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IGCP Board; 10th session; Report of the ... - unesdoc - Unesco

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to inorganic environments and biological activities.<br />

The Project was sponsored originally by<br />

<strong>the</strong> IAGOD Commission on Manganese and presently<br />

is conducted with its full cooperation.<br />

Summary <strong>of</strong> activities. The major activity in<br />

<strong>the</strong> field <strong>of</strong> publication is <strong>the</strong> 3-volume treatise<br />

on Geology and Geochemistry <strong>of</strong> Manganese,<br />

totalling 1, 333 pages and including 14 papers in<br />

Volume 1 (General Problems: Mineralogy,<br />

Geochemistry and Methods), 22 papers in Volume<br />

2 (Manganese Deposits on Continents), and<br />

15 papers in Volume 3 (Manganese on <strong>the</strong> Bottom<br />

<strong>of</strong> Recent Basins). The volumes were edited<br />

by I.M. Varentsov and Gyula Grasselly and<br />

were published by Akademiai Kiado, Budapest.<br />

A comprehensive book on 'Manganese Deposits'<br />

has been published by S. Roy in 1981 through<br />

Academic Press Inc. (London-New York). This<br />

book contains a detailed treatment on <strong>the</strong> characterization<br />

and genesis <strong>of</strong> manganese ore deposits<br />

on <strong>the</strong> floors <strong>of</strong> present-day basins as well as on<br />

<strong>the</strong> continents. A third book entitled 'Underwater<br />

Minerals' containing a detailed discussion<br />

and syn<strong>the</strong>sis on <strong>the</strong> manganese deposits in modern<br />

basins has been published through Academic<br />

Press Inc. (Londo-New York) by D.S. Cronan<br />

in 1980. Besides <strong>the</strong>se books, numerous<br />

papers have been published during <strong>the</strong> period<br />

under review by <strong>the</strong> participants <strong>of</strong> this Project.<br />

Substantial progress has been made in studies<br />

on <strong>the</strong> manganese deposits on <strong>the</strong> continents.<br />

Continuous detailed study is in progress on <strong>the</strong><br />

super large manganese deposits <strong>of</strong> <strong>the</strong> USSR and<br />

two technical <strong>session</strong>s, one at Nikopol and <strong>the</strong><br />

o<strong>the</strong>r at Chiatura were organized and <strong>the</strong> proceedings<br />

published. The manganese mineralogy<br />

<strong>of</strong> <strong>the</strong> polymetallic deposit <strong>of</strong> Primorye, USSR<br />

has been established. The manganese deposit<br />

at Groóte Eylandt, Australia has been investigated<br />

in detail and evidence <strong>of</strong> a biogeochemical<br />

origin has been suggested. Stratiform manganese<br />

deposits in <strong>the</strong> Palapye Group, Central-<br />

Eastern Botswana have been studied and a chemical<br />

sedimentary origin has been suggested for<br />

<strong>the</strong>m. Trace-element geochemistry <strong>of</strong> <strong>the</strong> manganese<br />

deposits <strong>of</strong> Israel and Sinai and <strong>of</strong> San<br />

Francisco Mine, Jalisco, Mexico has been completed.<br />

In India, detailed studies on <strong>the</strong> mineralogical<br />

and geochemical changes in manganese<br />

ore deposits due to dynamo<strong>the</strong>rmal metamorphism<br />

are being carried out. The deposits undertaken<br />

for such studies are those <strong>of</strong> Sausar Group,<br />

Aravalli Supergroup, and Khondalite Group where<br />

<strong>the</strong> grade <strong>of</strong> metamorphism ranges from<br />

greenschist to granulite facie. In addition, <strong>the</strong><br />

unmetamorphosed Mn-oxide deposits <strong>of</strong> <strong>the</strong> Proterozoic<br />

Pengagnga beds are being studied in<br />

detail.<br />

At <strong>the</strong> University <strong>of</strong> Bern, Pr<strong>of</strong>. Giovanoli and<br />

his group undertook experiments with syn<strong>the</strong>tic<br />

buserite and applied dodecylammonium chloride<br />

to all types <strong>of</strong> syn<strong>the</strong>tic and natural buserites.<br />

The results show that Na-buserites react properly,<br />

Ca-buserite and Na-birnessite do not<br />

36<br />

yield 100 % and buserites with saturated transition<br />

metal contents do not react at all. No natural<br />

samples could be expanded by dodecylammonium<br />

chloride. Syn<strong>the</strong>sis and investigation <strong>of</strong> psilomelane,<br />

hollandite, cryptomelane, etc. have been<br />

done. Pr<strong>of</strong>essor Stumm and his coworkers at<br />

<strong>the</strong> Zurich Polytechnic studied <strong>the</strong> surface properties<br />

and colloid chemistry <strong>of</strong> manganese oxides<br />

and found that Metallogenium manganooxydans<br />

acts as a powerful oxidizing catalyst producing<br />

always Z-disordered mangana te.- At <strong>the</strong> Hokkaido<br />

University, Japan, studies have been done on<br />

hydrogen isotopic composition <strong>of</strong> hydrated manganese<br />

minerals. O<strong>the</strong>r laboratory investigations<br />

at various centres include cation absorption by<br />

hydrous MnC>2, structural modification <strong>of</strong> Mn (IV)<br />

oxides, nature <strong>of</strong> bixbyite, braunite I and braunite<br />

II, characterization <strong>of</strong> different manganese silicates<br />

such as Mn-pyroxenes, Mn-pyroxenoids,<br />

winchite etc.<br />

Important contributions have been made to manganese<br />

deposits in present-day basins. Hydro<strong>the</strong>rmally<br />

active areas <strong>of</strong> manganese deposition on<br />

Mid-Atlantic Ridge at 26° N, Carlsberg Ridge<br />

(Indian Ocean), East Pacific Rise, and o<strong>the</strong>r<br />

areas have been undertaken and substantial new<br />

data have been generated. A joint New Zealand<br />

Océanographie Institute /Imperial College, UK<br />

cruise investigated hydro<strong>the</strong>rmal deposits in <strong>the</strong><br />

south-westernPacific Ocean and <strong>the</strong> first collection<br />

<strong>of</strong> submarine hydro<strong>the</strong>rmal manganese deposit<br />

from an island arc setting was made. The<br />

partition geochemistry <strong>of</strong> sediments from <strong>the</strong> Galapagos<br />

Hydro<strong>the</strong>rmal Mounds Field has been established.<br />

Detailed field and laboratory work on <strong>the</strong><br />

mode <strong>of</strong> occurrence, physical characterization,<br />

mineralogy, and geochemical partitioning in coexisting<br />

phases in manganese and ferromanganese<br />

nodules from Central Pacific, North-east Equatorial<br />

Pacific, South-west Pacific and Indian<br />

Ocean helped considerably in unravelling <strong>the</strong> mystery<br />

<strong>of</strong> manganese nodule growth in <strong>the</strong> oceans.<br />

The papers embodying <strong>the</strong>se numerous investigations<br />

are cited in <strong>the</strong> reference list. Among <strong>the</strong><br />

active groups participating in this Project on this<br />

aspect are <strong>the</strong> Marine Geochemistry Group <strong>of</strong><br />

<strong>the</strong> Federal Institute <strong>of</strong> Geosciences and Natural<br />

Resources, Hanover, Universities <strong>of</strong> Clausthal<br />

and Aachen (FRG), Imperial College <strong>of</strong> Science<br />

and Technology (UK), New Zealand Océanographie<br />

Institute, and NOAA, University <strong>of</strong> Washington<br />

at Pullman (USA).<br />

Activities planned. It is proposed to continue all<br />

<strong>the</strong> ongoing programmes under this Project during<br />

1982, A symposium on Manganese Deposits is<br />

scheduled under <strong>the</strong> joint auspices <strong>of</strong> <strong>the</strong> IAGOD<br />

Commission on Manganese and <strong>the</strong> <strong>IGCP</strong> Project<br />

111 during <strong>the</strong> Vlth IAGOD Symposium scheduled<br />

at Tbilisi, USSR in 1982. Already more than<br />

forty abstracts have been received for this technical<br />

<strong>session</strong>. A business meeting <strong>of</strong> <strong>the</strong> Project<br />

also is scheduled during <strong>the</strong> symposium where<br />

<strong>the</strong> progress and future plans <strong>of</strong> <strong>the</strong> Project will<br />

be discussed.

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