Application Compendium - Agilent Technologies

More documents

Recommendations

Info

Table 1. Chemical Information of Antioxidants and Tinuvin P Name: Vitamin E DL-all-rac-α-Tocopherol Formula: C29H50O2 Molecular Weight: 430.71 CAS No.: 10191-41-0 Name: Irgafos 168 Tris(2,4 di-tert-butylphenyl) phosphite Formula: [[(CH3)3C]2C6H3O]3P Molecular Weight: 646.92 CAS No.: 31570-04-4 Name: Irganox 3114 Tris(3,5-di-tert-butyl-4-hydroxybenzyl) isocyanurate Formula: Molecular Weight: C48H69N3O6 784.08 3 O C(CH3 ) 3 CAS No.: 27676-62-6 N N OH C (CH 3) HO Name: Erucamide cis-13-docosenamide Formula: CH3(CH2)7CH=CH(CH2)11CONH2 Molecular Weight: 337.58 CAS No.: 112-84-5 2 C H 3 CH 3 N H 2 CH 3 H3C C CH 3 3C (CH 3) O C CH3 C CH 3 CH3C C H 3 CH 3 O CH 3 C O CH 3 CH 3 O P CH 3 CH 3 O N 3C (CH 3) CH 3 CH 3 CH2 (CH2 ) 9 CH2 C H CH 3 C CH 3 O OH CH3 C C CH 3 CH 2 (CH 2 ) 6 CH 3 H CH3 CH3 O CH3 CH 3 C(CH 3 ) 3 C(CH 3 ) 3 CH 3 OH
Table 1. Chemical Information of Antioxidants and Tinuvin P (Continued) Name: Irganox 1010 Pentaerythritol tetrakis Formula: [HOC6H2[C(CH3)3]2CH2CH2CO2CH2]4C (3,5-di-tert-butyl-4-hydroxyhydrocinnamate) Molecular Weight: 1177.63 CAS No.: 6683-19-8 Name: Irganox 1076 Octadecyl 3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate Formula: [(CH3)3C]2C6H2(OH)CH2CH2CO2(CH2)17CH3 CH3 Molecular Weight: CAS No.: 530.86 2082-79-3 CH3 C CH3 O Name: Tinuvin P 2-(2-hydroxy-5-methylphenyl)benzotriazole Formula: C13H11N3O Molecular Weight: 225.25 CAS No.: 2440-22-4 Experimental System Agilent 1200 Series Rapid Resolution LC (RRLC), consisting of: G1379B micro vacuum degasser G1312B binary pump SL G1367C high-performance autosampler SL G1316B thermostatted column compartment SL G1315C UV/VIS diode array detector SL with 3 mm, 2 µL flow cell ChemStation 32-bit version B.02.01-SR1 Columns Agilent ZORBAX Eclipse XDB-C18, 4.6 mm × 150 mm, 5 µm Agilent ZORBAX Eclipse XDB-C8, 4.6 mm × 150 mm, 5 µm Agilent ZORBAX Eclipse XDB-C8, 4.6 mm × 100 mm, 3.5 µm Agilent ZORBAX Eclipse XDB-C8, 4.6 mm × 50 mm, 1.8 µm Agilent ZORBAX Eclipse XDB-C8, 3.0 mm × 100 mm, 3.5 µm Agilent ZORBAX Eclipse XDB-C8, 3.0 mm × 50 mm, 1.8 µm HO CH 3 CH 3 HO CH 3 C CH 3 CH 3 C CH3 C CH3 CH 3 CH 3 N N N HO CH 2 CH 2 C OCH 2 (CH 2 ) 16 CH 3 CH 3 Mobile Phase Gradients: A: water B: acetonitrile (ACN) Gradient conditions: See individual chromatograms Column temperature See individual chromatograms Samples 1. Standard mixture of Tinuvin P, Erucamide, Irganox 3114, Irganox 1010, Vitamin E, Irganox 1076, and Irgafos168, all 200 μg/mL in isopropanol 2. Polypropylene Homopolymer Formulation, from customer, extracted by ultrasonic according to the method ASTM D6042-04 3. Polypropylene extract spiked with 20 μg/mL standard mixture O 4 CH 2 CH 2 C OCH 2 C 3
Page 1 and 2:
MATERIALS TESTING AND RESEARCH SOLU
Page 3 and 4:
When accuracy and reliability in me
Page 5 and 6:
AGILENT TECHNOLOGIES APPLICATIONS F
Page 7 and 8:
Figure 1. Agilent Cary 630 FTIR spe
Page 9 and 10:
The calibration samples were measur
Page 11 and 12:
Author Frank Higgins Agilent Techno
Page 13 and 14:
Figure 1. The overlaid aliphatic be
Page 15 and 16:
Author John Seelenbinder Agilent Te
Page 17 and 18:
Figure 3. Sample is lightly pressed
Page 19 and 20:
Author Dr. Mustafa Kansiz Agilent T
Page 21 and 22:
microscopy provides for a factor of
Page 23 and 24:
Standard ATR IR Image No Pressure (
Page 25 and 26:
A visual inspection of the sample u
Page 27 and 28:
Experimental Instrumentation To per
Page 29 and 30:
Authors Jonah Kirkwood † and Must
Page 31 and 32:
Spectra were collected from each lo
Page 33 and 34:
Infrared mapping allows for multipl
Page 35 and 36:
The spectra in Figure 2 are visuall
Page 37 and 38:
Conclusion Agilent‟s Cary 610 FTI
Page 39 and 40:
Authors Dr. Wayne Collins*, John Se
Page 41 and 42:
The calibration curve obtained for
Page 43 and 44:
Conclusion Select ‘Peak Ratio’
Page 45 and 46:
Summary This method describes a pro
Page 47 and 48:
Method configuration To determine t
Page 49 and 50:
Page 51 and 52:
The calibration curve for the deter
Page 53 and 54:
Figure 6. The MicroLab PC FTIR soft
Page 55 and 56:
Summary An analytically representat
Page 57 and 58:
Figure 3. The Irganox 1010 peak are
Page 59 and 60:
Page 61 and 62:
The calibration curve and equation
Page 63 and 64:
Select ‘Peak Ratio’ - from the
Page 65 and 66:
Summary An analytically representat
Page 67 and 68:
Figure 3. The GMS peak height absor
Page 69 and 70:
Advanced Atomic Force Microscopy: E
Page 71 and 72:
signal) image indicating the overwh
Page 73 and 74:
A dependence of surface potential o
Page 75 and 76:
A B C Figure 6A-C. The topography (
Page 77 and 78:
A B Figure 10A-C. The topography (A
Page 79 and 80:
KFM with AM-FM operation in the int
Page 81 and 82:
ibbons is only slightly different f
Page 83 and 84:
References 1. G. Binnig, C.F. Quate
Page 85 and 86:
Figure 1. AFM topographic image of
Page 87 and 88: 100nm 100nm 350nm 100nm Figure 3. A
Page 89 and 90: to perfect hexagonal patterns, whic
Page 91 and 92: Single-pass KFM studies have been k
Page 93 and 94: images due to the difference of the
Page 95 and 96: 0.5 V) of the nanowires. Additional
Page 97 and 98: appeared in the topography image. T
Page 99 and 100: of PSS component. TEM studies of mo
Page 101 and 102: Atomic Force Microscopy Studies in
Page 103 and 104: on graphite and MoS2 are shown in F
Page 105 and 106: A B C D Scan size: 5 µm. Scan size
Page 107 and 108: images of PEDOT:PSS blend, (PEDOT -
Page 109 and 110: Young’s Modulus of Dielectric ‘
Page 111 and 112: Figure 3. Young’s modulus as a fu
Page 113 and 114: Nanoindentation, Scratch, and Eleva
Page 115 and 116: The samples listed as “D” sampl
Page 117 and 118: Figure 6. Elastic modulus results f
Page 119 and 120: Figure 11. Elastic modulus results
Page 121 and 122: Sample B Figure 16. Scratch curves
Page 123 and 124: Conclusions Nanoindentation and scr
Page 125 and 126: measurement technique has been expl
Page 127 and 128: References 1. J.L. Hay, “Using In
Page 129 and 130: Theory The complex shear modulus (G
Page 131 and 132: References 1. Jain, S.K., Bhattacha
Page 133 and 134: LCCC relies on carrying out isocrat
Page 135 and 136: log Mp 5 4.6 4.2 3.8 0.5 15% Water
Page 137: Authors Wei Luan and Chunxiao Wang
Page 141 and 142: Injection Volume Influence of Real
Page 143 and 144: translator into three modes on diff
Page 145 and 146: To identify the matrix influence on
Page 147 and 148: Authors Chun-Xiao Wang and Wei Luan
Page 149 and 150: Table 1. Polymer Additives in ASTM
Page 151 and 152: 1 2 3 4 5 1 Tinuvin P 2 BHT 3 BHEB
Page 153 and 154: 1 Tinuvin P 2 BHT 3 BHEB 4 Isonox 1
Page 155 and 156: Authors Edgar Naegele Agilent Techn
Page 157 and 158: Results and discussion To meet the
Page 159 and 160: Authors Melissa Dunkle, Gerd Vanhoe
Page 161 and 162: Experimental The analyses were perf
Page 163 and 164: Repeatability of the SFC/MS analysi
Page 165 and 166: Conclusion The combination of the A
Page 167 and 168: Introduction Phthalates form a grou
Page 169 and 170: The analytical method was applied t
Page 171 and 172: Introduction Bisphenol A (BPA) is a
Page 173 and 174: Preparation of standards BPA and BP
Page 175 and 176: Limit of Detection (LOD) and Limit
Page 177 and 178: Sample analysis The content of BPA
Page 179 and 180: The calibration for BPA and BPF, wh
Page 181 and 182: Author Stephen Ball Agilent Technol
Page 183 and 184: Results and discussion By operating
Page 185 and 186: Introduction The wavelength of UV r
Page 187 and 188: LC parameters Premixed solutions of
Page 189 and 190:
Linearity A linearity study was per
Page 191 and 192:
References 1. Dr. James H. Gibson,
Page 193 and 194:
Instrumentation Columns: 2 x PLgel
Page 195 and 196:
Authors Greg Saunders and Ben MacCr
Page 197 and 198:
Authors Greg Saunders, Ben MacCreat
Page 199 and 200:
Page 201 and 202:
Page 203 and 204:
Page 205 and 206:
Author Greg Saunders Agilent Techno
Page 207 and 208:
Figure 5. Universal calibration cur
Page 209 and 210:
Methods and Materials Conditions Co
Page 211 and 212:
Materials and Methods A column set
Page 213 and 214:
Page 215 and 216:
show all

Application Compendium - Agilent Technologies

Create successful ePaper yourself

Delete template?

Save as template?