Catalytic Synthesis and Characterization of Biodegradable ...

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Preface Catalytic Synthesis and Characterization of Biodegradable Polyesters and Their Radical Block Copolymers 生分解性ポリエステルおよびそのラジカルブロック共重合体の触媒的合成と特性 Contents Chapter 1 Polymerization and Applications of Biodegradable Polyesters 1.1 Introduction …..2 1.2 Copolymer of Epoxide and Carbon Dioxide …..2 1.3 Polylactide …11 1.4 Others Biodegradable Polyesters …15 1.5 Electroactive Polymers …18 1.6 Radical Polymers …39 References …49 Chapter 2 Synthesis and Electrochemistry of Schiff Base Cobalt(III) Complexes and Their Catalytic Activity for Copolymerization of Epoxide and Carbon Dioxide 2.1 Introduction …60 2.2 Synthesis and Characterization of L-Co III -dnp Complexes …60 2.3 Copolymerization of CO2 and rac-PO …63 2.4 Electrochemistry of Cobalt(III) Complexes …66 2.5 Conclusions …68 2.6 Experimental Section …68 References …71 IV
Chapter 3 Polymerization of Lactic O-Carboxylic Anhydride using Organometallic Catalysts 3.1 Introduction …76 3.2 Polymerization of LacOCA using Co(III) Complexes with Schiff Base Ligands …77 3.3 Polymerization of LacOCA using Tin(II) or Al(III) Based Complexes …79 3.4 Characterization of the Obtained PLA …80 3.5 Conclusions …82 3.6 Experimental Section …82 References …83 Chapter 4 Synthesis of Lactide-Grafted Poly(TEMPO-acrylamide) and its Electrochemical Property and Biocompatibility 4.1 Introduction …86 4.2 Synthesis of PTAm-g-PLA …87 4.3 Electrochemical Properties …90 4.4 Thermal Properties …92 4.5 Phase Separation Behavior of PTAm-g-PLA …92 4.6 Cytotoxicity of PTAm-g-PLA …93 4.7 Cell Adhesion and Spreading …94 4.8 Conclusions …95 4.9 Experimental Section …95 References …98 Chapter 5 Synthesis of Triblock Copolymers of TEMPO-Acrylamide and Lactate by RAFT Polymerization 5.1 Inroduction ..102 5.2 Synthesis of Triblock Copolymer ..103 5.3 Thermal Properties ..105 V
Page 1 and 2: Catalytic Synthesis and Characteriz
Page 3: Preface Biodegradable polyesters ha
Page 7 and 8: Chapter 1 Polymerization and Applic
Page 9 and 10: - 3 - Polymerization and Applicatio
Page 13 and 14: 1.2.2 Aluminum Catalysts - 7 - Poly
Page 17 and 18: 1.3 Polylactide 1.3.1 Introduction
Page 19 and 20: - 13 - Polymerization and Applicati
Page 21 and 22: 1.3.4 Application of PLA Figure 1.3
Page 27 and 28: 1.5.1.4 Polyaniline (PANi) - 21 - P
Page 47 and 48: 1.6.1 Radical Polymers for Organic
Page 51 and 52: initialization of the device by app
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1.6.2.4 Others - 49 - Polymerizatio
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- 51 - Polymerization and Applicati
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182. R. B. Weller, J. Invest. Derma
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Chapter 2 Synthesis and Electrochem
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Synthesis and Electrochemistry of S
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Chapter 3 3.1 Introduction Poly(lac
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Chapter 3 polydispersity index (PDI
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Chapter 3 aluminum based complexes
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Chapter 3 3.5 Conclusions Co(III) c
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Chapter 3 22. Z. H. Tang, X. S. Che
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Chapter 4 4.1 Introduction Stimulus
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Chapter 4 the proton of methenyl gr
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Chapter 4 attributed to the amide g
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Chapter 4 4.4 Thermal Properties Th
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Chapter 4 Figure 4.8 MTT assay for
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Chapter 4 The 1 H NMR and 13 C NMR
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Chapter 4 Cell viability (%) = (Asa
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Chapter 5 Synthesis of Triblock Cop
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5.2 Synthesis of Triblock Copolymer
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Sample Table 1. Feed and result com
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= 25 μm. B: MTT assay for the cyto
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‐ 109 ‐ Synthesis of Triblock C
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‐ 111 ‐ Synthesis of Triblock C
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Chapter 6 6.1 Introduction Since th
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Chapter 6 6.3 Synthesis of MPEG-b-P
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Chapter 6 used to characterize the
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Chapter 6 Figure 6.6 Cyclic voltamm
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Chapter 6 vivo cytotoxicity was als
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Chapter 6 NMR. Characterization of
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Chapter 6 CO2 for 24 h. RSC96 cells
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Chapter 7 Conclusion and Future Pro
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‐ 131 ‐ Conclusion and Future P
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‐ 133 ‐ Conclusion and Future P
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13. Xuan Pang, Xuesi Chen, Xiuli Zh
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Acknowledgments The present thesis
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