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Conference Program - LOPE-C 2011

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SCIENTIFIC CONF. | THURSDAY-JUNE 30, <strong>2011</strong><br />

Track 4<br />

Inorganic Materials (11:30 am - 01:20 pm) | LOCATION HARMONIE D / LEVEL C2<br />

11:30 am Conductive Ink-Jet Printing of Silver and Air-Stable Copper inks for Flexible and Plastic Electronics<br />

Mr Michael Grouchko,<br />

The Hebrew University of Jerusalem, Israel<br />

One of the greatest challenges in fabrication of flexible and plastic electronics devices by printing is to obtain highly conductive patterns at sufficiently low temperatures<br />

which will not damage the heat sensitive substrates. Another challenge is to achieve it by the use of low cost metallic inks. However, to date, sufficient conductivity of<br />

metallic patterns was achieved usually after prolonged heating at elevated temperatures by the use of highly cost metals (silver and gold), thus limiting fabrication of low<br />

cost plastic devices.<br />

We report new copper based metallic inks which anable to achieve high conductivities of printed patterns. These copper inks contain copper nanoparticles synthesized in<br />

aqueous medium, tailored to be sintered at low temperatures. One of the major challenges while using copper is to prevent its oxidation while exposed to air, which in our<br />

case is prevented by coating the copper core nanoparticles by a thin silver shell.<br />

These approaches allow the formation of low cost conductive patterns on flexible and plastic substrates is enabled, for example, the printing of electroluminescence devices<br />

on PET substrate.<br />

12:00 pm Low temperature processing of inkjet printed metal oxides and nanoparticles<br />

Dr Nenad Marjanovic,<br />

Fraunhofer Institute for Electronic Nano Systems ENAS, Senior Scientist, Germany<br />

Amorphous metal oxides and nanoparticles have numerous advantages due to their atmospheric and temperature stability, as well as relatively high field-effect mobility,<br />

which make them competitive candidates to be integrated into functional devices and electronic systems. However, high sintering temperatures, in some cases up to 400<br />

&deg;C, are required to remove residual organic components upon printing, as well as to sinter the printed film to impart continuity. The organic additives are necessary to<br />

prepare stable solutions or dispersions of these materials as inkjet inks. Therefore, material design, inks formulation, printing and low temperature film formation/processing<br />

are of highest importance, in order to enable the deployment of those materials in electronic systems on polymer substrates (e.g. Polyethylene terephthalate (PET)), which<br />

are commonly used for Printed Electronics. Here, we are reporting on the characterization and application of inkjet printed amorphous Silicon oxide layer on PET. The<br />

sol-gel process was applied for obtaining Silicon oxide ink. The inkjet printing, sintering behavior under room temperature, and the effect of solvent and surfactant on silicon<br />

matrix were investigated. The studies on film formation, morphological and electrical film characterization will be presented. In addition, colloidal Ferromagnetic<br />

nanoparticles synthesized in organic solvents were also inkjet printed. The influence of capping agent such as oleylamine and oleic acid on ferromagnetic nanoparticles<br />

was investigated. Results on room temperature film formation will be presented.<br />

page 87

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