>FTIR</strong>-8100/8200/8500/8600.<br />
Specifications<br />
Detector<br />
Wavelength range<br />
Liquid nitrogen<br />
retention time<br />
When Using an External<br />
Optical System1<br />
External Light Beam<br />
Switching Kit<br />
External Light Beam<br />
Switching Kit<br />
Second sample<br />
compartment<br />
External Light Flux<br />
Extraction Kit<br />
Exterior and Content of External Light Beam Switching Kit<br />
Liquid nitrogen cooled MCT detector<br />
With glass dewar (approx. 300 ml)<br />
With liquid nitrogen monitor<br />
4,600 to 650 cm -1<br />
8 hours<br />
(when liquid nitrogen is newly purchased)<br />
Notes<br />
This kit cannot be mounted at the same time as the NIR set<br />
(P/N 206-72015-91).<br />
Liquid nitrogen is required when using the MCT detector.<br />
29
30<br />
External Detector/Optional Detector<br />
Second Sample Compartment (with MCT detector)<br />
SSU-8000MCT (P/N 206-62306-01)<br />
(Not applicable to <strong>FTIR</strong>-8101)<br />
If a gas cell, a flow cell, a thermovac evaporation type diffuse<br />
reflectance attachment, or another attachment that is to be installed<br />
externally is mounted to, and removed from, the standard sample<br />
compartment, high analytical productivity cannot be expected. The<br />
second sample compartment is used to accept such an attachment,<br />
so that measurement can be made by only switching the light beam.<br />
This method dramatically enhances analytical productivity.<br />
Also, the second sample compartment is designed to accept a<br />
customer-developed attachment.<br />
Features<br />
The base plate of the <strong>FTIR</strong> main body is removed and the SSU-<br />
8000MCT is installed in that place.<br />
The front panel and the top lid may be separately opened. The<br />
front panel may be removed by one-touch operation.<br />
A part (an acrylic resin plate) of the top lid may be removed.<br />
Equipped with piping for purge gas (dry air or nitrogen).<br />
For the type that accepts both the second compartment and the<br />
infrared microscope, please contact us or your local distributor.<br />
The MCT-8000 detector (supplied as standard) provides extremely<br />
high sensitivity and covers a wavenumber region of 4600 cm-1 to<br />
750 cm-1 .<br />
The glass dewar type MCT detector requires no reevacuation.<br />
The liquid nitrogen monitoring system protects the MCT elements.<br />
Second Sample Compartment<br />
SSU-8000 (P/N 206-62306)<br />
A second sample compartment without MCT detector.<br />
MCT Detector<br />
MCTD-8000 (P/N 206-62307)<br />
A set of a second sample compartment, an MCT detector, a<br />
preamplifier, and a condenser mirror.<br />
(Window)<br />
326<br />
305<br />
460<br />
622<br />
584<br />
Parallel beem, 40mm dia.<br />
214<br />
552<br />
Dimensions of <strong>FTIR</strong>-8000 <strong>Series</strong> and SSU-8000<br />
2-6 x 8 hole depth 5<br />
Window (removable)<br />
6 dia. x 8 H hole depth 5<br />
(Window)<br />
Second Sample Compartment (SSU-8000) External Dimensions<br />
and Base Plate Dimensions<br />
192<br />
M4 depth 5<br />
30<br />
M6 depth 5<br />
M5 depth 5<br />
145<br />
Focus position<br />
2-6 mm dia. pin length 3<br />
Base fastening screw (3 places) Front cover (removable)<br />
Handle<br />
297<br />
408<br />
247<br />
Chassis base plate (not removable)<br />
mm
Transmission Measurement<br />
<strong>Accessories</strong> for Transmission Measurement<br />
Film samples can be measured easily if they are attached to the<br />
standard cassette or optional film holder.<br />
Cassette (Sample Holder) (P/N 206-17384)<br />
A cassette (sample holder) provided as standard on the <strong>FTIR</strong> can be<br />
used for options for attaching to cassettes for liquid and gas cells.<br />
However, with some accessories, there may be clearance between<br />
the cell and the cassette, which sometimes results in poor<br />
attachment reproducibility.<br />
Also, bending sometimes occurs when heavy accessories such as<br />
the 10 cm gas cell are attached. Use this optional cassette when<br />
performing measurement with such accessories with better<br />
reproducibility.<br />
This attachment cannot be used on the <strong>FTIR</strong>-8100/8100M/8100A/<br />
8200/8200D/8200A/8500/8600 and <strong>FTIR</strong>-8200PC/8600PC.<br />
Features<br />
Little clearance<br />
Rigid<br />
Standard Content<br />
Description Quantity<br />
Cassette ASSY<br />
1<br />
Maintenance Parts<br />
Description P/N<br />
Cassette mounting screws<br />
037-02820-18<br />
Magnetic-Type Film Sample Holder<br />
(P/N 200-66754-11)<br />
Film samples are held between the stainless backplate (SUS 430)<br />
and rubber magnet for direct analysis.<br />
Standard Content<br />
Backplate (SUS430)<br />
Magnet sheet without hole<br />
Magnet sheet with 13 mm dia. hole<br />
Magnet sheet with 7 x 13 mm hole<br />
Magnet sheet with 7 x 19 mm hole<br />
Magnet sheet with 10 x 23 mm hole<br />
Description Quantity<br />
1<br />
1<br />
1<br />
1<br />
1<br />
1<br />
Dimensions of Magnetic-Type Film<br />
31
32<br />
Transmission Measurement<br />
Universal Clip Holder (P/N 208-97207)<br />
This holds a sample by one-touch operation through the use of a clip.<br />
A silicone rubber o-ring is used for positive contact and sample<br />
protection.<br />
Features<br />
Applicable sample sizes range from 13 to 40 mm in diameter, and<br />
up to 13 mm thick.<br />
The pressure nut ensures easy measurement of mull samples.<br />
The rubber magnet and o-ring are used for positive holding of<br />
samples.<br />
Standard Content<br />
Universal clip holder<br />
Magnet base, 22 mm dia.<br />
Magnet base, 10 x 14 mm hole<br />
Spare O-ring<br />
Description Quantity<br />
1<br />
EZ-Clip13 (P/N 208-97208)<br />
This one-touch sample holder uses a clip exclusive for 13 mm dia.<br />
samples. An O-ring is located on the surface of the holder that<br />
contacts the sample to prevent damage to the sample.<br />
Features<br />
Thick samples (max. thickness 13 mm) also can be held.<br />
Diameter of light passage hole: 10 mm<br />
Standard Content<br />
Description Quantity<br />
EZ-Clip13<br />
1<br />
EZ-Clip25 (P/N 208-97209)<br />
This one-touch sample holder uses a clip exclusive for 25 mm dia.<br />
samples. An O-ring is located on the surface of the holder that<br />
contacts the sample to prevent damage to the sample.<br />
Features<br />
Thick samples (max. thickness 13 mm) also can be held.<br />
Diameter of light passage hole: 10 mm<br />
Standard Content<br />
Description Quantity<br />
EZ-Clip25<br />
1<br />
1<br />
1<br />
1<br />
Silicone rubber o-ring<br />
Slide stopper<br />
O rings for spare<br />
Universal Clip Holder<br />
Pressure nut<br />
Clip<br />
Two types of magnet base,<br />
22mmø and 10mmø<br />
EZ-Clip13 EZ-Clip25
Transmission Measurement<br />
Gas Cell<br />
Gas cells are used when measuring gas samples. Select the optical<br />
pathlength to suit the concentration of the component.<br />
Short Pathlength Gas Cells<br />
5 cm Gas Cell (P/N 202-32006- )<br />
10 cm Gas Cell (P/N 202-32007- )<br />
Used for measurement of gas samples or liquid samples of low<br />
boiling points. The cells are designed conic to make the inner volume<br />
smaller.<br />
The inner volumes of the 5 cm and 10 cm gas cells are 42mL and<br />
98mL, respectively. The last two digits of the catalog numbers show<br />
the material of the window plate, as listed below.<br />
Cell Window Plates<br />
Type of Window Plate<br />
Last two digits of P/N<br />
Long Pathlength Gas Cell<br />
NaCl<br />
-10<br />
KBr<br />
-20<br />
KRS-5<br />
-30<br />
A gas cell with a long pathlength is used when measuring low<br />
concentration gas samples. Inside a long pathlength gas cell, light<br />
repeatedly doubles back, which results in a long pathlength.<br />
There are two types of long pathlength gas cells, one with a sample<br />
compartment and the other with a second sample compartment. A<br />
regular MCT detector is used as the detector.<br />
The pathlength of long pathlength gas cells, gas cell material,<br />
window plate material, and detector must be selected according to<br />
the gas component, concentration, temperature, capacity, and other<br />
factors to be measured. When selecting a long pathlength gas cell,<br />
contact us so that you can select the appropriate cell.<br />
to detector<br />
Spectrum of HCl Gas<br />
Dimensions of Long Pathlength Gas Cell<br />
Window<br />
Optics of Long Path Cell<br />
Sample inlet / outlet pipe<br />
Pressure<br />
gauge<br />
33
34<br />
Pellet Measurement<br />
KBr Pellet Method<br />
With this method, powder samples are diluted with KBr powder to produce pellets for transmission measurement. On the <strong>FTIR</strong>, the light<br />
intensity is large, so measurement is possible using pellets made easily with the Mini Hand Press. When making regular 13 mm dia. pellets, the<br />
evacuable die for KBr pellets, hydraulic press and vacuum pump are used.<br />
Mini Hand Press<br />
MHP-1 (P/N 200-66747-91)<br />
This is a compact, inexpensive hand-driven press used to produce<br />
KBr pellets.<br />
A pellet produced in the frame is directly measured using the<br />
dedicated holder; this ensures exceptional simplicity of operation.<br />
No dies or vacuum pump are required.<br />
Standard Content<br />
Description P/N Quantity<br />
1 Mini Hand Press<br />
200-66747-01 1<br />
2 Pellet holder<br />
202-35258<br />
1<br />
3<br />
4<br />
Upper and lower cylinder<br />
Briquetting frame, 4 mm dia.<br />
206-73717-91<br />
1 set<br />
10<br />
5 Pellet remover<br />
200-66747-03 1<br />
6 Pellet remover base<br />
200-66747-04 1<br />
* Parts other than Mini Hand Press 1 are provided as maintenance parts. 2,<br />
5 and 6 are shared for 4 and 3 mm dia. parts.<br />
Options and Maintenance Parts<br />
Description P/N<br />
4 mm dia. briquetting frame, 20 pieces<br />
206-73718-91<br />
3 mm dia. briquetting frame, 10 pieces<br />
Upper/lower cylinder set<br />
200-66748<br />
3 mm dia. briquetting frame, 20 pieces<br />
200-66749-01<br />
Evacuable Die for KBr Pellets (P/N 202-32010)<br />
Used to prepare KBr pellets, 13 mm dia. The amount of KBr crystal<br />
necessary for one pellet is about 200 mg and the sample 1 to 2 mg.<br />
Standard Content<br />
Description P/N Quantity<br />
1 Base<br />
202-35247 1<br />
2 Barrel<br />
202-35251 1<br />
3 Spring<br />
202-35252 1<br />
4 Plunger<br />
204-21049 1<br />
5 Mandrel<br />
202-35248* 2<br />
6 Die frame<br />
202-35250* 4<br />
7 Pellet holder<br />
202-35258* 4<br />
8 Punching rod<br />
202-35256 1<br />
9 Punching base<br />
202-35255 1<br />
!0 Plug<br />
202-35257 1<br />
!1 Sieve<br />
202-35261 1<br />
!2 Exhaust port<br />
202-35254 1<br />
* Packet of one when ordering by this P/N.<br />
Supplies<br />
Description P/N<br />
10 briquetting frames, 3 mm dia., and<br />
upper and lower cylinders<br />
200-66748<br />
7<br />
8<br />
9 !0<br />
SSP-10A Hydraulic Press<br />
SA18-3M Vacuum Pump<br />
KBr Crystal<br />
Agate Mortar and Pestle<br />
Micro spatula<br />
6 5<br />
The following items are recommended for producing pellets of high<br />
transmittance:<br />
Description Quantity<br />
!1<br />
4<br />
3<br />
2<br />
1<br />
1<br />
1<br />
100g<br />
1 each<br />
1
Micro Die for 2 mm dia. KBr Pellets<br />
(P/N 202-32011)<br />
Micro Die for 5 mm dia. KBr Pellets<br />
(P/N 202-32012)<br />
Used in combination with the KBr die (P/N 202-32010), which is for 13<br />
mm dia. pellets, to produce smaller pellets, 5 mm or 2 mm in diameter.<br />
Specify the diameter you require or the Cat. No. when placing an order.<br />
Standard Content<br />
Description P/N Quantity<br />
1 Mandrel for 2mm dia. pellets<br />
Mandrel for 5 mm dia. pellets<br />
202-35262<br />
202-35264<br />
2<br />
2 Die frame for 2 mm dia. pellets<br />
Die frame for 5 mm dia. pellets<br />
202-35263<br />
202-35265<br />
4<br />
3 Tool<br />
202-35266 2<br />
4 Pellet holder<br />
202-35258 4<br />
Hydraulic Press<br />
SSP-10A (P/N 200-64175)<br />
Used for producing KBr pellets. The maximum pressure is 10 tf/cm2 .<br />
A high-precision pressure gauge is provided.<br />
Vacuum Pump<br />
SA18-3M (P/N 261-79017)<br />
This is a compact rotary vacuum pump, having a displacement<br />
capacity of 10 to 30 L/min., used for vacuum dehydration in<br />
production of KBr pellets. (100 VAC power is required.)<br />
3<br />
4<br />
2<br />
1<br />
35
36<br />
Pellet Measurement<br />
Magnetic-Type Pellet Holder<br />
(P/N 200-66753-11)<br />
13 mm diameter pellets are held between the stainless backplate<br />
(SUS430) and rubber magnet for direct analysis.<br />
Agate Mortar and Pestle (P/N 200-93508)<br />
Used to prepare KBr pellets or samples for diffuse reflectance<br />
method.<br />
KBr Crystal (100 g) (P/N 202-34141)<br />
Used to prepare KBr pellets. Features a long storage life, thanks to<br />
its low hygroscopicity.
Cells for Liquid Samples<br />
Measurement Using<br />
Demountable Cells<br />
Demountable cells, sealed liquid cells, fixed thickness cells, etc. are<br />
useful for measurement of liquid samples. In quantitative analyses, it<br />
is necessary to know the thickness of the cell accurately.<br />
Interference patterns are often used for the thickness measurement.<br />
In transmission/reflection <strong>FTIR</strong> of thin films, an interference pattern<br />
as shown above is overlaid on the spectrum. The film thickness, t, is<br />
given by the next equation:<br />
M<br />
n= 2√n 2 -sin 2 θ(ν1-ν2)<br />
where ν1 and ν2 are the wavelengths of peaks or valleys, M is the<br />
degree of interference (number of the waves) between ν1 and ν2.<br />
When the refractive index (n) of the film is known and is uniform<br />
between the ν1 and ν2, the cell thickness may be obtained from the<br />
above equation. In practice, the cell is measured without any sample<br />
in it, and its thickness is obtained by substituting n = 1 and θ = 0°.<br />
37
38<br />
Cells for Liquid Samples<br />
Demountable Cell (P/N 202-32000- )<br />
This type of cell is used for qualitative analysis of less volatile liquid<br />
samples, Nujol mulls, or film samples. The cell is assembled and<br />
disassembled in each analysis run.<br />
Type<br />
Contents<br />
Type<br />
Cell Window and Thickness<br />
Thickness<br />
0.025 mm<br />
0.05 mm<br />
0.1 mm<br />
0.2 mm<br />
0.5 mm<br />
1.0 mm<br />
2.0 mm<br />
5.0 mm<br />
P/N<br />
P/N<br />
NaCl<br />
-13<br />
-14<br />
-15<br />
-16<br />
-18<br />
-19<br />
-11<br />
-12<br />
NaCl Demountable Cell<br />
A pair of NaCl plates (201-97942)<br />
Metal holder (201-77662)<br />
0.05 mm lead spacer (204-04900-14)<br />
Sealed Liquid Cell (P/N 202-32001- )<br />
This type of cell is used for measurement of volatile liquid samples.<br />
The cell is assembled sandwiching a spacer of the desired thickness,<br />
a sample is injected into the cell, and then drawn out with a syringe.<br />
When it is necessary to prevent leaks of samples, the use of the<br />
fixed thickness cell is recommended.<br />
Contents<br />
KBr<br />
-23<br />
-24<br />
-25<br />
-26<br />
-28<br />
-29<br />
-21<br />
-22<br />
202-32000-10 202-32000-20 202-32000-30<br />
NaCI Sealed Liquid Cell<br />
A pair of NaCl plates, with and<br />
without hole (201-77160-10)<br />
Metal holder (201-77661)<br />
Gasket (202-35425)<br />
Lead cushion (202-35426)<br />
Rubber cushion (202-35427)<br />
Teflon stopper (201-75546)<br />
Syringe (200-34835)<br />
KRS-5<br />
Not available<br />
-34<br />
-35<br />
-36<br />
-38<br />
-39<br />
-31<br />
-32<br />
1 set.<br />
2 pcs.<br />
2 pcs.<br />
2 pcs.<br />
2 pcs.<br />
1 pc.<br />
KBr Demountable Cell<br />
A pair of KBr plates (201-97977)<br />
KRS-5 Demountable Cell<br />
1set 0.025 mm lead spacer (204-04900-13)<br />
10sheets 0.1 mm lead spacer (204-04900-15)<br />
KBr Sealed Liquid Cell<br />
A pair of KBr plates, with and<br />
without hole (201-77160-20)<br />
0.025 mm lead spacer (204-04901-13)<br />
0.05 mm lead spacer (204-04901-14)<br />
(204-04901-34) for KRS-5<br />
0.1 mm lead spacer (204-04901-15)<br />
(204-04901-35) for KRS-5<br />
0.5 mm lead spacer (204-04901-18)<br />
(204-04901-38) for KRS-5<br />
A pair of KRS-5 plates (201-97943)<br />
202-32001-10 202-32001-20 202-32001-30<br />
KRS-5 Sealed Liquid Cell<br />
10 sheets<br />
10 sheets<br />
A pair of KRS-5 plates, with and<br />
without hole (201-77160-30)<br />
4 sheets<br />
4 sheets<br />
4 sheets<br />
4 sheets<br />
Fixed Thickness Cell (P/N 202-32002- )<br />
This type of cell is used for quantitative measurement of liquid or volatile samples. The cell is assembled in the <strong>Shimadzu</strong> factory to have the<br />
customer-specified cell thickness.<br />
Matched pair of fixed thickness cells are also available.<br />
The last two digits of catalog numbers indicate the type of cell window plates, as shown in the table below:<br />
Example: The catalog number of the fixed thickness cell, 0.1 mm in thickness, KBr window plate, is 202-32002-25
Sample Cell for Oil Content Determination<br />
This cell is used to quantitatively determine the concentration of oils<br />
extracted into carbon tetrachloride.<br />
Type of cell<br />
100 mm quartz cell (P/N 200-34473-02)<br />
50 mm quartz cell (P/N 200-34473-01)<br />
10 mm quartz cell (P/N 201-98716)<br />
KRS-5<br />
Oil content cell holder<br />
Type 1 (P/N 202-39897)<br />
Square cell holder<br />
(P/N 204-51216)<br />
Crystal Polishing Kit (P/N 202-32024)<br />
This kit is used for polishing an NaCl and KBr window plate. The kit<br />
contains a polishing plate, abrasive, chamois and rubber gloves.<br />
39
40<br />
Others<br />
Far Infrared Kit (P/N 206-72016-91)<br />
In the far infrared region up to 240 cm-1, peaks of inorganic<br />
compounds and organometallic complexes are observed. The Far<br />
Infrared Kit is a Csl beam splitter mounted on the IRPrestige-21 for<br />
measuring spectra in the far infrared region. Using the Csl beam<br />
splitter enables spectra in the far infrared region up to 240 cm-1 to be<br />
measured.<br />
A standard light source and detector are used.<br />
Since the 400 cm-1 to 240 cm-1 region absorbs lots of moisture in air,<br />
purge the instrument with desiccated air, for example, before<br />
performing measurement. Also, store the Csl beam splitter in a<br />
desiccator when it is not in use since it is extremely sensitive to<br />
moisture.<br />
Feature<br />
Measurement wavelength range 5000 cm-1 to 240 cm-1 Standard Content<br />
Csl beam splitter<br />
Description Quantity<br />
1<br />
Far Infrared Spectrum of Bismuth Oxide
NIR Measurement<br />
NIR Measurement <strong>Accessories</strong> for<br />
the IRPrestige-21<br />
<strong>Accessories</strong> are available for easier and higher-sensitivity NIR<br />
measurement of a wide range of samples. Each accessory is<br />
equipped with the Automatic Accessory Recognition function.<br />
Introduction to Near-Infrared (NIR) Analysis<br />
In the near IR regions, absorption due to molecular vibration<br />
appears. Therefore, substances can be identified by comparing<br />
spectral patterns, and quantitatively determined from the peak<br />
intensity.<br />
Absorbance is lower in the near IR region than in the mid IR region,<br />
so samples can be measured without dilution. The IRPrestige-21,<br />
which employs the Fourier transform method and offers spectra with<br />
Near-Infrared Applications<br />
Near-Infrared is used for qualitative and quantitative analysis, just as<br />
with the mid-infrared. Its applications include quality inspections of<br />
raw materials received, and endpoint quantitations for reaction<br />
processes.<br />
Applications and <strong>Accessories</strong><br />
Multicomponent Quantitation of Liquid Samples<br />
The quantities of various components in liquid pharmaceuticals and<br />
foods are measured and controlled. For example, quantitation can be<br />
made of the quantities of components such as sugar and proteins<br />
when manufacturing soft drinks. In this case, the location and shape<br />
Acceptance Inspections for Raw Materials (Qualitative)<br />
When determining whether the correct raw materials have been<br />
delivered based on the spectral shape, select accessories in<br />
accordance with the form of the raw materials. After measurement,<br />
pass/fail determinations and library searches can be conducted using<br />
the PharmaReport program (Macro Platform required).<br />
If the sample is a powder, use either diffuse reflection equipment<br />
UpIR A, near-infrared integrating sphere IntegratIR A, or a reflectiontype<br />
fiber probe.<br />
For liquid samples, pastes, pellets, and cloths, use near-infrared<br />
integrating sphere IntegratIR A.<br />
For tablet samples (pharmaceuticals), use either near-infrared<br />
integrating sphere IntegratIR A or a reflection-type fiber probe.<br />
Difference Between UpIR A and IntegratIR A<br />
Diffuse reflection equipment UpIR A and near-infrared integrating<br />
sphere IntegratIR A differ as shown below. The selection should be<br />
made on the basis of the experimental objective.<br />
Benefits of IntegratIR A<br />
1. The peak strength is several times stronger than for UpIR A, and<br />
the obtained spectrum has a superior S/N ratio.<br />
2. Good data is obtained when measuring powdered samples in<br />
plastic bags.<br />
3. Measurements can be conducted of pellets, pastes, tablets, liquids<br />
and cloth samples.<br />
When the accessory is fitted to the sample compartment, the<br />
accessory type and its serial number are recognized automatically<br />
and the optimal measurement parameters are set.<br />
high wavelength precision, is optimal for identifying substances by<br />
comparing spectral patterns. Samples contained in glass or thin<br />
plastic containers can be measured directly. It is also possible to<br />
analyze a sample using a probe. Thus, sample pretreatment is easy,<br />
and the near IR measurement is also suitable for measuring samples<br />
that cannot be easily unpacked.<br />
of each component peak will depend on temperature. Therefore,<br />
measurement is conducted at a constant temperature using a heating<br />
transmission cell system. Here, the IRSolution PLS Quantitation<br />
Program will be required to create the calibration curves.<br />
For diffuse reflection equipment UpIR A and near-infrared integrating<br />
sphere IntegratIR A, the sample is prepared, and the prepared<br />
sample is then placed in the measurement window for measurement.<br />
Measurement can be conducted as is with the sample placed in the<br />
test tube included, or left in a plastic bag. In the latter case, however,<br />
there may be a significant impact from the bag's interference fringe.<br />
If the reflection-type fiber probe is used, measurement is possible<br />
without sampling. The probe can be inserted directly into the sample,<br />
or measurement can be taken directly of a sample placed in a glass<br />
bottle or plastic bag. In the latter case, however, there may be a<br />
significant impact from the bag's interference fringe.<br />
Benefits of UpIR A<br />
1. Cost<br />
2. Specialized for powdered sample analysis.<br />
41
42<br />
NIR Measurement<br />
NIR Set (P/N 206-72015-91)<br />
This option is attached to the IRPrestige-21, enabling near-infrared<br />
measurement. Experiments are conducted via software that switches<br />
between the mid-infrared and the near-infrared. (Cannot be used with<br />
the <strong>FTIR</strong>-8000 series.)<br />
Specifications<br />
Measurement Range: 12,500 cm -1 to 3,800 cm -1<br />
Beam Splitter: Silicon-coated CaF2<br />
Light Source: Tungsten iodine lamp<br />
Detector: InGaAs detector<br />
Measurement range: 10,000 to 3,800 cm-1 Specifications<br />
Accessory recognition function: Included<br />
Standard <strong>Accessories</strong><br />
Product Name P/N<br />
Quantity<br />
UpIR A Main Unit<br />
1<br />
Gold-coated mirror for reference 208-97271-13 1<br />
Test tube (pack of 6)<br />
1<br />
Test tube holder<br />
208-97271-17 1<br />
Sample holder with sapphire window 208-97271-18 1<br />
Measurement range: 10,000 to 3,800 cm-1 Specifications<br />
Accessory recognition function: Included<br />
Standard <strong>Accessories</strong><br />
Product Name P/N<br />
Quantity<br />
IntegratIR A Main Unit<br />
1<br />
Gold diffusion mirror with protective cap 208-97272-12 1<br />
Test tube (pack of 6)<br />
1<br />
Test tube holder<br />
208-97271-17 1<br />
Standard Contents<br />
Beam Splitter Storage Box<br />
CaF2 Beam Splitter<br />
Upload Type Diffuse Reflectance Attachment UpIR A (P/N 208-97271-91)<br />
Powder samples can be placed on the sample stage for measurement.<br />
Pretreatment such as KBr dilution is unnecessary.<br />
Powders can be measured directly. Alternatively, directly set the sample contained in a<br />
plastic bag or glass bottle.<br />
Applications include qualitative or verification tests in acceptance inspections and<br />
quantitative analysis of components contained within samples.<br />
NIR Integrating Sphere IntegratIR A (P/N 208-97272-91)<br />
Pretreatment such as KBr dilution is unnecessary. Samples contained in a plastic bag or<br />
glass bottle can be measured.<br />
Applications include qualitative or verification tests in acceptance inspections and<br />
quantitative analysis of components contained within samples.<br />
Powders, tablets, liquids, pastes, fibers, plastic pellets and molded samples can be placed<br />
on the sample stage for measurement (reflectance measurement).<br />
A highly sensitive InGaAs detector is built-in.<br />
The IntegratIR installation kit (P/N 206-72715-92 for IRPrestige-21 CE model, or<br />
P/N 206-72715-91 for other IRPresige-21 model) must be purchased separately.<br />
Product Name Quantity<br />
Options<br />
Product Name P/N<br />
Test tube with screw cap (pack of 200)<br />
208-97271-20<br />
25 x 2 mm sapphire window<br />
208-97271-21<br />
Options<br />
Spectrum of a tablet (antipyretic)<br />
Product Name P/N<br />
Test tube (pack of 6)<br />
208-97272-14<br />
1<br />
1
NIR Measurement<br />
Fiber Coupler (P/N 206-72751-91)<br />
The fiber coupler comes with two SMA connectors. Various fiber probes with SMA<br />
connectors can therefore be connected.<br />
The fiber coupler and fiber probe are separate items. Please purchase both of them.<br />
Contact <strong>Shimadzu</strong> when using fiber probes other than the recommended probe.<br />
Specifications<br />
Measurement range:<br />
10,000 to 3,800 cm -1<br />
Connector shape:<br />
(However, this varies depending on the probe used.)<br />
2 x SMA<br />
Accessory recognition function: Included<br />
Standard <strong>Accessories</strong><br />
Fiber Coupler<br />
Storage Box<br />
Product Name Quantity<br />
1<br />
1<br />
Reflective Fiber Probe (P/N 206-72760-91)<br />
Near IR rays emitted from the probe head are directed to the sample, and the reflected<br />
light is collected for measurement.<br />
Pretreatment such as KBr dilution is unnecessary.<br />
Just insert the probe into the sample powders, or samples can be analyzed while they<br />
are contained in bags or glass bottles.<br />
Measurement range: 10,000 to 3,800 cm<br />
Connector shape:<br />
Probe shape:<br />
Operating temperature:<br />
Permissible bending radius:<br />
Length:<br />
-1<br />
Specifications<br />
2 x SMA<br />
Probe head 6.4 mm dia. x 50 mm, SUS303<br />
Handle 18 mm dia. x 100 mm, aluminum<br />
Room temperature<br />
100 mm<br />
1 m from the probe head to connector<br />
Standard <strong>Accessories</strong><br />
Fiber Probe<br />
Mini Stand<br />
Reference Mirror<br />
Product Name Quantity<br />
1<br />
1<br />
1<br />
Options<br />
Product Name P/N<br />
Gold Diffusion Mirror<br />
208-97272-12<br />
Gold-coated Mirror<br />
208-97271-13<br />
Flexible Stand<br />
046-05514-01<br />
Mini Stand<br />
046-05514-02<br />
Options<br />
Product Name P/N<br />
Fiber cable for adjustment<br />
206-72758-91<br />
Black: L-Ala<br />
Blue: L-Arg<br />
Red: L-(Cys)2<br />
Spectra of drugs contained in a glass bottle<br />
43
44<br />
NIR Measurement<br />
Heating Transmission Cell<br />
Liquid samples contained in the 6-mm diameter test tube can be measured while they are<br />
being heated, or maintained at a constant temperature.<br />
Applications include multi-component quantitative analysis of liquid samples and tracing<br />
reactions and changes in the sample under heating.<br />
The temperature can be set from room temperature to 120°C.<br />
The set comprises a transmission cell for measurement under heating and a temperature controller.<br />
Measurement range:<br />
12,500 to 3,800 cm<br />
Accessory recognition function:<br />
Temperature range:<br />
Applicable test tube:<br />
Output:<br />
Power supply:<br />
-1<br />
Specifications<br />
Included<br />
Room temperature to 120°C (heater temperature)<br />
6 mm dia. x 50 mm<br />
5A Max.<br />
120/220 V selectable<br />
Results of measuring<br />
octanoic acid under<br />
heating (measured at<br />
Standard <strong>Accessories</strong><br />
10°C intervals from 30<br />
Product Name P/N<br />
Quantity to 120°C).<br />
Heating Transmission Cell Holder 208-97273-92 1<br />
Increase in liberated<br />
Temperature Controller<br />
208-97274-92 1<br />
OH (6,920 cm<br />
6 x 50 mm test tube (pack of 500)<br />
1<br />
-1 )<br />
caused by heating can<br />
be verified.<br />
Measurement range (Note) : 10,000 to 3,800 cm-1 Specifications<br />
Equipped with an electrically powered aperture and stage<br />
PC control (measurement position memory function/ auto-centering/<br />
auto focus etc). Can also be operated from the keyboard<br />
Note) If combined with an IRPrestige-21 unit with the NIR set installed.<br />
Options<br />
Product Name P/N<br />
IRsolution Mapping Program<br />
206-72332-91<br />
Options<br />
Infrared Microscope AIM-8800 (P/N 206-72500-92/96/34/35)<br />
NIR measurements of microscopic parts of the sample can be made.<br />
By fitting the AIM-8800 to an IRPrestige-21 unit with the NIR set installed and using the highsensitivity<br />
MCT detector, measurements can be conducted in the 10,000 to 3,800 cm-1 region.<br />
In order to use this accessory, the Light Beam Switching Kit (206-70125-92), AIM<br />
Connection Kit (206-72019-92) and Video Capture Board (088-50648-01) are required<br />
separately. The AIM-8800 will not work with notebook PCs.<br />
Product Name P/N<br />
6 x 50 mm test tube (pack of 500)<br />
208-97273-11<br />
50<br />
%T<br />
25<br />
Reflection spectrum of an<br />
electronic part.<br />
The thickness of the coating film<br />
was calculated to be 2.28 μm<br />
from the interference fringe.<br />
(refractive index 1.5)<br />
10000 9000 8000 7000 6000 5000 4000<br />
1/cm
Optional Software<br />
Wide Variety of Optional Programs<br />
A variety of optional software is available for IRsolution, the Windows-based IRPrestige-21 control software that offers outstanding ease-ofoperation<br />
and functionality. IRsolution features standard functionality that includes data processing functions, such as subtraction spectra and<br />
Kubelka-Munk transform functions, quantitative analysis functions, such as multi-point calibration curve and multi-regression methods, and<br />
spectral search functions. Adding optional software programs allows extending the range of applications even further.<br />
IRsolution Agent (P/N 206-21600-92)<br />
IRsolution Agent is a tool for managing data from IRsolution results in a<br />
database. This allows managing analytical data records over their entire<br />
life cycle, from creation (measurement), review, approval, storage,<br />
viewing, backup, and disposal.<br />
Compliant with FDA 21 CFR Part 11 (electronic records and electronic<br />
signatures), this program provides security management and electronic<br />
signature functions for data stored and recorded in a database.<br />
Measurement data is automatically saved in a database to allow easy<br />
searching of target data at a later time.<br />
Spectral waveform data, peak detection tables, and other information<br />
stored in the database can be view directly.<br />
Mapping Program (P/N 206-73738-91)<br />
The mapping program captures microscope images and synthesizes them<br />
to create a visual image for large areas. It allows specifying the range,<br />
measurement interval, background position, and other mapping<br />
parameters on the synthesized image. Icons are provided for switching<br />
between transmittance and reflectance modes, and other microscope and<br />
mapping operations. Mapping modes include area mapping, linear<br />
mapping, and random mapping (a feature that automatically maps<br />
multiple desired measurement points specified in advance). In addition to<br />
normal mapping using transmittance or reflectance modes, microscope<br />
ATR mapping measurement is possible (ATR object mirror is optional).<br />
From the mapping data obtained, spectra can be extracted and functional<br />
group maps can be calculated for specific peaks.<br />
Data can be rendered in 3D, with contour lines,<br />
or as an overlay of spectra.<br />
Measurement Example of Area Mapping<br />
(area map of flux on a circuit board)<br />
Note:<br />
Not compatible with data measured or analyzed using the mapping program.<br />
45
46<br />
Optional Software<br />
Macro Platform (P/N 206-72330-91)<br />
Macro Platform is a module to run Macro programs provided by <strong>Shimadzu</strong> on IRsolution software. Please contact your <strong>Shimadzu</strong> representative<br />
when you need an automatic measurement system with an automatic sample changer or to perform routine operation with repeated specified<br />
operations.<br />
3D Display Program (P/N 206-73737-91)<br />
The 3D display program offers the following functionality.<br />
Changes the method of displaying dataData can be displayed in bird’s<br />
eye view (3D), as an intensity distribution or using contour lines, as a<br />
spectral overlay, or rotated.<br />
3D data processingChanges at specific wavenumbers can be isolated.<br />
Functions include data extraction, data points thinning, smoothing,<br />
zero-baseline, background correction, normalization, log conversion,<br />
first- or second-order derivative, and ATR correction.<br />
Creation of 3D data from spectraSpectra measured at fixed intervals,<br />
such as by repeated measurements, can be arranged consecutively to<br />
create 3D data.<br />
Note:<br />
The 3D display program cannot control mapping measurements or AIM-8800<br />
series infrared microscopes.<br />
PLS Quantitation Software (P/N 206-72331-91)<br />
PLS (Partial Least Squares) quantitation is a widely used<br />
Chemometrics method like the Multiple Linear Regression (MLR)<br />
method for quantitation of multicomponents.IRsolution has PLS I and<br />
PLS II methods for PLS quantitation. IRsolution analyzes PLS<br />
calibration curves by calculating "Influence", "Residuals", "Scores",<br />
"Loadings", "Press Values", etc.<br />
Curvefitting (Peak split) Software (P/N 206-72333-91)<br />
Usually, an IR band can consist of several overlapping peaks. Curvefitting<br />
(Peak split) software separates IR bands into individual component peaks.<br />
This software is good for many applications, such as analysis of a peak<br />
with hydrogen bond influences and analysis of hidden peaks overlapped<br />
with other peaks.Curvefitting (Peak split) software separates the band<br />
with suitable curves from 6 types of curves such as Gaussian, Lorentian,<br />
Gaussian+Lorentian. Component peaks and a synthesized peak are<br />
displayed to evaluate the separation.<br />
Curvefitting (Peak split) result of peak (3150-2750 cm -1 ) of ABS resin spectrum.<br />
Top : Target peak and specified peaks<br />
Bottom : Component peaks and a synthesized peak<br />
Screen of<br />
PLS quantitation
Materials for Cell Window Plate<br />
2. Materials for Cell Window Plate<br />
Sample cells have a window made of various materials to meet the requirements of your analyses, such as wavenumber range and physical and<br />
chemical characteristics of the sample.<br />
The characteristics and features of the materials popularly used for the window of sample cells are described below. Some of the materials are used<br />
only rarely due to the difficulty of processing and high costs.<br />
Materials of Sample Cell Windows<br />
KBr<br />
NaCl<br />
KCl<br />
Csl<br />
MateriaI<br />
KRS-5(TIBr+Tll)<br />
KRS-6(TIBr+TICI)<br />
AgCl<br />
AgBr<br />
ZnS(Irtran-2)<br />
ZnSe(Irtran-4)<br />
As2Se3<br />
BaF2<br />
CaF2(Irtran-3)<br />
CdTe(Irtran-6)<br />
Si<br />
Ge<br />
Diamond,type<br />
SiO2(Fused Silica)<br />
Wavenumber<br />
range,<br />
cm -1 (μm)<br />
40,000~340<br />
(0.25~29.4)<br />
50,000~600<br />
(0.2~16.6)<br />
40,000~500<br />
(0.25~20.2)<br />
33,000~200<br />
(0.3~50.0)<br />
16,600~250<br />
(0.6~40.0)<br />
20,000~330<br />
(0.5~30.0)<br />
25,000~450<br />
(0.4~22.2)<br />
22,000~300<br />
(0.45~33.3)<br />
10,000~550<br />
(1.0~13.3)<br />
10,000~550<br />
(1.0~18.1)<br />
10,000~600<br />
(1.0~16.6)<br />
50,000~770<br />
(0.2~12.9)<br />
50,000~1,100<br />
(0.2~9.9)<br />
20,000~320<br />
(0.5~31.2)<br />
8,000~660<br />
(1.25~15.1)<br />
5,500~660<br />
(1.8~16.6)<br />
40,000~12.5<br />
(0.25~800)<br />
50,000~2,500<br />
(0.20~4.0)<br />
Refractive<br />
index<br />
(1000cm -1 )<br />
1.52<br />
1.49<br />
1.46<br />
1.74<br />
2.37<br />
2.17<br />
1.98<br />
2.2<br />
2.2<br />
2.4<br />
2.6<br />
1.42<br />
1.39<br />
(2000cm-1 )<br />
2.69<br />
3.4<br />
4.0<br />
2.38<br />
1.42<br />
(3000cm-1 )<br />
Water solubility<br />
at 20˚C<br />
(g/100 g H2O)<br />
% transmission<br />
(thickness)<br />
90%<br />
(5mm)<br />
90%<br />
(5mm)<br />
90%<br />
(10mm)<br />
90%<br />
(5mm)<br />
70%<br />
(2mm)<br />
75%<br />
(1.5mm)<br />
80%<br />
(5mm)<br />
Max.Temp.<br />
(Melting point)<br />
%Transmission values given are typical ones, in the wavenumber range applicable to the respective materials, including the loss due to surface reflection.<br />
65<br />
36<br />
34<br />
44(0°C)<br />
0.05<br />
0.32<br />
1.5 x10 -4<br />
12 x10 -6<br />
Insoluble<br />
Insoluble<br />
Insoluble<br />
0.004<br />
Insoluble<br />
Insoluble<br />
Insoluble<br />
Insoluble<br />
Insoluble<br />
Insoluble<br />
—<br />
70%<br />
(1mm)<br />
65%<br />
(1mm)<br />
60%<br />
(0.63mm)<br />
90%<br />
(1mm)<br />
95%<br />
(3.6mm)<br />
40%<br />
(5mm)<br />
55%<br />
(2.5mm)<br />
50%<br />
(2mm)<br />
70%<br />
(1mm)<br />
85%<br />
(1mm)<br />
300<br />
(700)<br />
400<br />
(801)<br />
(776)<br />
200<br />
(621)<br />
200<br />
(414)<br />
(423)<br />
(457)<br />
200<br />
300<br />
(1180 Sublimate)<br />
350<br />
(1700)<br />
180<br />
(Softening poinit)<br />
500<br />
(1280)<br />
900<br />
(1402)<br />
300<br />
(1041)<br />
300<br />
(1420)<br />
270<br />
(936)<br />
(400)<br />
1710<br />
Softens<br />
Knoop hardness<br />
7.0<br />
18.2<br />
9.3<br />
—<br />
40.2<br />
29.9<br />
—<br />
—<br />
354<br />
250<br />
—<br />
82(500g)<br />
158(500g)<br />
43.5<br />
Vickers hardness<br />
1150<br />
—<br />
10<br />
Mohs scale<br />
500<br />
47
48<br />
Materials for Cell Window Plate<br />
Characteristics of Cell Window Materials<br />
Only the main characteristics of the cell window materials are<br />
described below.<br />
The "Clean-up" lists present only the representative solvents used<br />
to wash the cell windows. Even if a solvent is listed as "Clean-up",<br />
confirm that the solvent does not react with the samples.<br />
The "Harm" solvents can destroy the window plate through<br />
corrosion or dissolving.<br />
Some solvents not listed as "Harm" can be harmful to the material.<br />
KBr<br />
"Clean-up": chloroform, carbon tetrachloride.<br />
(Potassium bromide)<br />
Low cost and wide wavenumber<br />
"Harm":<br />
range.<br />
• Aqueous solution.<br />
Easy to process with alcohol<br />
Lower alcohol.<br />
anhydride.<br />
Most popularly used.<br />
High mechanical strength.<br />
Store under humidity conditions lower than 50%.<br />
Some solvents not listed as "Harm" can be harmful to the<br />
material.<br />
NaCl<br />
(Sodium chloride)<br />
Most inexpensive.<br />
Wide wavenumber range.<br />
Store under humidity conditions<br />
lower than 50%.<br />
KCI<br />
(Potassium chloride)<br />
Similar characteristics as NaCl<br />
and KBr.<br />
Not popularly used.<br />
Csl<br />
(Cesium iodide)<br />
"Clean-up": chloroform, carbon tetrachloride.<br />
"Harm":<br />
• Aqueous solution.<br />
Lower alcohol.<br />
"Clean-up": chloroform, carbon tetrachloride.<br />
Soft and hence liable to injure.<br />
"Harm":<br />
Applicable to analysis in<br />
• Aqueous solution.<br />
far-infrared region.<br />
Lower alcohol.<br />
Highly deliquescent.<br />
Store under humidity conditions lower than 40%, and handle<br />
with care.<br />
KRS-5<br />
(Thallium bromide-iodide)<br />
Wide wavenumber range.<br />
High refractive index.<br />
Most widely used for ATR prisms.<br />
Almost insoluble in water.<br />
Toxic; must be processed at an<br />
authorized manufacturer's site.<br />
KRS-6<br />
(Thallium Bromide-Iodide)<br />
Similar characteristics as KRS-5.<br />
Not so popular as KRS-5.<br />
AgCI<br />
(Silver chloride)<br />
Almost insoluble in water.<br />
Darkens when hit by<br />
ultraviolet rays.<br />
Corrodes metals other than<br />
stainless steel.<br />
Fragile.<br />
AgBr<br />
(Silver bromide)<br />
Similar characteristics as AgCl.<br />
ZnS<br />
(Zinc sulfide)<br />
"Clean-up": chloroform, carbon<br />
tetrachloride, xylene.<br />
"Harm":<br />
• Lower alcohol.<br />
Ammonium salt solution,<br />
sulfuric acid, ammonia,<br />
EDTA, a solution of a<br />
compound that reacts with<br />
thallium to form a complex.<br />
"Clean-up": xylene, methanol.<br />
"Harm":<br />
• A solution of a compound<br />
that reacts with thallium to<br />
form a complex.<br />
"Clean-up": acetone, CH2Cl2.<br />
"Harm":<br />
• Ammonia salt solution,<br />
EDTA, a solution of a<br />
compound that reacts with<br />
silver to form a complex.<br />
"Clean-up": with acetone, CH2Cl2.<br />
"Harm":<br />
• Ammonia salt solution,<br />
EDTA, a solution of a<br />
compound that reacts with<br />
silver to form a complex.<br />
"Clean-up": acetone, alcohol.<br />
Non-water soluble.<br />
"Harm":<br />
Resistant against mechanical • Acidic solution.<br />
and thermal shocks.<br />
High refractive index.<br />
Effectively used for evaporation depositing.<br />
Pulverized and briquetted ZnS is called lrtran-2
ZnSe<br />
(Zinc selenide)<br />
"Clean-up": acetone, H2O.<br />
Non-water soluble.<br />
"Harm":<br />
Resistant against weakly acidic<br />
• Strongly acidic or<br />
or alkaline solution.<br />
alkaline solution.<br />
High refractive index.<br />
Used for ATR prisms.<br />
Pulverized and briquetted ZnSe is called lrtran-4.<br />
Applicable pH range: 6.5-9.5<br />
As2Se3<br />
(Arsenic tri-selenide)<br />
Insoluble in water.<br />
Brittle.<br />
BaF2<br />
(Barium fluoride)<br />
Soluble in acidic solution and<br />
ammonia.<br />
Usable up to 500°C.<br />
Almost insoluble in water.<br />
CaF2<br />
(Calcium fluoride)<br />
"Clean-up": acetone, H2O.<br />
Soluble in ammonium salt solution.<br />
"Harm":<br />
Resistant against acidic or<br />
• Ammonium salt<br />
alkaline solution.<br />
solution, acidic<br />
solution.<br />
Hard, high mechanical strength.<br />
Suitable for high-pressure cell.<br />
CaF2 that occurs in nature is called fluorite.<br />
CaF2 which is pulverized and briquetted is called lrtran-3.<br />
CdTe<br />
(Cadmium telluride)<br />
"Clean-up": acetone, H2O.<br />
"Clean-up": acetone, H2O.<br />
"Harm":<br />
• Ammonium salt<br />
solution, acidic<br />
solution.<br />
"CIean-up": acetone, alcohol.<br />
Material for mercury cadmium<br />
"Harm":<br />
telluride (MCT) detector.<br />
• Acidic solution.<br />
Expensive.<br />
Used for cell window only in<br />
special cases.<br />
CdTe which is pulverized and briquetted is<br />
called Irtran-6.<br />
Si<br />
(Silicon)<br />
Ge<br />
(Germanium)<br />
SiO2<br />
(Fused silica)<br />
"Clean-up": toluene, H2O.<br />
Widely used as the material<br />
"Harm":<br />
for semiconductors.<br />
• Hot sulfuric acid.<br />
Easily processed to<br />
be lenses.<br />
High refractive index, suitable as the material for ATR<br />
prism used in analysis of highly refractive samples.<br />
Non-watersoluble.<br />
Diamond Type II<br />
(Diamond)<br />
"Clean-up": acetone, H2O.<br />
Widely used as the material<br />
"Harm":<br />
for semiconductors.<br />
• HF-NO3 mixture.<br />
Rarely used as cell window<br />
material.<br />
Ge can substitute Si as cell window material.<br />
"CIean-up": ethanol, acetone.<br />
Harder than any other material.<br />
Applicable to wavelength range from ultraviolet to far<br />
infrared, though a gradual absorption is seen in the<br />
range from 3000cm-1 to 1500cm-1. Natural diamond is classified as Type I and Type II, and<br />
only the Type II is used as the material for cell window.<br />
Extremely expensive.<br />
Recommended for the window of high-pressure cell.<br />
"CIean-up": ethanol, acetone.<br />
Effective for analysis in the ultraviolet and<br />
visible regions.<br />
Though useful up to 4 nm in the lR region, this material<br />
ensures high stability and is easy to process.<br />
49
50<br />
Materials for Cell Window Plate<br />
Transmittance Characteristics of Representative Cell Window Materials<br />
Transmittance (%)<br />
Transmittance (%)<br />
Wavenumber (cm -1 )<br />
Transmittance of Alkali Halide Pellet (1mm thick)<br />
Wavenumber (cm -1)
Usable Wavenumber Range for Various Solvents<br />
Carbon disulfide<br />
(0.1mm)<br />
Carbon<br />
tetrachloride<br />
(0.1mm)<br />
Chloroform<br />
(0.1mm)<br />
Dichloroethane<br />
(0.1mm)<br />
Ethylene<br />
tetrachloride<br />
(0.1mm)<br />
Wavenumber (cm -1)<br />
51
JQA-0376<br />
Founded in 1875, <strong>Shimadzu</strong> Corporation, a leader in the<br />
development of advanced technologies, has a distinguished<br />
history of innovation built on the foundation of contributing to<br />
society through science and technology. We maintain a global<br />
network of sales, service, technical support and applications<br />
centers on six continents, and have established long-term<br />
relationships with a host of highly trained distributors located<br />
in over 100 countries. For information about <strong>Shimadzu</strong>, and to<br />
contact your local office, please visit our Web site at<br />
www.shimadzu.com<br />
SHIMADZU CORPORATION. International Marketing Division<br />
3. Kanda-Nishikicho 1-chome, Chiyoda-ku, Tokyo 101-8448, Japan<br />
Phone: 81(3)3219-5641 Fax. 81(3)3219-5710<br />
URL http://www.shimadzu.com<br />
Printed in Japan 3295-03001-30ANS<br />
The contents of this brochure are subject to change without notice.