Catalytic Synthesis and Characterization of Biodegradable ...

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List of Publications 1. Xiuli Zhuang, Kenichi Oyaizu, Yongsheng Niu, Kenichiroh Koshika, Xuesi Chen, Hiroyuki Nishide, “Synthesis and Electrochemistry of Schiff Base Cobalt(III) Complexes and Their Catalytic Activity for Copolymerization of Epoxide and Carbon Dioxide” Macromol. Chem. Phys., 210, 669-676 (2009). 2. Xiuli Zhuang, Han Zhang, Natsuru Chikushi, Changwen Zhao, Kenichi Oyaizu, Xuesi Chen, Hiroyuki Nishide, “Biodegradable and Electroactive TEMPO-Substituted Acrylamide/Lactide Copolymer” Macromol. Biosci., (2010) in press. 3. Xiuli Zhuang, Chunsheng Xiao, Kenichi Oyaizu, Natsuru Chikushi, Xuesi Chen, Hiroyuki Nishide, “Synthesis of Amphiphilic Block Copolymers bearing Stable Nitroxyl Radicals” J. Polym. Sci., Part A: Polym. Chem.,, (2010), submitted. 4. Xiuli Zhuang, Haiyang Yu, Zhaohui Tang, Kenichi Oyaizu, Hiroyuki Nishide, Xuesi Chen, “Polymerization of Lactic o-Carboxylic Anhydride Using Organometallic Catalysts” Cn. J. Polym. Sci., (2010), in press. 5. Xiuli Zhuang, Han Zhang, Yu Wang, Changwen Zhao, Kenichi Oyaizu, Xuesi Chen, Hiroyuki Nishide, “Synthesis of Biodegradable and TEMPO-Substitute Triblock Copolymers by Combination of ROP and RAFT Polymerization Methods” Polymer, (2010), submitted. 6. Changwen Zhao, Xiuli Zhuang, Pan He, Chunsheng Xiao, Chaoliang He, Jingru Sun, Xuesi Chen, Synthesis of Biodegradable Thermo- and pH-Responsive Hydrogels for Controlled Drug Release, Polymer, 50, 4308-4316 (2009) 7. Zhaopei Guo, Yanhui Li, Huayu Tian, Zhuang Xiuli, Xuesi Chen, Xiabin Jing, Self-Assembly of Hyperbranched Multiarmed PEG-PEI-PLys(Z) Copolymer into Micelles, Rings, and Vesicles, Langmuir, 25, 9690-9696 (2009). 8. Youliang Hong, Yanan Li, Zhuang Xiuli, Xuesi Chen, Xiabin Jing, Electrospinning of Multicomponent Ultrathin Fibrous Nonwovens for Semi-Occlusive Wound Dressings, J. Biomed. Mater. Res. A, 89A, 345-354 (2009). 9. Jun Hu, Lihong Huang, Le Lang, Yadong Liu, Zhuang Xiuli, Xuesi Chen,Yen Wei, Xiabin Jing, The Study of Electroactive Block Copolymer Containing Aniline Pentamer Isolated from Different Solvents, J. Polym. Sci., Part A: Polym. Chem., 47, 1298-1307 (2009). 10. Yongsheng Niu, Hongchun Li, Xuesi Chen, Wanxi Zhang, Zhuang Xiuli, Xiabin Jing, Alternating Copolymerization of Carbon Dioxide and Propylene Oxide Catalyzed by Cobalt Schiff Base Complex, Macromol. Chem. Phys., 210, 1224-1229 (2009). 11. Yongsheng Niu, Wanxi Zhang, Hongchun Li, Xuesi Chen, Jingru Sun, Zhuang Xiuli, Xiabin Jing Carbon Dioxide/Propylene Oxide Coupling Reaction Catalyzed by Chromium Salen Complexes, Polymer, 50, 441-446 (2009). 12. Chunsheng Xiao, Huayu Tian, Zhuang Xiuli, Xuesi Chen, Xiabin Jing, Recent Developments in Intelligent Biomedical Polymers, Sci. China Ser B., 52, 117-130 (2009).
13. Xuan Pang, Xuesi Chen, Xiuli Zhuang, Xiabin Jing, Crown-Like Macrocycle Zinc Complex Derived from β-Diketone Ligand for the Polymerization of rac-Lactide, J. Polym. Sci., Part A: Polym. Chem., 46, 643–649 (2008). 14. Lihong Huang, Xiuli Zhuang, Jun Hu, Le Lang, Peibiao Zhang, Yu Wang, Xuesi Chen, Yen Wei, and Xiabin Jing, Synthesis of Biodegradable and Electroactive Multiblock Polylactide and Aniline Pentamer Copolymer for Tissue Engineering Applications, Biomacromolecules, 9, 850-858 (2008). 15. Jun Hu, Lihong Huang, Xiuli Zhuang, Xuesi Chen, Yen Wei, Xiabing Jing, New Oxidation State of Aniline Pentamer Observed in Water-Soluble Electroactive Oligoaniline-Chitosan Polymer, J. Polym. Sci., Part A: Polym. Chem.,46, 1124–1135 (2008). 16. Lihong Huang, Jun Hu, Le Lang, Xiuli Zhuang, Xuesi Chen, Yen Wei, Xiabin Jing, “Sandglass’’-Shaped Self-Assembly of Coil–rod–coil Triblock Copolymer Containing Rigid Aniline-Pentamer, Macromol. Rapid Commun., 29, 1242–1247 (2008). 17. Li Chen, Zhigang Xie, Xiuli Zhuang, Xuesi Chen, Xiabin Jing, Controlled Release of Urea Encapsulated by Starch-g-poly(L-lactide), Carbohyd. Polym., 72, 342–348 (2008). 18. Chaoliang He, Changwen Zhao, Xinhua Guo, Zhaojun Guo, Xuesi Chen, Xiuli Zhuang, Shuying Liu, Xiabin Jing, Novel Temperature- and pH-Responsive Graft Copolymers Composed of Poly(L-glutamic acid) and Poly(N-isopropylacrylamide), J. Polym. Sci., Part A: Polym. Chem., 46, 4140–4150 (2008). 19. Chaoliang He, Changwen Zhao, Xuesi Chen, Zhaojun Guo, Xiuli Zhuang, Xiabin Jing, Novel pH- and Temperature-Responsive Block Copolymers with Tunable pH-Responsive Range, Macromol. Rapid. Commun., 29, 490–497 (2008). 20. Li Chen , Xiuli Zhuang , Ge Sun , Xuesi Chen , XiabinJing, An Approach to Synthesize Poly(ethylene glycol)-b-poly(epsilon-caprolactone) with Terminal Amino Group via Schiff's Base as An Initiator, Cn. J. Polym. Sci., 26, 455-463 (2008). 21. Xueyu Qiu, Yadong Han, Xiuli Zhuang, Xuesi Chen, Yuesheng Li, Xiabin Jing, Preparation of Nano-Hydroxyapatite/Poly(L-lactide) Biocomposite Microspheres, J. Nanopaticle Res., 9, 901-908, (2007). 22. Yongsheng Niu, Wanxi Zhang, Xuan Pang, Xuesi Chen, Xiuli Zhuang, Xiabin Jing, Alternating Copolymerization of Carbon Dioxide and Propylene Oxide Catalyzed by (R,R)-SalenCo(III)-(2,4-dinitrophenoxy) and Lewis-Basic Cocatalyst, J. Polym. Sci., Part A: Polym. Chem., 45, 5050-5056 ( 2007). 23. Junli Hu, Yadong Han, Xiuli Zhuang, Xuesi Chen, Yuesheng Li, Xiabin Jing, Self-Assembly of a Polymer Pair Through Poly(lactide) Stereocomplexation, Nanotechnology, 18, 185607 (2007). 24. Hongzhi Du, Xuan Pang, Haiyang Yu, Xiuli Zhuang, Xuesi Chen, Dongmei Cui, Xianhong Wang, Xiabin Jing, Polymerization of rac-Lactide Using Schiff Base Aluminum Catalysts: Structure, Activity, and Stereoselectivity, Macromolecules, 40, 1904-1913 (2007). 25. Chaoliang He, Jingru Sun, Ting Zhao, Zhongkui Hong, Xiuli Zhuang, Xuesi Chen, Xiabin Jing,
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Catalytic Synthesis and Characteriz
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Preface Biodegradable polyesters ha
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Chapter 3 Polymerization of Lactic
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Chapter 1 Polymerization and Applic
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- 3 - Polymerization and Applicatio
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1.2.2 Aluminum Catalysts - 7 - Poly
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1.3 Polylactide 1.3.1 Introduction
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- 13 - Polymerization and Applicati
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1.3.4 Application of PLA Figure 1.3
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1.5.1.4 Polyaniline (PANi) - 21 - P
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1.6.1 Radical Polymers for Organic
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initialization of the device by app
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1.6.2.4 Others - 49 - Polymerizatio
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182. R. B. Weller, J. Invest. Derma
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Chapter 2 Synthesis and Electrochem
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Synthesis and Electrochemistry of S
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Chapter 3 3.1 Introduction Poly(lac
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Chapter 3 polydispersity index (PDI
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Chapter 3 aluminum based complexes
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Chapter 3 3.5 Conclusions Co(III) c
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Chapter 3 22. Z. H. Tang, X. S. Che
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Chapter 4 4.1 Introduction Stimulus
Page 96 and 97: Chapter 4 the proton of methenyl gr
Page 98 and 99: Chapter 4 attributed to the amide g
Page 100 and 101: Chapter 4 4.4 Thermal Properties Th
Page 102 and 103: Chapter 4 Figure 4.8 MTT assay for
Page 104 and 105: Chapter 4 The 1 H NMR and 13 C NMR
Page 106 and 107: Chapter 4 Cell viability (%) = (Asa
Page 109 and 110: Chapter 5 Synthesis of Triblock Cop
Page 111 and 112: 5.2 Synthesis of Triblock Copolymer
Page 113 and 114: Sample Table 1. Feed and result com
Page 115 and 116: = 25 μm. B: MTT assay for the cyto
Page 117 and 118: ‐ 109 ‐ Synthesis of Triblock C
Page 119: ‐ 111 ‐ Synthesis of Triblock C
Page 124 and 125: Chapter 6 6.1 Introduction Since th
Page 126 and 127: Chapter 6 6.3 Synthesis of MPEG-b-P
Page 128 and 129: Chapter 6 used to characterize the
Page 130 and 131: Chapter 6 Figure 6.6 Cyclic voltamm
Page 132 and 133: Chapter 6 vivo cytotoxicity was als
Page 134 and 135: Chapter 6 NMR. Characterization of
Page 136 and 137: Chapter 6 CO2 for 24 h. RSC96 cells
Page 141 and 142: Chapter 7 Conclusion and Future Pro
Page 143 and 144: ‐ 131 ‐ Conclusion and Future P
Page 145: ‐ 133 ‐ Conclusion and Future P
Page 149: Acknowledgments The present thesis
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