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Vol 33 No 4 Text - International Ozone Association

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Lake Lanier Islands, Site of Next IOA PAG Conference<br />

Prof. Somiya Retires. Prof. Tsuno becomes JOA President<br />

OZONE NEWS <strong>Vol</strong>ume <strong>33</strong>, <strong>No</strong>. 4 • August, 2005


<strong>Ozone</strong> News <strong>Vol</strong>ume <strong>33</strong>, <strong>No</strong>. 4<br />

OZONE NEWS<br />

<strong>Vol</strong>ume <strong>33</strong>, <strong>No</strong>. 4 August, 2005<br />

Editor: Barry L. Loeb<br />

<strong>Ozone</strong> News (ISSN 1065-5905) is a bimonthly publication of the<br />

<strong>International</strong> <strong>Ozone</strong> <strong>Association</strong> (IOA). Annual Subscription Rate<br />

$150.00. For editorial and advertising information, please contact:<br />

<strong>International</strong> <strong>Ozone</strong> <strong>Association</strong>/Editorial Office<br />

7534 Squirrel Creek Drive<br />

Cincinnati, Ohio 45247-3611<br />

Tel./ Fax: (1) 513.385.3906<br />

Email: blloeb@fuse.net<br />

Membership and Publication Information:<br />

The <strong>International</strong> <strong>Ozone</strong> <strong>Association</strong> is a nonprofit educational and<br />

scientific organization dedicated to the collection and dissemination of<br />

information on, and to promote research in, any and all aspects of ozone<br />

and related oxygen species technologies. Membership is open to any<br />

individual, corporation, or organization having interest in the latest<br />

developments and advancements in ozone technology.<br />

As a member of the IOA, you will receive bimonthly issues of the <strong>Ozone</strong><br />

News newsletter, bimonthly issues of the technical journal <strong>Ozone</strong>: Science<br />

& Engineering (OS&E), a listing and copy of Who's Who in <strong>Ozone</strong>, and<br />

IOA's Publication Catalog which includes worldwide conference<br />

proceedings, monographs, and special reprints. In addition, members<br />

receive discounts on IOA worldwide publications and meetings.<br />

Website: www.io3a.org<br />

For membership and publication information, please contact the IOA<br />

office nearest you:<br />

Pan American Group (PAG)<br />

Mr.Ron Caron, Office Manager<br />

<strong>International</strong> <strong>Ozone</strong> <strong>Association</strong>, Pan American Group<br />

PO Box 8761, Scottsdale, AZ 85252<br />

Tel: (1)480-529-3787<br />

Fax: (1)480-361-7725<br />

Email: info@io3a.org<br />

European-African-Asian-Australasian Group (EA3G)<br />

Mr. Alain Lasalmonie, SecretaryTreasurer<br />

<strong>Association</strong> <strong>International</strong>e de l'<strong>Ozone</strong><br />

83 avenue Foch F-75116 Paris, France<br />

Tel: <strong>33</strong> (0) 1 53 70 13 58<br />

Fax: <strong>33</strong> (0) 1 53 70 13 40<br />

Ms. Beatrice Bernard, Secretariat<br />

IOA-EA3G -ESIP-Plate-Forme Eaux 40, av. du Recteur Pineau<br />

86022 Poitiers Cedex, France<br />

Tel: <strong>33</strong> (0) 5 49 45 44 54<br />

Fax: <strong>33</strong> (0) 5 49 45 40 60<br />

Email: ioa@esip.univ-poitiers.fr; Web: www.ioa-ea3g.org<br />

Nippon Islands Group (NIG)<br />

Mr. Hirofumi Takahara<br />

<strong>International</strong> <strong>Ozone</strong> <strong>Association</strong><br />

Homei Building, 8th Floor<br />

1-3-19 Akasaka<br />

Minato-ku, Tokyo 107-0052<br />

Japan<br />

Tel: (81) 03 3583 5210<br />

Fax: (81) 03 3583 1461<br />

Email: joa@mrh.biglobe.ne.jp<br />

Page 3<br />

INSIDE THIS ISSUE<br />

ON THE COVER<br />

Make plans to attend the IOA-PAG conference<br />

in Lake Lanier, GA. Story on p. 32.<br />

New leadership for JOA. Story on p. 16.<br />

5 Editor’s <strong>No</strong>te<br />

6 INDUSTRY NEWS<br />

6 - Metropolitan Water District Board<br />

approves 2005-2006 Budget<br />

8 -Pacific <strong>Ozone</strong> Featured on World<br />

Business Review<br />

8 -Applications for <strong>Ozone</strong> in Food<br />

Processing Abound<br />

9 - Report from AWWA Conference<br />

12 - AWWA <strong>Ozone</strong> Handbook<br />

14 IOA NEWS<br />

14 - 23rd Japan <strong>Ozone</strong> <strong>Association</strong> Seminar<br />

on <strong>Ozone</strong> Technology<br />

16 - JOA General Assembly<br />

17 - EPRI/Global <strong>Ozone</strong> Handbook<br />

18 - <strong>Ozone</strong> Conference in Russia<br />

20 -Young Innovator Award will Finance<br />

Water Research<br />

20 -<strong>Ozone</strong> Usage Database<br />

21 Application of <strong>Ozone</strong> Resistant<br />

Microfiltration Membranes for the<br />

Reuse of Secondary Effluent<br />

25 Consultants Page<br />

26 New IOA Members<br />

29 Meetings Calendar<br />

32 Lanier <strong>Ozone</strong> Conference


<strong>Ozone</strong> News <strong>Vol</strong>ume <strong>33</strong>, <strong>No</strong>. 4<br />

The Pan American Group is holding<br />

a fall conference in Lake Lanier<br />

Islands, October 9-12, 2005 and is<br />

still in need of technical papers to<br />

be presented. If you would like to<br />

present a paper, submit your<br />

abstract immediately to Dr.<br />

Mohamed Gamal El-Din, at the<br />

University of Alberta, Canada<br />

<br />

Page 4<br />

INDEX OF ADVERTISERS<br />

2 AirTree <strong>Ozone</strong> Technology<br />

13 Analytical Technology Inc.<br />

11 Astro Pak<br />

25 Best Sulfur Products<br />

25 Black & Veatch<br />

8,9 BMT Messtechnik GmbH<br />

25 Bollyky Associates Inc.<br />

6 Eco Sensors, Inc.<br />

5 ENMET Analytical Instruments<br />

4 GDT Corporation<br />

28 IN USA Inc.<br />

14 Dr J. Hänsler GmbH<br />

25 Innovative <strong>Ozone</strong> Services Inc.<br />

25 Kennedy/Jenks Consultants<br />

5 Mazzei Injector Corporation<br />

35 Oxygen Generating Sytems Intl.<br />

36 Ozonia <strong>International</strong><br />

10 Pacific <strong>Ozone</strong> Technology<br />

11 Plasma Technics, Inc.<br />

7 SeQual Technologies<br />

Copyright© 2005 <strong>International</strong> <strong>Ozone</strong> <strong>Association</strong>. All rights reserved. <strong>No</strong><br />

part of this publication may be reproduced, stored, transmitted, or<br />

disseminated in any form or by any means without prior written permission<br />

from the <strong>International</strong> <strong>Ozone</strong> <strong>Association</strong>. The publisher assumes no<br />

responsibility for any statements of fact or opinion expressed in the published<br />

papers.


<strong>Ozone</strong> News <strong>Vol</strong>ume <strong>33</strong>, <strong>No</strong>. 4<br />

Editor’s <strong>No</strong>te<br />

You will be receiving this issue of <strong>Ozone</strong> News<br />

just before or during the Strasbourg World<br />

Congress. Considerable planning has gone<br />

into this Congress and I am sure that it will be a big<br />

success.<br />

This Congress will be followed in about two months<br />

by a Pan American Group conference at Lake<br />

Lanier Islands, GA. The PAG conferences are<br />

always well-attended and supported by the ozone<br />

manufacturing community. This will be an excellent<br />

stop to see what is new in the field of ozone.<br />

There has been much going on in the world of<br />

<strong>Ozone</strong>. The Japan <strong>Ozone</strong> <strong>Association</strong> has just<br />

completed an annual seminar and elected new<br />

leadership. An annual ozone conference in Russia<br />

was just completed. <strong>Ozone</strong> was nicely covered at<br />

the recent AWWA Conference and Exposition. All<br />

of these events are covered in this issue.<br />

After resolution of some technical issues, IOA<br />

members should now have access to <strong>Ozone</strong>:<br />

Science & Engineering on the Taylor & Francis<br />

website. I have used this website a number of times<br />

and it is a good way to retrieve past articles from<br />

recent issues of OS&E. It now makes OS&E<br />

assessable from any location, not just the location<br />

of the hard copy.<br />

All members should be very pleased with the<br />

positive recommendations that a number of ozone<br />

manufacturers have given for the IOA. By their<br />

email correspondence and advertising, they are<br />

directing others to our organization and our<br />

website.<br />

There is much being accomplished in the IOA to the<br />

benefit of all the membership.<br />

Barry Loeb<br />

Editor-in-Chief<br />

Page 5


<strong>Ozone</strong> News <strong>Vol</strong>ume <strong>33</strong>, <strong>No</strong>.4<br />

Metropolitan Water District Board approves<br />

2005-06 budget<br />

LOS ANGELES - A $1.69 billion spending plan was<br />

approved by Metropolitan Water District's Board of<br />

Directors.<br />

"This budget reflects our commitment to improve the<br />

reliability and quality of the Southland's water supplies<br />

and delivery capabilities to ensure that the region's water<br />

needs are met," said Metropolitan board Chairman Wes<br />

Bannister.<br />

The 2005-06 spending plan is $86.4 million or 5 percent<br />

higher than the previous fiscal year, primarily because of<br />

increases in Metropolitan's capital improvement budget,<br />

officials said.<br />

From July 1 to June 30 of next year, the capital budget is<br />

Industry News<br />

Page 6<br />

$500.6 million, covering more than 30 major construction<br />

contracts and 340 projects, according to MWD officials.<br />

Key system improvements will include the construction of<br />

the Inland Feeder and two other new major imported<br />

water lines; expansion of a water treatment plant serving<br />

southwest Riverside and San Diego counties; and the<br />

addition of ozone treatment facilities at two district<br />

filtration plants, which are needed to meet increasingly<br />

rigorous water quality regulations, according to the<br />

MWD.<br />

In other news, MWD announced that they have switched<br />

their primary disinfectant from chlorine to ozone, with<br />

the conversion of the 750 million gallon per day Joseph P.<br />

Jensen plant.<br />

Source: <strong>No</strong>rth County Times


<strong>Ozone</strong> News <strong>Vol</strong>ume <strong>33</strong>, <strong>No</strong>. 4<br />

Industry News (cont’d)<br />

Pacific <strong>Ozone</strong> Featured on World Business<br />

Review.<br />

A recent segment of World Business Review, hosted by<br />

Alexander Haig, focused on the benefits of using ozone<br />

as an alternative to water and air purification. Pacific<br />

<strong>Ozone</strong> presented the technology they provide to the<br />

market, addressing this very important issue.<br />

Brian Johnson, Pacific <strong>Ozone</strong> president, noted, "Pacific<br />

<strong>Ozone</strong> Technology is a complete ozone partner to users<br />

who need ozone as an integral part of their industrial<br />

process. We don't just sell ozone generators-we supply<br />

ozone know-how and expertise that help our customers<br />

succeed with their ozone application. In addition, we<br />

work closely with customers who have unique<br />

applications and needs, ensuring they get a solution that<br />

works properly and efficiently. We offer thoughtful service<br />

and support not only to our established worldwide<br />

Page 8<br />

customer base, but also to others who have an<br />

application requiring an ozone solution."<br />

The paid video gives a very positive impression of the<br />

ozone industry. The video can still be viewed on the World<br />

Business Review website, www.wbrtv.com. The ozone<br />

video can be found in Show #1609, last segment.<br />

Applications for ozone in food processing<br />

abound<br />

As reported in the July 2005 edition of Water<br />

Technology magazine, industry experts say the<br />

potential use of ozone in food-processing industries is<br />

likely to grow over time as food processors become<br />

more familiar with the technology and its capabilities.<br />

The Electric Power Research Institute (EPRI) has<br />

identified the following as some of the emerging<br />

applications:<br />

1. Eggs. Sanitize whole shell eggs to eliminate potentially<br />

pathogenic bacteria.<br />

2. Fruits and vegetables. Treat pre-process wash water for<br />

fruits and vegetables.<br />

3. Poultry. Sanitize poultry chiller water to reduce<br />

potential pathogenic bacteria, and recondition<br />

overflow water for recycling and reuse (within US<br />

Department of Agriculture guidelines).<br />

4. Wineries. Sanitize cold water, replacing traditional hot<br />

water and harsh chemical sanitation methods.<br />

5. Grain. Using ozone as a substitute for chlorinated<br />

water to control bacteria and mold in grain<br />

processing.<br />

6. Fish. Treatment of water in aquaculture tanks greatly<br />

reduces foaming even without purifying the water.<br />

7. Seafood. Using ozone for seafood processing<br />

applications, including shellfish depuration, fish<br />

pumps, fillet-line spray bars and surimi mixing tanks.<br />

Source: watertechonline.com<br />

<strong>No</strong>te: The IOA is offering a CD which gives<br />

applications case studies on many of the above uses<br />

of ozone. For more details see pg. 17.


<strong>Ozone</strong> News <strong>Vol</strong>ume <strong>33</strong>, <strong>No</strong>.4<br />

Industry News(cont’d)<br />

Report from AWWA Conference<br />

During June 12-16, 2005 some 12,700 delegates attended<br />

the 124th AWWA Annual Conference and Exposition in<br />

San Francisco, California. This conference was an<br />

excellent forum for learning the latest in research,<br />

technology and equipment developments and interacting<br />

with water professionals.<br />

Page 9<br />

At the opening session, AWWA Executive Director Jack<br />

Hoffbuhr addressed the challenges facing the AWWA<br />

including a worldwide water shortage. New challenges<br />

are the presence of pharmaceuticals/endocrine disruptors<br />

in the water supplies.<br />

AWWA President Kathryn McCain focused on the value<br />

of water. In many locations, water is not always accessible<br />

or safe to drink. The AWWA supports legislation and<br />

water rates to recognize this value.<br />

Regulatory Updates<br />

Several presentations were made by regulatory experts on<br />

the status of current and upcoming legislation.<br />

• The Groundwater rule is considering a multiple<br />

barrier approach to meeting the proposed<br />

regulations. The rule should be finalized in 2006<br />

• The stage 2 DBP (Disinfection byproducts) rule will<br />

be finalized in 2006. Focus is on Haloacetic acids<br />

(80 ppb max running average) and trihalomethanes<br />

(60 ppb).


<strong>Ozone</strong> News <strong>Vol</strong>ume <strong>33</strong>, <strong>No</strong>. 4<br />

• In February 2005, EPA published a contaminant list.<br />

Of specific emphasis are:<br />

• Lead – Regulation changes to be proposed in<br />

early 2006<br />

• Perchlorate – EPA is trying to determine whether<br />

to regulate. 26 states have found chlorate in excess of<br />

4 ppb.<br />

• MTBE – An advisory committee recommends a<br />

maximum limit of 20-40 ppb. A draft health<br />

assessment is being completed.<br />

• Arsenic rule. This rule was promulgated in 2001 and<br />

full compliance is required in some cases in early<br />

2006. EPA has held webcasts explaining the rule and<br />

is now conducting on-site workshops in Phoenix,<br />

Sacramento, Omaha, South Bend and Anchorage.<br />

These workshops provide information to users on<br />

technologies to remove Arsenic.<br />

A summary of the regulations and their compliance dates<br />

can be found at:<br />

www.epa.gov/safewater/regs.html<br />

Technical Sessions<br />

Industry News(cont’d)<br />

A number of technical presentations focused on ozone or<br />

related applications, a summary of which follows:<br />

J. Dan Shannon, CDM, discussed the expansion of the<br />

Fort Worth, TX Rolling Hills Water Plant from 160 to 200<br />

mgd capacity and the installation of a raw water<br />

ozonation facility. Ozonation was selected to meet current<br />

and future regulatory requirements, reduce tastes and<br />

odors, and improve overall treated water quality. Using<br />

LOX as the feed gas, the plant achieved 4.28 kwh/lb at<br />

10% ozone concentration. The sum of power and oxygen<br />

costs was $0.58/lb at this concentration.<br />

<strong>Ozone</strong>-enhanced biofiltration for geosmin and MIB<br />

removal was reviewed by Kerry Meyer, Carollo Engineers,<br />

and Debbie Metz, Greater Cincinnati Water Works. Pilot<br />

studies were made on the City of Boulder’s 63rd Street<br />

Water Treatment Plant and full-scale biofilter (pre GAC)<br />

tests were conducted at Cincinnati.<br />

There is increasing concern on the presence of<br />

pharmaceuticals and personal care products in drinking<br />

water. The effectiveness of treatment technologies in<br />

removing pharmaceuticals was reviewed by Shane Snyder,<br />

Page 10<br />

Southern Nevada Water Authority. <strong>Ozone</strong> is able to<br />

remove most of the products in question; byproduct<br />

formation still requires study. UV works on several<br />

products; UV combined with hydrogen peroxide is more<br />

effective. There has been success with the combination of<br />

membranes with UV.<br />

The Southern Nevada Water Authority is also facing<br />

challenges from the upcoming Stage 2 D/DBP regulations<br />

and the declining level of Lake Mead. Disinfection<br />

byproduct control strategies for this water authority were<br />

presented by Mark Janey, CH2M Hill. One interim<br />

solution may be ozone plus biologically active filtration.<br />

Update on <strong>Ozone</strong>, UV and Drinking Water<br />

A special session titled “An update on <strong>Ozone</strong>, UV and<br />

Drinking Water was jointly conducted by the AWWA,<br />

IOA and IUVA.<br />

Craig Thompson, Kennedy/Jenks Consultants, reviewed<br />

“Thirty Years of Experience Using <strong>Ozone</strong> in Water


<strong>Ozone</strong> News <strong>Vol</strong>ume <strong>33</strong>, <strong>No</strong>.4<br />

Industry News(cont’d)<br />

Treatment in the United States”. Currently there are<br />

approximately 204 drinking water plants (>1mgd) using<br />

ozone treating 9,200 mgd water and capable of producing<br />

340,000 lb/day ozone. By 2010, some 240 facilities are<br />

anticipated trating 13,000mgd water and producing<br />

420,000 lb/day ozone. Within the next five years it is<br />

expected that 1/3 of the water treatment capacity will<br />

involve ozone in some form. An ozone use questionnaire<br />

is available for users to input data to update the survey at<br />

http:/kjweb1.kennedyjenks.com/ioasurvey<br />

Kerwin Rakness, Process Applications outlined the<br />

upcoming AWWA <strong>Ozone</strong> Handbook. This handbook is<br />

intended to serve as a practical reference for anyone using<br />

ozone, or planning to use ozone. More details on this<br />

handbook are outlined elsewhere in this issue.<br />

Susan Teefy, Water Quality and Technical Solutions, Inc.<br />

surveyed ozone use in the San Francisco Bay Area.<br />

Robert Hulsey, Black & Veatch outlined the combining of<br />

ozone and UV research into a full-scale design. With UV,<br />

the biggest challenge is how to measure UV effectiveness.<br />

Page 11


<strong>Ozone</strong> News <strong>Vol</strong>ume <strong>33</strong>, <strong>No</strong>. 4<br />

Industry News(cont’d)<br />

There are currently 45 drinking water plants in the USA<br />

using UV. AWWARF Project 2749 is evaluating the<br />

combined usage of ozone and UV in drinking water<br />

treatment. A full-scale design was made of the Lake<br />

Pleasant, AZ water treatment plant. The treatment<br />

sequence of this plant, which is under construction, is<br />

Flocculation – Ozonation – Biological Filtration – GAC<br />

– UV.<br />

Joop Kruithof, IOA President, reviewed the use of UV for<br />

disinfection at the PWN Water Supply Co. IJssel water<br />

treatment plant, <strong>No</strong>rth Holland. <strong>Ozone</strong> was not used at<br />

this plant.<br />

James Bolton, IUVA, presented the upcoming<br />

AWWA/UV Handbook.<br />

Equipment Exhibition<br />

There were approximately 1000 exhibits at the conference,<br />

slightly more than the 2004 conference. Exhibitors with<br />

ozone equipment or interests included:<br />

• Analytical Technology<br />

• Applied Process Technology<br />

• Best Sulfur Products<br />

• Carus Chemical Co.<br />

• Emerson Process/Rosemont Analytical<br />

• Fuji Electric<br />

• GDT Water Process Corp.<br />

• Mitsubishi Electric Power Products, Inc.<br />

• <strong>Ozone</strong> Water Systems<br />

• Ozonia <strong>No</strong>rth America<br />

• Pacific <strong>Ozone</strong> Technology<br />

• ProMinent Fluid Controls Inc.<br />

• Statiflo Corporation<br />

• Wedeco/ITT Industries<br />

AWWA in 2006 will occur in San Antonio, TX June 11-<br />

15. AWWA 2005 appears to have met the expectations of<br />

the attendees. Those in the ozone business were<br />

optimistic about the upcoming year as the municipal<br />

business appears to be stronger and the industrial markets<br />

are still evolving.<br />

Page 12<br />

AWWA <strong>Ozone</strong> Handbook<br />

<strong>Ozone</strong> in Drinking Water Treatment: Design,<br />

Operation and Optimization<br />

This handbook, written and edited by Kerwin L.<br />

Rakness is designed as a practical, but detailed guide<br />

to using ozone in drinking water treatment. It is<br />

designed for water utilities, engineers, organizations<br />

using bench or pilot testing, and regulatory agency<br />

staff.<br />

The book is composed of 8 chapters plus an appendix.<br />

1. Introduction. <strong>Ozone</strong> safety, Physical and chemical<br />

properties, generation theory<br />

2. Applications in Drinking Water Treatment.<br />

Disinfection (Giardia, Cryptosporidium), <strong>Ozone</strong><br />

oxidation (iron, manganese, color, turbidity<br />

removal), Advanced oxidation<br />

3. <strong>Ozone</strong> Process Layout, Sizing and Cost.<br />

Generator design, Contactor design<br />

4. <strong>Ozone</strong> Process and Equipment Design &<br />

Operation. <strong>Ozone</strong> concentration and energy<br />

efficiency, Types of gas feed systems, <strong>Ozone</strong><br />

Contactor options<br />

5. Optimized <strong>Ozone</strong> Operation & Performance<br />

6. <strong>Ozone</strong> Concentration in Gas Measurement<br />

7. <strong>Ozone</strong> Residual-in-Water Measurement<br />

8. Gas Flow Measurement & Moisture Content<br />

Calculations<br />

9. Appendix – <strong>Ozone</strong> Calculations and Conversion<br />

Factors<br />

Cost of the handbook, which will be available in<br />

September, is $90 for IOA members and $125 for nonmembers.<br />

Ordering information will be available on<br />

the IOA PAG website www.io3a.org.<br />

This handbook will be a must for anyone involved in<br />

ozone system design and opearation.


OZONE MONITORING<br />

INSTRUMENTATION<br />

Dissolved <strong>Ozone</strong> Monitor<br />

Model A15/64 accurately measures<br />

dissolved ozone in all kinds of water systems,<br />

from potable to ultra-pure. Measurements<br />

from low PPB levels to 200 PPM are<br />

covered by one instrument.<br />

• Digital display with 1 PPB resolution<br />

• Isolated 4-20 mA output over ranges<br />

as low as 0-100 PPB<br />

• Programmable high and low alarms<br />

• Simple constant-head flowcell<br />

<strong>Ozone</strong> Gas Transmitter<br />

UniSens gas transmitters are looppowered<br />

devices capable of measuring<br />

ozone gas concentrations over ranges<br />

from 0-1.00 PPM up to 0-200 PPM.<br />

Transmitters are easily interfaced to plant<br />

PLC or computer systems.<br />

• 24 VDC loop-powered operation<br />

• Intrinsically safe transmitter design<br />

• Interchangeable smart sensors<br />

• Auto-Test sensor self-test option<br />

Portable <strong>Ozone</strong> Leak Detector<br />

The PortaSens II provides a simple and<br />

reliable tool for locating the source of<br />

ozone gas leaks in gas generators and<br />

piping systems. An internal sample pump<br />

draws sample through a flexible wand to<br />

allow pinpoint location of leak sources.<br />

• Interchangeable sensor for low range<br />

(0-1.00 PPM) or high range (0-200 PPM)<br />

measurements.<br />

• Audible and visual alarms<br />

• Backlit LCD indicator for use in any area<br />

• Internal data-logger stores up to 12000<br />

data points<br />

680 Hollow Road, Box 879<br />

Oaks, PA 19456<br />

800-959-0299<br />

610-917-0991 • Fax 610-917-0992<br />

www.analyticaltechnology.com<br />

––––––––––––<br />

European Headquarters:<br />

44 + (0161) 624-0200<br />

Fax 44 + (0161) 624-0400<br />

<strong>Ozone</strong> Gas Leak Detector<br />

GasSens ozone leak detectors provide<br />

economical protection against hazardous<br />

gas leakage in the area near ozone gas<br />

generation equipment. Two alarm levels, one at<br />

0.1 PPM and one at 0.3 PPM provide warning<br />

of gas leakage for personnel protection.<br />

• Operating ranges as low as 0-1 PPM<br />

• Modular design for multi-point systems<br />

• LED display of ozone concentration<br />

• Automatic sensor self-test option<br />

<strong>Ozone</strong> Gas Standards Generator<br />

Model A23-14 Generators provide a<br />

method for field calibration of ozone gas<br />

sensors. The generator provides a constant<br />

ozone gas concentration of 0.8 PPM in air,<br />

which can be used to verify or calibrate<br />

any ozone gas sensor.<br />

• NIST traceable gas concentration<br />

• Compact design for ease of transport<br />

• Simple operation<br />

• 120 VAC or 240 VAC Available


<strong>Ozone</strong> News <strong>Vol</strong>ume <strong>33</strong>, <strong>No</strong>. 4<br />

23rd Japan <strong>Ozone</strong> <strong>Association</strong> Seminar on<br />

<strong>Ozone</strong> Technology<br />

The 23rd Japan <strong>Ozone</strong> <strong>Association</strong> Seminar on ozone<br />

technology was held on June 1-3, 2005 at Aichi-ken<br />

Sangyo Boeki-kan, Nagaya-city. This seminar’s schedule<br />

was changed this year because the 14th Annual<br />

Conference on <strong>Ozone</strong> Science and Technology will be<br />

held on September 12-13 instead of June, 2005.<br />

There were approximately 100 attendees including<br />

engineers and researchers from many companies in ozone<br />

industries, the related, water treatment engineering<br />

IOA News<br />

Page 14<br />

companies and some water works.<br />

Prof. Dr. Somiya, President of the Japan <strong>Ozone</strong><br />

<strong>Association</strong> and a Past President of the IOA opened the<br />

seminar and welcomed all attendees.<br />

This seminar was sponsored by the Water Re-use<br />

Promotion Center, the Japan Water Works <strong>Association</strong><br />

and the Japan Industrial Water <strong>Association</strong>.<br />

This program covered eight technical papers and included<br />

a technical tour of the Pilot Scale Energy-saving<br />

wastewater treatment facility that has been installed in the<br />

Japanese exhibition hall back yards at Expo 2005<br />

Aichi, Japan.


<strong>Ozone</strong> News <strong>Vol</strong>ume <strong>33</strong>, <strong>No</strong>. 4<br />

The program was as follows:<br />

June 1st<br />

• Welcome address by JOA President, Prof. Dr. Isao<br />

Somiya, Ryukoku University<br />

•Perspective and future view of ozone applications for<br />

protection of the environment, Prof. Hiroshi Tsuno,<br />

Kyoto University<br />

•Safe assessment and utilization of safety standards of<br />

ozone, Prof. Hidetoshi Sugimitsu, President:<br />

Tokuyama University<br />

•Registration of factories and certification of small<br />

size ozone generation equipment, Prof. Tairo Ito,<br />

Formerly of Musashi Institute of Technology<br />

June 2nd<br />

•Improvement of the sludge reduction process and<br />

efficient methane fermentation using ozone, Kazuya<br />

Komatsu, Kurita Water Industries Ltd<br />

• Studies and research on ship’s ballast water<br />

treatment testing in a hybrid special pipe system using<br />

ozone, Masato Wada, The Japan <strong>Association</strong> of<br />

Marine Safety and Shuji Ueki, Mitsui Engineering &<br />

Shipbuilding Co. Ltd<br />

IOA News (cont’d)<br />

Page 15<br />

• <strong>Ozone</strong> generation by dielectric barrier discharge for<br />

soil sterilization, Prof. Kenji Ebihara, Kumamoto<br />

University<br />

• Ozonation of seawater-Applicability of ozone for<br />

recycled hatchery cultivation, Tateki Ozawa,<br />

Mitsubishi Electric Co. Ltd<br />

• Report of joint project JOA and JWWA “Research<br />

to optimize ozone treatment in drinking water<br />

purification plant -outline of Pilot scale plant”,<br />

Keiichi Sato, Japan Water Works <strong>Association</strong>;<br />

Takayuki Morioka, Fuji Electric Systems Co. Ltd<br />

Closing address, Vice-president Suguru Kono, Ebara<br />

Co. Ltd<br />

June 3rd<br />

A technical tour was conducted of the pilot-scale<br />

energy-saving wastewater treatment facility that has<br />

been installed in the Japanese exhibition hall back<br />

yards at Expo 2005, Aichi, Japan<br />

The next meeting of the Japan <strong>Ozone</strong> <strong>Association</strong> will<br />

be the 14th Annual Conference on <strong>Ozone</strong> Science and<br />

Technology held on September12-13, 2005.


<strong>Ozone</strong> News <strong>Vol</strong>ume <strong>33</strong>, <strong>No</strong>. 4<br />

IOA News (cont’d)<br />

JOA General Assembly<br />

A general assembly of the Japan <strong>Ozone</strong> <strong>Association</strong><br />

was held on June 1, 2005. At this assembly, Prof.<br />

Hiroshi Tsuno was appointed president of the<br />

<strong>Association</strong> replacing Prof. Isao Somiya, who is<br />

retiring as president of JOA. Prof Somiya becomes<br />

the Chairman of the Executive Committee of JOA.<br />

Prof Somiya has given more than 14 years of<br />

dedicated service and contributions to the JOA and<br />

the IOA. His contributions to these organizations are<br />

deeply appreciated.<br />

Prof. Dr. Isao Somiya is currently Professor in the<br />

Engineering Department at Ryukoku University,<br />

Kyoto and is Professor Emeritus of Kyoto University.<br />

He received his Bachelor in Engineering from Kyoto<br />

University in 1962 and a Doctor of Environmental<br />

and Sanitary Engineering from Kyoto University in<br />

1967.<br />

After several years in industry he rejoined Kyoto<br />

University in 1979 as Professor, Faculty of<br />

Engineering. He was appointed Professor, Graduate<br />

School of Engineering, Kyoto University.<br />

In 2002 he became Professor, Faculty of Engineering,<br />

at Ryukoku University (Japan)<br />

Dr. Somiya’s research has focused in ozonation of<br />

water and wastewater, development of effective<br />

advanced treatment of wastewater and mechanisms of<br />

Page 16<br />

water pollution.<br />

Dr. Somiya served as president of the Japan <strong>Ozone</strong><br />

<strong>Association</strong> from 1991-2006, President of the<br />

<strong>International</strong> <strong>Ozone</strong> <strong>Association</strong> 1995-1997 and<br />

President of the Japan Society on water Environment<br />

from 1995-1997.<br />

Prof. Dr. Hiroshi Tsuno is currently Professor in the<br />

Engineering Department at Kyoto University.<br />

He received his Master in Engineering degree at Kyoto<br />

University in 1972 and a Doctorate in Engineering<br />

from Kyoto University in 1978.<br />

Prof. Tsuno has served in the Civil Engineering<br />

Section in Osaka Pref. and with the Environmental<br />

Agency of Japan. His specialty is water quality<br />

engineering and wastewater treatment. He has many<br />

technical publications specializing in environmental<br />

and sanitary engineering, water environment science<br />

and environmental water control.<br />

Address of Prof. Tsuno to the JOA<br />

I have been inaugurated to be the President of Japan<br />

<strong>Ozone</strong> <strong>Association</strong> (JOA) from June 1st, 2005,<br />

following Professor Tamon Ishibashi and Professor<br />

Isao Somiya. I will do my best for more and more<br />

development of JOA with respecting the distinguished<br />

services and base established by the two past<br />

presidents for JOA.<br />

Though ozonation technologies have been used in<br />

wide fields in Japan, such as water purification,<br />

sewage treatment, industrial wastewater treatment,<br />

night soil treatment, treatment of wastewater


<strong>Ozone</strong> News <strong>Vol</strong>ume <strong>33</strong>, <strong>No</strong>. 4<br />

IOA News (cont’d)<br />

permeated from landfill site of solid waste, pool and spa,<br />

aquarium, preservation of environmental water and so<br />

on, they have not yet been defined as a main and<br />

indispensable technology for treatment of water and<br />

wastewater even in above mentioned fields. We must try<br />

to inform the advantages and features of ozone and<br />

stimulate understanding to ozone based on the fortune of<br />

information and knowledge accumulated until now in<br />

JOA. We are also requested to collect and develop new<br />

information and scientific knowledge.<br />

JOA holds an annual conference and seminar on ozone<br />

science and technology including a training course every<br />

year. It is also important to establish the opportunities<br />

and systems to collaborate among private company<br />

engineers and researchers, government officers and<br />

university professors in study, development and<br />

application of ozone-associated technologies. Activities<br />

of proposing and training safety standard for ozone<br />

application and of authorization of ozone generators<br />

with high safety level are indispensable from the concept<br />

that excellent technologies should be adopted with high<br />

safety and efficiency. Seminars on ozone for citizens<br />

should also be planned.<br />

JOA has been trying to spread new international<br />

information and knowledge by collaborating with IOA<br />

through several activities, for example distributing IOA<br />

<strong>Ozone</strong> News and the IOA Journal of <strong>Ozone</strong>: Science &<br />

Engineering and attending IOA Conferences. We are<br />

planning to hold the 19th IOA World Congress in Japan<br />

in 2009. We would like to ask IOA members for their<br />

kind guidance, support and help for JOA.<br />

EPRI/Global <strong>Ozone</strong> Handbook: Agriculture and<br />

Food Industries<br />

The 2004 EPRI/Global <strong>Ozone</strong> Handbook: Agriculture<br />

and Food Industries is produced by Global Energy<br />

Partners, LLC (Global) and offered through the<br />

<strong>International</strong> <strong>Ozone</strong> <strong>Association</strong> (IOA). This report<br />

summarizes research efforts pertaining to ozone's use<br />

in the agriculture and food industries. It includes<br />

experimental results from over 100 research groups<br />

and organizations and describes over two dozen<br />

specific end uses of ozone in these industries.<br />

Contributors to this publication included IOA<br />

Page 17<br />

members and member companies.<br />

Global Energy Partners, LLC, a subsidiary of the<br />

Electric Power Research Institute (EPRI) through<br />

EPRI Solutions, Inc., is a leading management<br />

consulting firm serving the energy industry. You can<br />

visit Global on the web at www.gepllc.com.<br />

The CD is designed particularly for someone who is<br />

trying to learn more about ozone and its uses in the<br />

agriculture and food industries. It contains nearly 200<br />

pages of application examples, complete with<br />

operating data in many cases.<br />

The CD is divided into several sections:<br />

Introduction<br />

• History of ozone in the agriculture and food<br />

industries<br />

Technology Description<br />

• Generation of ozone<br />

• Applications of aqueous ozone and gaseous ozone<br />

• Merits and limitations of ozone<br />

Specific End-Uses of <strong>Ozone</strong><br />

• <strong>Ozone</strong> for livestock and poultry water irrigation<br />

• <strong>Ozone</strong> for beverage manufacturing<br />

• <strong>Ozone</strong> for sanitation of equipment and work areas<br />

in food production and processing<br />

• <strong>Ozone</strong> in pest management<br />

• <strong>Ozone</strong> in the fish and seafood industry<br />

• <strong>Ozone</strong> for fruit and vegetable production and<br />

processing<br />

• <strong>Ozone</strong> for the production and processing of meat<br />

and poultry products<br />

• <strong>Ozone</strong> for indoor air quality in food production<br />

and processing<br />

• <strong>Ozone</strong> for indoor air quality in food production<br />

and processing<br />

• <strong>Ozone</strong> for food storage and preparation in homes<br />

Cost of the CD is $125 to IOA members and $150 to<br />

nonmembers. The CD can be ordered through the Pan<br />

American Group of the IOA at info@io3a.org.<br />

This CD is a must for anyone interested in the use of<br />

<strong>Ozone</strong> in the agriculture and food industries!


<strong>Ozone</strong> News <strong>Vol</strong>ume <strong>33</strong>, <strong>No</strong>. 4<br />

IOA News (cont’d)<br />

<strong>Ozone</strong> Conference in Russia<br />

The First Russian Conference “<strong>Ozone</strong> and Other<br />

Environment Friendly Oxidants: Science and<br />

Technologies” was held at the Chemistry Department<br />

of M.V. Lomonosov Moscow State University June 7-<br />

9, 2005 The Conference was devoted to the 250th<br />

anniversary of Moscow State University.<br />

255 participants took part in the Conference. Apart<br />

from Russian participants, scientists from Ukraine,<br />

Belarus, Latvia, Kyrgyzstan, Bulgaria, Poland and<br />

Singapore took part in the Conference. The Program<br />

of the conference included 9 plenary lectures<br />

concerning various aspects of ozone application, 83<br />

oral reports and 37 poster presentations.<br />

Four sections on the different aspects of ozone<br />

application were organized in the Conference. The<br />

first section was devoted to synthesis and analysis of<br />

ozone, ozone generator configurations, processes and<br />

apparatus. In the second section “Scientific<br />

elaboration and ozone technologies” reports with a<br />

technological character were presented. These reports<br />

were related to ozone application in hydrometallurgy,<br />

agriculture, organic synthesis and other<br />

manufacturing. Ecological problems resolved by<br />

means of ozone as well as ozone application for water<br />

treatment and wastewater purification were also in the<br />

scope of the third section. The forth section was<br />

completely devoted to ozone application in medicine.<br />

As to the plenary lectures in the first place we would<br />

mark the lecture of Dr. S.D. Razumovskii’ “Reactions<br />

of <strong>Ozone</strong> with Aromatic and Poly-conjugated<br />

Systems”. The influence of the minor differences in<br />

the structure of a number of allied aromatic<br />

hydrocarbons on the reaction with ozone was studied.<br />

The mechanism of ozone reaction with the similar<br />

structure of fullerenes C60 and C70 is not the same.<br />

The presence of the substitutes in the aromatic<br />

structures enlarges the amount of the primary and the<br />

secondary products. So, besides the molecular<br />

channels of labile intermediates transformations the<br />

radical and the chain-type processes take place.<br />

The excellent lecture of Ph.D. K.V. Kozlov “Modern<br />

Insight to Mechanism of Barrier Discharge in Oxygen<br />

Page 18<br />

– Nitrogen Mixtures” in the popular and at the same<br />

time in the scientific form gave the account of the<br />

modern insight into the detailed mechanism of the<br />

barrier discharge in oxygen and in air.<br />

The lecture of Dr. S.N. Tkachenko (M.V. Lomonosov<br />

Moscow State University, Chemistry Department)<br />

“Homogeneous and Heterogeneous <strong>Ozone</strong><br />

Decomposition” was devoted to the regularities of<br />

photochemical, thermal and catalytic ozone<br />

decomposition. The field of ozone decomposition<br />

occurring on oxide cement-containing catalyst (COC)<br />

was determined both under high and low temperatures<br />

in the flowing reactor filled by COC granules. The<br />

mechanism of ozone decomposition on the surface of<br />

COC was proposed. The process was found to be<br />

limited by the desorption process of the reaction<br />

product (oxygen) from the surface. In the work were<br />

determined the lifetimes of adsorbed oxygen and<br />

ozone molecules. The heat emanation induced by<br />

ozone destruction on COC covering the bead-type<br />

thermistors was also simulated. The rate constants of<br />

the principle stages of the heterogeneous ozone<br />

decomposition on Mn - Cu catalysts were evaluated in<br />

the work.<br />

The lecture of Dr. N.M. Lihterova and co-authors<br />

addressed the role of ozone in relation to processing of<br />

heavy petroleum raw materials by ionizing irradiation.<br />

The investigations revealed that the pre-ozonation has<br />

changed the mechanism and the route of the radiolysis<br />

reactions, completely. At the same time the changes of<br />

the colloid structure of the heavy petroleum raw<br />

materials were observed. Besides, the drastic decrease<br />

in vanadylporphyrine concentration also took place.<br />

Probably the following investigations in this way could<br />

allow development of new technology of petroleum<br />

raw materials treatment.<br />

It is necessary to draw attention to the lecture of Prof.<br />

V.A. Maximov and A.G. Kulikov concerning the<br />

principle achievements in ozonetherapy. The authors<br />

considered the possibilities of this new perspective<br />

method of the medical treatment of a number of<br />

diseases (atherosclerosis, diabetes mellitus, hepatitis,<br />

ischemic insult, ulcer of the stomach, osteomyelitis<br />

and also in cosmetology).<br />

As regards to the section reports we would like to draw<br />

attention to the several most interesting works. In the<br />

first section the numerous reports informed about the


<strong>Ozone</strong> News <strong>Vol</strong>ume <strong>33</strong>, <strong>No</strong>. 4<br />

IOA News (cont’d)<br />

construction of the high-frequency ozone generator with<br />

adiabatic cooling (by Joule – Thomson Method). This<br />

idea has appeared in the literature many times, but the<br />

authors (Shapiro S.V. and Amirkhanov A.Sh. from Ufa<br />

state service institute) have successfully utilized this<br />

method of the reaction gases cooling.<br />

Many very interesting reports were presented in the<br />

second section of the Conference. This section focused on<br />

the intensification of hydrometallurgical processes by<br />

means of ozone (the investigation of L.N. Krylova and<br />

colleagues –Moscow state institute of Steel and Alloys),<br />

the successful application of ozone in the processes of<br />

gaseous fuel combustion by research by Ukraine<br />

scientists, and a number of reports on ozone application<br />

in biochemistry for the synthesis of new compounds. This<br />

research was presented by Bashkortostan chemists. It is<br />

necessary to note the high professional level of these<br />

investigations. Great attention was attracted to the report<br />

of Ph.D. V.V.Timofeev (Chemistry Department of M.V.<br />

Lomonosov Moscow State University) on ozone<br />

reactions with organic compounds in the supercritical<br />

carbon dioxide region. Oxidation processes under these<br />

conditions were shown to occur through the modified<br />

mechanism. The author noted the high selectivity, good<br />

yield of the products. It allows the production of organic<br />

isocyanates.<br />

Among the applied research of this section, it is necessary<br />

to note the thorough report of Moscow and Tomsk<br />

scientists (the lecturer A. Golubkovich) concerned with<br />

ozone – air mixtures application in the process of the<br />

grain drying. The technology is introduced into practice.<br />

It allows a power reduction of 20% and shortening the<br />

drying duration time to one third in comparison with the<br />

air.<br />

The third section included a number of clearly scientific<br />

reports (reports of I.M. Piskarev, G.S. Stolyarenko and<br />

G.I. Rogozhkin). The last author proposed the<br />

nontraditional method of the quantitative evaluation of<br />

the kinetics and the effectiveness of water ozonation. In<br />

particular, it focused on the concept of ozone dose.<br />

The report by V.L. Budovich and E.B. Polotnuyk on<br />

indoors air ozonation led to lively discussion for and<br />

against the concept. The authors emphasized that in this<br />

case ozone application is accompanied by the number of<br />

Page 19<br />

concurrent effects, so the every individual case should be<br />

investigated specially.<br />

A resolution was made on the creation of Russian Fund<br />

“<strong>Ozone</strong> Society”- <strong>Association</strong> “<strong>Ozone</strong> and Other<br />

Environment Friendly Oxidants. Science and<br />

Technologies during the general meeting of the<br />

participants on the 7th of June. About 45 regions of the<br />

Russian Federation will be presented in the Fund.<br />

Academician of RAN, Prof. Valery V. Lunin was elected<br />

as the President of the <strong>Association</strong>. Vice- presidents are<br />

Ph.D. Vadim G. Samoilovoch, Dr. Sergei N. Tkachenko,<br />

and Prof. Stanislav D. Razumovskii’. The central office of<br />

the <strong>Association</strong> will be in the Chemistry Department of<br />

Moscow State University.<br />

The Proceedings of the Conference were published as<br />

collected articles in Russian (Publishing house-“Knizhnii’<br />

dom universitet”, 2005). Details on the conference and<br />

the proceedings can be found on the conference website<br />

(see below).<br />

The next Workshop (28th) will be held June 7-8, 2006.<br />

Information on previous workshops can be found in<br />

<strong>Ozone</strong> News <strong>Vol</strong>. 30, <strong>No</strong>. 4; <strong>Vol</strong>. 31 <strong>No</strong>s. 1,4; <strong>Vol</strong>. 32 <strong>No</strong>s.<br />

1,4.<br />

For additional information visit the Conference web site:<br />

http//www.kge.msu.ru/ozone<br />

Reported by Conference Vice-Chairman Dr. Vadim G.<br />

Samoilovich.<br />

See ozone generators in action at Lanier Conference!


<strong>Ozone</strong> News <strong>Vol</strong>ume <strong>33</strong>, <strong>No</strong>. 4<br />

IOA News (cont’d)<br />

Young Innovator Award will Finance Water<br />

Research<br />

Dr. Mohamed Gamal El-Din of the University of<br />

Alberta is the recipient of this year’s Petro-Canada<br />

Young Innovator Award, which provides $20,000<br />

towards his research into water treatment.<br />

The Petro-Canada Young Innovator Award Program<br />

was created in 1995 to recognize and help support the<br />

work of outstanding and innovative young faculty<br />

researchers at Canadian universities, colleges and<br />

major research institutes. Grants are made to<br />

universities who select recipients of the award.<br />

At the University of Alberta, the award is designed to<br />

recognize, promote and support outstanding and<br />

innovative faculty researchers whose academic work<br />

impacts positively on the learning environment of the<br />

department in which they work and whose research<br />

has potential to be of significance to society at large.<br />

This program is intended to articulate the<br />

commitment of Petro-Canada and the University of<br />

Alberta to support these researchers in the launch of<br />

their scholarly careers and enable them to carry their<br />

research forward.<br />

Dr. Gamal El-Din is a frequent contributor to IOA<br />

Conferences and serves on the Editorial Board of<br />

<strong>Ozone</strong>: Science & Engineering.<br />

Congratulations, Dr. Gamal El-Din!<br />

Page 20<br />

<strong>Ozone</strong> Usage Database<br />

The Pan American Group IOA Municipal Water<br />

Treatment Task Force is assembling a database of<br />

ozone installations in the US and Canada. This<br />

includes the use of ozone for both municipal drinking<br />

water and wastewater. This database is currently in<br />

the process of being posted on the IOA website for use<br />

by members. In order to complete the database and<br />

ensure that the data included are current, an ozone<br />

questionnaire has been developed.<br />

All water treatment plant operators and engineers are<br />

requested and encouraged to fill out this<br />

questionnaire. It is available at the following website.<br />

http://kjweb1.kennedyjenks.com/ioasurvey<br />

The above chart shows some of the information that<br />

will be generated from this questionnaire. In 1975,<br />

there was one drinking water plant using ozone,<br />

treating 4 mgd water, with an ozone capacity of 50<br />

lb/day. In 2005, there are more than 204 water<br />

treatment plants using ozone treating 9,200 mgd water<br />

with 340,000 lb/day ozone (installed capacity). In<br />

2010, 220 plants are anticipated, treating 12,600 mgd<br />

water with 420,000 lb/day ozone. The charges also<br />

illustrate the increase in size of individual ozone<br />

installations.<br />

The report will be summarized in its entirety in a<br />

future issue of <strong>Ozone</strong> News.


<strong>Ozone</strong> News <strong>Vol</strong>ume <strong>33</strong>, <strong>No</strong>. 4<br />

Application of <strong>Ozone</strong> and <strong>Ozone</strong> Resistant Microfiltration Membranes<br />

for the Reuse of Secondary Effluent<br />

Takuya Onitsuka, Shizuo Takeda<br />

R&D Division of SUIDO KIKO Co., Ltd, 5-48-16 Sakuragaoka Setagaya-ku, Tokyo,156-0054, JAPAN<br />

Abstract<br />

A new reclamation system by combining microfiltration (MF) membrane with ozone was developed<br />

to obtain a better water quality in sewerage reuse. The MF membrane was a hollow fiber made from<br />

polyvinylidenefluoride that has a high ozone resistance. The reclamation system using this MF<br />

membrane together with ozone could provide high filtration flux of 5 m3 /m2. d and a stable operation<br />

without chemical cleaning for long terms. This is because ozone decomposed or denatured a part of<br />

organic materials in the sewerage water and reduced fouling of the membrane surface. The water<br />

obtained by this reclamation system has a high quality and excellent in security against pathogenic<br />

organisms. This system was constructed at Shibaura water reclamation center, bureau of sewerage of<br />

Tokyo Metropolitan Government. The reclamation water of a high grade has been supplied to the<br />

redeveloped area as toilet flush water and cooling water since April 2004.<br />

Keywords<br />

<strong>Ozone</strong>; Reuse; Reclamation; <strong>Ozone</strong> Resistant Microfiltration Membrane;<br />

Introduction<br />

The effective usage of water resources and energy in<br />

sewage works is desired and the ability to recycle water is<br />

a priority to assist in the problem of global water<br />

shortage. The secondary effluent from wastewater<br />

treatment plants is a valuable water resource and its reuse<br />

is given priority in this issue. The reclamation water is<br />

used a in variety of applications such as landscape<br />

irrigation, environmental uses, industrial activities,<br />

agricultural irrigation, snow melting use and toilet<br />

flushing etc. In case of water shortage areas and the<br />

redeveloped area in a large city, the use of reclamation<br />

water for environmental uses and toilet flushing is<br />

increasing. It is necessary for these reclamation waters to<br />

have a high quality, as human beings have more<br />

opportunities for being in direct touch with them.<br />

Therefore, bacteria and pathogenic organisms must be<br />

taken into consideration in addition to suspended<br />

matters, color and odor.<br />

Membrane filtration is a solid-liquid separation method<br />

with high performance. There are few instances of<br />

membranes in sewerage reclamation division, as it is likely<br />

to be fouled by the organic matters and a higher cost than<br />

that of other separation methods. <strong>Ozone</strong> has a strong<br />

Page 21<br />

chemical oxidation property. <strong>Ozone</strong> is expected to<br />

decompose organic materials in the water and reduce a<br />

fouling of the membrane surface. The new reclamation<br />

system using MF membrane together with ozone was<br />

developed and introduced into the sewerage treatment<br />

plant.<br />

Materials and Methods<br />

Figure 1. The flow sheet of the developed reclamation<br />

system


<strong>Ozone</strong> News <strong>Vol</strong>ume <strong>33</strong>, <strong>No</strong>. 4<br />

The reclamation system flow<br />

As shown in Figure 1, the developed reclamation system<br />

consists of a pre ozone process, bio filtration process,<br />

ozone oxidation process and MF membrane process. Pre<br />

ozone and bio filtration treat a part of organic matters<br />

and nitrogen in the secondary effluent and have a<br />

function to decrease ozone dosage in following ozone<br />

treatment. <strong>Ozone</strong> can decompose color and odor by<br />

oxidation function and disinfect bacteria. MF membrane<br />

is a hollow fiber with pore size of 0.1μm and can remove<br />

micro suspended matters including bacteria and<br />

Cryptosporidium.<br />

Features of MF membrane<br />

MF membrane is made from polyvinylidenefluoride that<br />

has a high ozone resistance. In addition, the membrane<br />

module is made from silicon that has an ozone resistance.<br />

Therefore, this membrane can filter the suspended water<br />

that includes dissolved ozone.<br />

Experimental Methods<br />

To clarify treatment efficacy and performance<br />

characteristics, pilot test was carried out during 5 months.<br />

The flow of test plant is shown in Figure 2. Treatment<br />

capacity was approximately 30 m 3/day. The treated water<br />

Figure 2. The experimental flow sheet of the reclamation system.<br />

Page 22<br />

sampled from each treatment process was analyzed<br />

regularly. The analyzed items were BOD, COD,<br />

heterotrophes, Escherichia coliform, fecal coliform,<br />

ammonia nitrogen, color and so on. In addition,<br />

Cryptosporidium was also examined to prove treatment<br />

efficacy.<br />

Regarding membrane operation, the behavior of the<br />

transmembrane pressure (TMP) was examined with<br />

change of dissolved ozone concentration on membrane<br />

surface. After deciding adequate dissolved ozone<br />

concentration for preventing the rise of TMP, the<br />

continuous filtration test was carried out with controlling<br />

dissolved ozone concentration automatically.<br />

Results and Discussion<br />

Treatment efficacy of this reclamation system<br />

The results of analyzed water quality are shown in Table<br />

I. Heterotrophes, escherichia coliform and fecal coliform<br />

are sterilized in the ozone treatment process. BOD is<br />

removed to 87%. Color is reduced to 8 (c.u.) on ozone<br />

treatment process and furthermore 1(c.u.) on membrane<br />

process. This is because ozone coagulates a part of color<br />

substances. Most of the ammonia nitrogen is nitrified by<br />

the bio filtration process and converted to nitrate<br />

nitrogen. The membrane process can remove not only


<strong>Ozone</strong> News <strong>Vol</strong>ume <strong>33</strong>, <strong>No</strong>. 4<br />

Table I. Treated water quality in each treatment process<br />

suspended matters but also ova or larva of organisms.<br />

As a result, the final treatment water can provide a<br />

better water quality than that of Japanese reuse<br />

standards. The outbreak of Chironomid in<br />

reclamation water could be also eliminated.<br />

Treatment efficacy of Cryptosporidium oocysts<br />

The determinations of Cryptosporidium oocysts were<br />

carried three times for the duration of continuous test.<br />

The results are shown in Table II. The determinations<br />

could not prove whether Cryptosporidium oocysts<br />

detected in ozone treatment water were active or<br />

inactive. But it was reported in other research<br />

(Oomura etc,2000) that Cryptosporidium oocysts was<br />

inactivated to approximately 4 log by ozone, as shown<br />

in Table III. Therefore, it is considered that<br />

Cryptosporidium oocysts are inactivated by this ozone<br />

system with C.T. value of more than 13 (mg/L?min.).<br />

Moreover, Cryptosporidium oocysts in MF<br />

membrane treatment water are not detected at all.<br />

This reveals that ozone and MF membrane provide<br />

double hygienic barrier against pathogenic organisms.<br />

Page 23<br />

Table II.Removal effect of Cryptosporidium oocysts<br />

Table III. Inactive ratio of C.P.O. to CT value by <strong>Ozone</strong>


<strong>Ozone</strong> News <strong>Vol</strong>ume <strong>33</strong>, <strong>No</strong>. 4<br />

Effect of dissolved ozone on TMP<br />

The change of TMP (transmembrane pressure) with a<br />

variation of dissolved ozone on the membrane surface<br />

is shown in Figure 3. It is evident that the behavior of<br />

TMP is influenced by dissolved ozone concentration.<br />

That is, keeping the dissolved ozone concentration on<br />

the membrane surface at 1.0mg/L can prevent the rise<br />

of TMP. Therefore, this reveals that the dissolved<br />

ozone may decompose or modify organic materials on<br />

the membrane surface and reduce fouling of<br />

membrane. The dissolved ozone concentration of<br />

1.0mg/L is necessary to keep the stable operation of<br />

MF membrane system.<br />

Page 24<br />

The change of TMP during the continuous filtration test<br />

is shown in Figure 4. The dissolved ozone concentration<br />

on the membrane surface was controlled approximately<br />

1.0 mg/L. Membrane flux was 5.0 m3/m2. d. TMP doesn’t<br />

rise rapidly and change slowly. At an elapse of 3,800<br />

hours, TMP goes to only 120kPa. This value is less than<br />

TMP of 200kPa, at which chemical cleaning is necessary.<br />

This proves that a stable membrane operation at high flux<br />

in the long term is obtained by controlling the dissolved<br />

ozone concentration of 1.0 mg/L on the membrane<br />

surface.<br />

Conclusions<br />

The reclamation system using MF membrane together<br />

with ozone could provide high filtration flux of 5 m3 /m2. d<br />

and a stable operation without chemical cleaning in the<br />

long term. The water obtained by this reclamation system<br />

was a high quality and excellent in security against<br />

pathogenic organisms.<br />

This system has following superior features:<br />

1. The reclamation water obtained has a high quality<br />

without color, odor and suspended matters.<br />

Furthermore, it is excellent in security against<br />

pathogenic organisms.<br />

2. An economical membrane filtration system can be<br />

designed based on higher filtration flux.<br />

3. This system can be installed in a limited space.<br />

Based on the above-mentioned data, the reclamation<br />

plant was constructed at Shibaura water reclamation<br />

center, bureau of sewerage of Tokyo Metropolitan<br />

Government and began to operate in April 2004. This<br />

plant has treatment capacity of 4,300 m 3/d. MF<br />

membrane units are shown in Figure 5 (page 30). The<br />

reclamation water is distributed to the redeveloped areas<br />

in Shinagawa, Shiodome and Oosaki as toilet flashing<br />

water and environmental uses. The water quality of<br />

reclamation water obtained is much better than that of<br />

existing sand filters and gets a good reputation by users.<br />

In addition, the heat island phenomenon is now at stake<br />

in highly urbanized areas. Sprinkling water on the roads<br />

gives effect of preventing temperature on the roads and in<br />

the atmosphere from going up. This reclamation water is<br />

used as a measure of the heat island phenomenon. In the<br />

future, the reclamation water with high water quality is<br />

desired to apply progressively for many kinds of reuse.


<strong>Ozone</strong> News <strong>Vol</strong>ume <strong>33</strong>, <strong>No</strong>.4<br />

Page 25


<strong>Ozone</strong> News <strong>Vol</strong>ume <strong>33</strong>, <strong>No</strong>. 4<br />

NEW IOA MEMBERS<br />

The <strong>International</strong> <strong>Ozone</strong> Asociation takes great pleasure in welcoming our new members<br />

AUSTRALIA<br />

Mr. Richard LEBRETON<br />

19/924 Pacific Highway<br />

GORDON<br />

NSW 2072<br />

Tel. +61 2 9498 1444<br />

Fax. +61 2 9498 1666<br />

richard@citywater.com.au<br />

Mr. Andrew MATHESON<br />

53 Riverson Street<br />

CLAYFIELD 4011<br />

Tel. +61 3862 3500<br />

info@aquazen.com.au<br />

BRAZIL<br />

Leticia Maria Borsarini Philippi<br />

Alameda Duque de Caxais<br />

145 Sala 102<br />

Blumenau, SC 89015-010<br />

Tel: 55 4732 61593<br />

Fax: 55 4732 61593<br />

CANADA<br />

Elia Edwards<br />

Associated Engineering<br />

525-21 Four Seasons Place<br />

Toronto, Ontario M9B 6J8<br />

Tel: (416) 622-9502<br />

Fax: (416) 622-6249<br />

Myriam Rivard<br />

450 St-Jean Baptiste<br />

Quebec City, QB G2E 6H5<br />

Tel: (418) 844-2825\<br />

myriam_rivard@hotmail.com<br />

EGYPT<br />

Mr. Mohamed Nabil MAWSOUF<br />

4 Ahmed El-Zomar St.<br />

Arca 8<br />

Nasi City<br />

11768 CAIRO<br />

Tel. +202 50 50 111<br />

Fax. +202 27 25 036<br />

mawsouf@hotmail.com<br />

FRANCE<br />

Mr. Juan Gabriel GARCIA<br />

INSA<br />

135 avenue de Rangueil<br />

31077 TOULOUSE CEDEX 4<br />

Tel. +<strong>33</strong> 561 55 97 87<br />

Fax. +<strong>33</strong> 561 55 97 60<br />

garciam@insa-toulouse.fr<br />

Mr. Gilles HEBRARD<br />

INSA<br />

135 avenue de Rangueil<br />

31077 TOULOUSE CEDEX 4<br />

Tel. +<strong>33</strong> 561 55 97 89<br />

Fax. +<strong>33</strong> 561 55 97 60<br />

hebrard@insa-toulouse.fr<br />

Mr. Dominique JUIF<br />

3 rue Orphéroux<br />

87000 LIMOGES<br />

Tel. +<strong>33</strong> 587708179<br />

Fax. +<strong>33</strong> 587708179<br />

judovivi@aol.com<br />

Mr. Jean-Stéphane PIC<br />

INSA<br />

135 avenue de Rangueil<br />

31077 TOULOUSE CEDEX 4<br />

Tel. +<strong>33</strong> 561 55 97 47<br />

Fax. +<strong>33</strong> 561 55 97 60<br />

pic@insa-toulouse.fr<br />

GERMANY<br />

Mrs. Monique HERMANS<br />

MESSER GROUP GmbH<br />

Application Technology & Technology<br />

Management<br />

Gahlingspfad 31<br />

47803 KREFELD<br />

Tel. +49 2151 7811 221<br />

Fax. +49 2151 7811 503<br />

monique.hermans@messergroup.com<br />

Page 26<br />

GREECE<br />

Mr. Lazaros DANIILIDIS<br />

Kouskoura 6<br />

54622 THESSALONIKI<br />

Tel. +30 231 0 250 351<br />

Fax. +30 231 0 250 354<br />

medilaser@otenet.gr<br />

ITALY<br />

Mr. Raffaele PAGANO<br />

OZONIS SRL<br />

Via Como 69/A<br />

CESANO MADERNO (MILANO)<br />

20031<br />

Tel. +39 362 54 08 48<br />

Fax. +39 362 57 50 91<br />

info@ozonis.it<br />

JAPAN<br />

Mr. Masakazu USUI<br />

Executive Managing Director<br />

Fuji Electric Construction Co.,Ltd<br />

Solid Square West Tower<br />

580 Horikawa-cho,Saiwai-ku<br />

Kawasaki-city, 212-0013<br />

Tel:81-44-548-4495<br />

Fax:81-44-548-4424<br />

usui-masakazu@fujikoji.co.jp<br />

Dr. Akira MURAI<br />

Reseacher<br />

The Kansai Electric Power Company<br />

1-7 Seika-cho, Souraku-gun,<br />

Kyoto Prefecture<br />

81-774-93-2893<br />

Fax: 81-774-93-2894<br />

murai.akira@e3.kepco.co.jp<br />

LEBANON<br />

Mr. Fadi SABBAH<br />

PO Box 113<br />

5916 HAMRA<br />

BEIRUT<br />

Tel. +961 3-742240<br />

Fax. +961 1-348988<br />

fadident@cyberia.net.lb


<strong>Ozone</strong> News <strong>Vol</strong>ume <strong>33</strong>, <strong>No</strong>. 4<br />

MEXICO<br />

Carlos G-M Barajas-Diaz<br />

Carbar’s<br />

Juan Bautista Lasalle 502<br />

Leon, Guanajuato 37160<br />

Tel: (52) 477-418-6566<br />

Fax: (52) 477-717-7349<br />

carbars@yahoo.com<br />

Alfredo Lopez Arratia<br />

Water & Gases Technologies<br />

Chilapa 46<br />

Tlalpan, DF<br />

Tel: (52) 5555-731322<br />

Fax: (52) 5555-731322<br />

P.R. CHINA<br />

Mr. MingXing HUANG<br />

LIMICEN OZONE R&D Center Co. Ltd.<br />

Room 901, NO. 239<br />

Chashan Road<br />

Tianhe District, Guangzhou City<br />

Guangdong Province,GUANGZHOU<br />

510640<br />

Tel. +86 2038903226<br />

Fax. +86 2038903211<br />

liumeichang@163.com<br />

RUSSIA<br />

Mr. Ruslan KABISOV<br />

2nd Botkinsky Proezd, 3<br />

MOSCOW<br />

Tel. +7 095 945 87 09<br />

Fax. +7 095 945 68 82<br />

muioi@mail.ru<br />

Mr. Vladimir PANTELEEV<br />

Vorovsky St., 125-48<br />

KIROV 610021<br />

Tel. +7 8<strong>33</strong> 2 52 67 60<br />

marketing@lepse.kirov.ru<br />

Mr. Serguei SAVILOV<br />

Moscow State University<br />

Chemistry Dept.<br />

Leninskie Gory, 1-3<br />

New IOA Members (cont’d)<br />

MOSCOW 19992<br />

Tel. +7 095 939 <strong>33</strong>21<br />

Fax. +7 095 939 4575<br />

savilov@chem.msu.ru<br />

SWITZERLAND<br />

Mr. Marc-Olivier BUFFLE<br />

Ueberlandstrasse 1<strong>33</strong><br />

8600 DUEBENDORF<br />

Tel. +41 44 823 5087<br />

Fax. +41 44 823 5210<br />

mbuffle@eawag.ch<br />

Mr. Michael DODD<br />

EAWAG<br />

Ueberlandstrasse 1<strong>33</strong><br />

8600 DUEBENDORF<br />

Tel. +41 44 823 50 64<br />

Fax. +41 44 823 52 10<br />

michael.dodd@eawag.ch<br />

THE NETHERLANDS<br />

Mr. Joop NEINDERS<br />

Ceckumerstraat 172<br />

7548 BJ ENSCHEDE<br />

Tel. +31 53-4283078<br />

Fax. +31 53-4283081<br />

joop.neinders@ibth.nl<br />

UNITED STATES OF AMERICA<br />

Tom Barrs<br />

5S484 Gordon Terrace<br />

Naperville, IL 60563<br />

Tel: (630) 961-0837<br />

dad484@wideopenwest.com<br />

Vitaly Berkman<br />

MKS Instruments<br />

90 Industrial Way<br />

Wilmington, MA 01887<br />

Tel: (978) 284-4605<br />

Fax: (978) 284-4605<br />

Page 27<br />

Jose Bonilla<br />

11020 Huebner Oaks, apt 2125<br />

San Antonio, TX 78230<br />

Tel: (210) 538-5202<br />

Fax: (210) 538-5202<br />

jbonilla8@satx.rr.psi<br />

Richard Caldwell<br />

Caldwell Mechanical<br />

1617 Whitton Ave.<br />

San Jose, CA 95969<br />

Tel: (530) 624-2434<br />

Fax: (408) 251-16<strong>33</strong><br />

richiecaldwell@mac.com<br />

Johon Decanio<br />

Newaire, Inc.<br />

P. O. Box 1<strong>33</strong><br />

Ashburn, VA 20146<br />

Tel: (703)654-0385<br />

Fax: (703) 654-0386<br />

Michael Dodd<br />

1005 Camden Court<br />

Atlanta, GA 30327<br />

Tel: (404) 843-9255<br />

michaeldodd@eawag.ch<br />

Susan Duffy<br />

Newaire, Inc.<br />

P. O. Box 1<strong>33</strong><br />

Ashburn, VA 20146<br />

Tel: (703) 654-0385<br />

Fax: (703) 654-0386<br />

David W Ferguson<br />

MWH Global<br />

301 <strong>No</strong>rth Lake Ave., Suite 600<br />

Pasadena, CA 91101<br />

Tel: (626) 568-6924<br />

Fax: (626) 568-6101<br />

david.ferguson@mwhglobal.com<br />

Robert Hulsey<br />

Black & Veatch<br />

8400 Ward Parkway<br />

Kansas City, MO 64114<br />

Tel: (913) 458-3441<br />

Fax: (913) 458-3802<br />

hulseyra@bv.com


<strong>Ozone</strong> News <strong>Vol</strong>ume <strong>33</strong>, <strong>No</strong>. 4<br />

Adam Karbaf<br />

Fulham Co.<br />

499 Forest Park Circle<br />

Franklin, TN 37064<br />

Tel: (615) 591-2371<br />

Fax: (615) 523-2120<br />

akarbaf@comcast.net<br />

Delisa Kennedy<br />

Nalco Co.<br />

1601 E Diehl Road<br />

Naperville, IL 60563<br />

Tel: (630) 305-2845<br />

Fax: (630) 305-2845<br />

dkennedy@nalco.com<br />

Richard Luscombe-Mills<br />

Newaire, Inc.<br />

P. O. Box 1<strong>33</strong><br />

Ashburn, VA 20146<br />

Tel: (315) 393-1959<br />

Fax: (703) 654-0386<br />

Pat Mc Kenna<br />

Sports-O-Zone USA, LLC<br />

53847 <strong>No</strong>rth Park Ste B<br />

Elkhart, IN 46514<br />

Tel: (574) 264-6062<br />

Fax: (574) 264-6062<br />

sozusa@msn.com<br />

Chris Morrison<br />

Nalco Co.<br />

1601 E Diehl Road<br />

Naperville, IL 60563<br />

Tel: (415) 497-1772<br />

Fax: (630) 305-2845<br />

Mary Ann Naddy<br />

MKS Instruments<br />

90 Industrial Way<br />

Wilmington, MA 01887<br />

Tel: ((78) 284-4250<br />

Fax: (978) 284-4605<br />

Derek Miller<br />

Air Products & Chemicals Inc.<br />

7201 Hamilton Blvd.<br />

Allentown, PA 18195<br />

Tel: (610) 481-3296<br />

Fax: (610) 481-4715<br />

Miller3@airproducts.com<br />

New IOA Members (cont’d)<br />

Evelio Sevillano<br />

MKS Instruments<br />

90 Industrial Way<br />

Wilmington, MA 01887<br />

Tel: (978) 284-9129<br />

Fax: (978) 284-4605<br />

Anthony Sommese<br />

Nalco Co.<br />

1601 E Diehl Road<br />

Naperville, IL 60563<br />

Tel: (630) 305-1000<br />

Fax: (630) 305-2845<br />

Hans Sundstrom<br />

MKS Instruments<br />

90 Industrial Way<br />

Wilmington, MA 01887<br />

Tel: (978) 284-4200<br />

Fax: (978) 284-4605<br />

hsundstrom@mksinst.com<br />

Paul M. Vervalle<br />

5109 Diablo Drive<br />

Sacramento, CA 95842<br />

Tel: (916) 348-0288<br />

ao3t@mindspring.com<br />

William Walling<br />

Filtercon Technologies<br />

2801 Camino Del Rio South,<br />

Suite 300C<br />

San Diego, CA 92108<br />

Tel: (619) 688-1810<br />

Fax: (619) 688-1854<br />

info@filtercon.com<br />

Page 28


<strong>Ozone</strong> News <strong>Vol</strong>ume <strong>33</strong>, <strong>No</strong>. 4<br />

Upcoming IOA Meetings<br />

2005<br />

August 22-25, 2005, 17th <strong>Ozone</strong> World Congress,<br />

Strasbourg, France. The upcoming congress will host<br />

experts from all over the world to present and discuss the<br />

latest advances in knowledge and technology for<br />

development and application of processes based on<br />

ozone or any derived or comparable oxidants for:<br />

•Environmental and human health protection (water,<br />

gas, soil and waste purification)<br />

•Industrial manufacture and conditioning (pulp and<br />

paper, food, electronics, chemicals)<br />

•Medical therapy<br />

This Congress will be held in parallel with the 7th<br />

Gas/Liquid/Solid World Congress.<br />

For more information, visit:<br />

www.ensic.inpl-nancy.fr/IOA17/ or contact the IOA<br />

Congress Office: IOA17@ensic.inpl-nancy.fr.<br />

Registration and hotel information is available on this website.<br />

September 12-13, 2005, 14th Annual Conference on <strong>Ozone</strong><br />

Science & Technology (Japan). This conference is being<br />

arranged by the Japan <strong>Ozone</strong> <strong>Association</strong>. For more<br />

information, contact: joa@mrh.biglobe.ne.jp<br />

October 8-12, 2005, PAG Regional Conference,<br />

Renaissance Pineisle Resort, Lake Lanier Islands,<br />

Georgia, USA. A wide range of technical topics will be<br />

included in this conference ranging from drinking water<br />

disinfection to food and agricultural applications. The<br />

technical program, when complete will be available on the<br />

PAG website www.io3a.org. Following up on past<br />

successful conferences, an Operators Workshop will be<br />

held on Tuesday afternoon for operators to learn more<br />

about equipment, monitoring, process control and safety.<br />

For more information: See additional informationa nd<br />

registration forms in this issue or visit www.io3a.org.<br />

<strong>No</strong>vember 29, 2005, Seminar on Hot topics for <strong>Ozone</strong><br />

Application, Paris , France. This seminar is organized by<br />

EA 3 G in the framework of Pollutec Paris 2005.<br />

Meetings Calendar<br />

Page 29<br />

Located at the heart of France’s leading economic region,<br />

the 21st Pollutec will attract over 40,000 managers and<br />

specifiers from industry and local authorities and those<br />

involved in the protection of the environment and<br />

sustainable development. Over 4 days, 1,500 eco<br />

exhibitors will present a unique international array of<br />

techniques and services for the prevention and treatment<br />

of pollution of all kinds. For more information, visit:<br />

www.ioa-ea3g.org<br />

Upcoming Meetings of Other Organizations<br />

2005<br />

September 26-30, 2005, <strong>International</strong> Bottled Water<br />

<strong>Association</strong> 47th Annual Convention & Trade Show,<br />

Orlando Convention Center & The Rosen Center Hotel,<br />

Orlando, Florida. For more information, contact:<br />

www.bottledwater.org.<br />

October 23-27, 2005, 11th <strong>International</strong> Conference on<br />

Advanced Oxidation Technologies for Treatment of Water,<br />

Air and Soil, Marriott Chicago O’Hare, Chicago, IL,<br />

USA. For more infromation, contact:<br />

hussain@alekabi.com.<br />

October 29-<strong>No</strong>vember 2, 2005, WEFTEC 05, Washington<br />

Convention Center, Washington, DC. For more<br />

information, contact: www.weftec.org.<br />

October 31 - <strong>No</strong>vember 2, 2005, <strong>International</strong> Pool and Spa<br />

Expo, Orlando, FL. For more information, visit:<br />

www.poolandspaexpo.com<br />

<strong>No</strong>vember 6-10, 2005, AWWA Water Qualilty Technology<br />

Conference, Quebec City, Canada. Contact:<br />

www.awwa.org<br />

2006<br />

March 6-9, 2006, Water China / PVP China / AW China<br />

2006,Guangzhou / PR China.


<strong>Ozone</strong> News <strong>Vol</strong>ume <strong>33</strong>, <strong>No</strong>. 4<br />

Meetings Calender (cont’d)<br />

This trade fair is the biggest and most important of its<br />

kind in China. The organizers are China Foreign Trade<br />

Centre Group in association with MEREBO Messe<br />

Marketing.Contact: www.waterchina.merebo.com<br />

March 16-18, 2006: <strong>International</strong> Symposium on<br />

Waterborne Pathogens, Atlanta, Georgia. Contact:<br />

awwa.org<br />

April 3-7, 2006, Wasser Berlin 2006. Contact:<br />

www.wasser-berlin.com. <strong>No</strong>te: Usually there is an IOA<br />

conference in conjunction with Wasser Berlin.<br />

June 11-15, 2006, AWWA Annual Conference and<br />

Exposition, San Antonio, Texas. Contact: www.awwa.org<br />

June 24-26, 2006, Institute of Food Technologists Annual<br />

Meeting and Exposition, Orlando Florida. Contact:<br />

www.ift.org<br />

Continued from Page 24<br />

Figure 5. <strong>Ozone</strong> resistant membrane filtration units<br />

Page 30<br />

September 10-14, 2006, World Water Congress &<br />

Exposition, Beijing China. The conference will focus on<br />

drinking and wastewater treatment, and on health issue.<br />

Call for papers due October 31, 2005. For more<br />

information, contact: www.iawq.org<br />

September 26-29,2006, Aquatech Amsterdam, For more<br />

information, contact www,aquatechtrade.com<br />

August 9-12, 2006, Specialized Conference on<br />

Management of Residues Emanating from Water and<br />

Wastewater Treatment, Sandton Convention Centre,<br />

South Africa. Hosted by IWA Specialist Group on Sludge<br />

Management and WISA Anaerobic and Sludge<br />

Management Division. For more information, visit<br />

www.iwa.hq.org<br />

October 21-25, 2006, WEFTEC 06, Dallas Convention<br />

Center, Dallax TX. For more information, contact:<br />

www.weftec.org


<strong>Ozone</strong> News <strong>Vol</strong>ume <strong>33</strong>, <strong>No</strong>. 4<br />

25 Years of <strong>Ozone</strong>: Science & Engineering on CD ROM<br />

Are you tired of searching for articles from OS&E and finding that they may not be<br />

available? The IOA is providing the complete series of <strong>Vol</strong>umes 1-25 on CD ROM. A<br />

master index is provided at the beginning of the CD so that keyword and author<br />

searching is simplified. This CD is now available and can be ordered through the IOA<br />

regional Group office. For those holding the CD ROM containing the first 22 years, an<br />

updated CD is available for a modest cost.<br />

Price per set (2CDs) $350.00 Members $600.00 non-members<br />

Updated CD $50.00 members $90.00 non-members<br />

To order your set, copy this page and fax or mail to Regional IOA Office<br />

PAG<br />

PO Box 8761<br />

Scottsdale, AZ 85252<br />

Fax: (480) 361-7725<br />

EA3G<br />

Bat. ESIP-40 Av. Du recteur Pineau<br />

85922 Poitiers Cedex, France<br />

Fax: (<strong>33</strong>) 5 49 45 40 60<br />

Name_________________________________________________________________<br />

Address_______________________________________________________________<br />

City ____________________________State/Province________________________<br />

Postal Code_______________Country_______________Phone<br />

__________________Fax______________________<br />

____Member ____<strong>No</strong>n Member Number of Sets _____ New CD__________ Updated CD ______________<br />

_____Payment Enclosed _____Bill to Credit Card (Visa/MasterCard)<br />

Card Number _________________________________________ Expiration Date __________________________<br />

Page 31<br />

Nippon Islands Group<br />

Homei Building, 8th Floor<br />

1-3-19 Akasaka<br />

Minato-ko, Toko 107-0052, Japan<br />

Fax: (81) 03 3583 1461


<strong>Ozone</strong> News <strong>Vol</strong>ume <strong>33</strong>, <strong>No</strong>. 4<br />

2005 Annual Conference<br />

<strong>International</strong> <strong>Ozone</strong> <strong>Association</strong>-Pan American Group<br />

October 8-12, 2005, PineIsle Resort, Lake Lanier, Georgia, USA<br />

On October 8-12, 2005 the IOA Pan American Group (PAG) will be holding its 2005 Annual<br />

Conference titled “<strong>Ozone</strong>: A valuable tool for a wide range of applications”. The conference will be<br />

held at the Renaissance PineIsle Resort, Lake Lanier Islands, GA. The resort is located 52 miles<br />

northeast of the Atlanta Hartsfield <strong>International</strong> Airport. Neal Spivey of the Gwinnett County, GA<br />

water district is the conference chair.<br />

Technical Sessions<br />

The conference is intended to provide information to<br />

engineers, scientists, and end users of ozone and<br />

other active oxygen species. Topics can include, but<br />

not be limited to:<br />

Disinfection<br />

Cooling Tower Applications<br />

Chemical and Biochemical Reactions<br />

Food and Agricultural Applications<br />

Biofiltration<br />

Spa/Pool/Aquarium<br />

Bromate Formation and Control<br />

Industrial Applications<br />

<strong>Ozone</strong> Generation<br />

Waste Water Treatment<br />

Contactor Design<br />

Advanced Oxidation<br />

Small Systems<br />

Emerging Issues in Water Quality<br />

Exhibition<br />

Like past conferences, an equipment exhibition will occur. The conference is being planned to<br />

maximize traffic throughout the Exhibit Hall, including holding coffee breaks in the Exhibit hall and<br />

hosting a complimentary “Attitude Adjustment Hour” on Monday evening within the Exhibit Hall<br />

at the close of the Technical Sessions. Coffee break times will be extended to allow greater<br />

opportunity for attendees to visit the Exhibition throughout the conference.<br />

Space is still available for exhibitors. For more information, visit www.io3a.org.<br />

Operators Workshop: • Special Tuesday Afternoon Session for Operators to learn more about<br />

equipment, monitoring, process control and safety. CEU credits provided.<br />

PAG web page http://www.io3a.org<br />

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<strong>Ozone</strong> News <strong>Vol</strong>ume <strong>33</strong>, <strong>No</strong>. 4<br />

Technical Tours: • Several Technical Tours have been arranged for Wednesday.<br />

Tour 1 -Will visit three ozone facilities; the 75-MGD Shoal Creek Filter Plant, the 150 MGD Scott Chandler<br />

Filter Plant,and the 40-MGD F. Wayne Hill Advanced Wastewater Treatment Plant.<br />

Tour 2- Will visit several agricultural facilities that use ozone.<br />

Each Tour will be limited to 50 people. After the tours, buses will take you to<br />

the Atlanta airport for a convenient return trip home.<br />

Social Tours • Several Social Tours have been arranged:<br />

Tour 1- Monday 10-11-05: Shopping Spree at Atlanta’s premiere Shopping and Entertainment<br />

Complex, Mall of Georgia. Leaving at 10:00 am - returning 4:00pm.<br />

Tour 2- Tuesday 10-10-05; Lunch and Tour of Arts/Craft shops in picturesque Buford.<br />

Leaving at 11:00 am- returning by 4:00 pm.<br />

Don’t Miss all that is offered at Pine Isle Resort<br />

The Conference site, Pine Isle Resort offers our attendees a wide range of recreational activities including golf, tennis,<br />

hiking, boating and fishing, or the opportunity to just relax in a lovely, quiet setting. Visit the resort website<br />

www.marriott.com/property/propertypage/ATLSR to learn of all the possibilities.<br />

Golf Anyone?<br />

To play in our Sunday Tournament, simply complete the Conference Registration form For additional tee times visit<br />

www.pineislegolf.com for Pine Isle course.<br />

Hotel Reservations<br />

We have reserved rooms at the Pine Isle Resort hotel at the reasonable nightly rate of $119 (plus tax- estimated to be<br />

6%). Our reserved conference rooms will be held for us only until September 14, 2005. Please book your rooms early<br />

directly through the hotel at Tel 770-945-8921, or visit the Pine isle Resort website (Group Code IOAIOAA).<br />

www.marriott.com/property/propertypage/ATLSR. <strong>No</strong>te, shuttles can be arranged from Atlanta airport to the resort<br />

through the hotel at reasonable costs.<br />

Sponsorship<br />

There is ample opportunity for equipment manufacturers and engineering consultants to sponsor events, meals coffee<br />

breaks, conference bags, proceedings, etc. For more information, contact the Pan American office at info@io3a.org<br />

or phone at (480) 529-3787 (Pacific time)<br />

Conference at a Glance<br />

The chart on the following page gives the schedule of all events planned for the conference, including the IOA Board,<br />

committee and task force meetings on the weekend before the conference opens.<br />

This conference will prove to be another excellent conference hosted by PAG. The opportunities to learn more about<br />

ozone technology and network with experts in the field will be outstanding. Plan to attend!<br />

Page <strong>33</strong>


ISSN 1065-5905<br />

<strong>International</strong> <strong>Ozone</strong> <strong>Association</strong>/Editorial Office<br />

P. O. Box 8761<br />

Scottsdale, AZ 85252<br />

Tel: 480-529-3787<br />

Fax: 480-361-7725<br />

Email: info@io3a.org

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