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safety data sheet 790 - EGO - Dichtstoffwerke

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Safety Data Sheet<br />

according to Regulation (EC) No 1907/2006<br />

<strong>EGO</strong>CON <strong>790</strong><br />

<strong>EGO</strong> <strong>Dichtstoffwerke</strong> GmbH & Co.Betriebs KG<br />

Print date: 22.05.2012 Product code: 662<br />

Page 1 of 7<br />

SECTION 1: Identification of the substance/mixture and of the company/undertaking<br />

Product identifier<br />

Product group:<br />

<strong>EGO</strong>CON <strong>790</strong><br />

Primer<br />

Relevant identified uses of the substance or mixture and uses advised against<br />

Use of the substance/mixture<br />

Primer for Silicone Sealant<br />

Details of the supplier of the <strong>safety</strong> <strong>data</strong> <strong>sheet</strong><br />

Company name:<br />

Street:<br />

Place:<br />

Post-office box:<br />

<strong>EGO</strong> <strong>Dichtstoffwerke</strong> GmbH & Co.Betriebs KG<br />

Lilienthalstraße 7<br />

D-82205 Gilching<br />

1347<br />

D-82198 Gilching<br />

Telephone: +49 8105 217-0 Telefax:+49 8105 217-37<br />

e-mail: Paulus@ego.de<br />

Contact person: Mrs. Paulus<br />

Telephone: - 34<br />

Internet:<br />

Responsible Department:<br />

Emergency telephone:<br />

SECTION 2: Hazards identification<br />

http://www.ego.de<br />

export<br />

Classification of the substance or mixture<br />

Label elements<br />

+49 89 19240<br />

Indications of danger : Highly flammable, Harmful, Irritant, Dangerous for the environment<br />

R-phrases:<br />

Highly flammable.<br />

Irritating to eyes and skin.<br />

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.<br />

Harmful: may cause lung damage if swallowed.<br />

Vapours may cause drowsiness and dizziness.<br />

Danger symbols: F - Highly flammable; Xn - Harmful; N - Dangerous for the environment<br />

F - Highly flammable Xn - Harmful N - Dangerous for the<br />

environment<br />

Hazardous components which must be listed on the label<br />

C7-C10 Isoalkane<br />

R phrases<br />

11 Highly flammable.<br />

36/38 Irritating to eyes and skin.<br />

51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.<br />

65 Harmful: may cause lung damage if swallowed.<br />

67 Vapours may cause drowsiness and dizziness.<br />

Revision No: 1,00 GB - EN<br />

Revision date: 01.09.2011


Safety Data Sheet<br />

according to Regulation (EC) No 1907/2006<br />

<strong>EGO</strong>CON <strong>790</strong><br />

<strong>EGO</strong> <strong>Dichtstoffwerke</strong> GmbH & Co.Betriebs KG<br />

Print date: 22.05.2012 Product code: 662<br />

Page 2 of 7<br />

S phrases<br />

02 Keep out of the reach of children.<br />

09 Keep container in a well-ventilated place.<br />

16 Keep away from sources of ignition - No smoking.<br />

23 Do not breathe vapour .<br />

56 Dispose of this material and its container at hazardous or special waste collection point.<br />

61 Avoid release to the environment. Refer to special instructions / Safety <strong>data</strong> <strong>sheet</strong>s.<br />

62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container<br />

or label.<br />

SECTION 3: Composition/information on ingredients<br />

Mixtures<br />

Chemical characterization<br />

silanes and siloxanes with functional groups + auxiliary material in solvent<br />

Hazardous components<br />

EC No Chemical name<br />

CAS No<br />

Classification<br />

Index No<br />

GHS classification<br />

REACH No<br />

292-458-5<br />

90622-56-3<br />

227-006-8<br />

5593-70-4<br />

203-625-9<br />

108-88-3<br />

601-021-00-3<br />

201-083-8<br />

78-10-4<br />

014-005-00-0<br />

C7-C10 Isoalkane<br />

F, Xn, Xi, N R11-38-65-67-51-53<br />

Titantetrabutanolat<br />

Xi R10-38-41<br />

toluene<br />

F, Repr. Cat. 3, Xn, Xi R11-63-48/20-65-38-67<br />

Flam. Liq. 2, Repr. 2, Asp. Tox. 1, STOT RE 2, Skin Irrit. 2, STOT SE 3; H225 H361d<br />

*** H304 H373 ** H315 H336<br />

ethyl silicate, tetraethyl silicate<br />

Xn, Xi R10-20-36/37<br />

Full text of R- and H-phrases: see section 16.<br />

SECTION 4: First aid measures<br />

Description of first aid measures<br />

Flam. Liq. 3, Acute Tox. 4, Eye Irrit. 2, STOT SE 3; H226 H332 H319 H335<br />

After inhalation<br />

Move to fresh air in case of accidental inhalation of vapours. If not breathing, give artificial<br />

respiration.<br />

If you feel unwell, seek medical advice (show the label where possible).<br />

After contact with skin<br />

Wash off with soap and water. Take off all contaminated clothing immediately.<br />

After contact with eyes<br />

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.<br />

After ingestion<br />

Do NOT induce vomiting. Danger of inhalation Show this <strong>safety</strong> <strong>data</strong> <strong>sheet</strong> to the doctor in<br />

attendance.<br />

Revision No: 1,00 GB - EN<br />

Revision date: 01.09.2011<br />

Quantity<br />

> 75 %<br />

< 10 %<br />

< 5 %<br />

< 2,5 %


Safety Data Sheet<br />

according to Regulation (EC) No 1907/2006<br />

<strong>EGO</strong>CON <strong>790</strong><br />

<strong>EGO</strong> <strong>Dichtstoffwerke</strong> GmbH & Co.Betriebs KG<br />

Print date: 22.05.2012 Product code: 662<br />

Page 3 of 7<br />

SECTION 5: Firefighting measures<br />

Extinguishing media<br />

Suitable extinguishing media<br />

Water spray, Dry powder, Foam, Carbon dioxide (CO2).<br />

Extinguishing media which must not be used for <strong>safety</strong> reasons<br />

High volume water jet<br />

Special hazards arising from the substance or mixture<br />

Combustion may provoke smoke emission.<br />

Advice for firefighters<br />

In the event of fire, wear self-contained breathing apparatus.<br />

Additional information<br />

Standard procedure for chemical fires.<br />

SECTION 6: Accidental release measures<br />

Personal precautions, protective equipment and emergency procedures<br />

Use personal protective equipment. Do not breathe vapours or spray mist. Ensure adequate<br />

ventilation, especially in confined areas. Avoid contact with skin and eyes.<br />

Environmental precautions<br />

Do not flush into surface water or sanitary sewer system. Inform the responsible authorities in case of<br />

gas leakage, or of entry into waterways, soil or drains.<br />

Methods and material for containment and cleaning up<br />

Use mechanical handling equipment. Soak up with inert absorbent material (e.g. sand, silica gel, acid<br />

binder, universal binder, sawdust). Treat recovered material as described in the section "Disposal<br />

considerations".<br />

Reference to other sections<br />

Remove all sources of ignition.<br />

SECTION 7: Handling and storage<br />

Precautions for safe handling<br />

Advice on safe handling<br />

Provide sufficient air exchange and/or exhaust in work rooms.<br />

Advice on protection against fire and explosion<br />

Take measures to prevent the build up of electrostatic charge.<br />

Processing may lead to evolution of flammable volatiles. Vapours may form explosive mixtures with<br />

air.<br />

Keep away from sources of ignition - No smoking.<br />

Keep product and empty container away from heat and sources of ignition.<br />

Conditions for safe storage, including any incompatibilities<br />

Requirements for storage rooms and vessels<br />

Keep containers tightly closed in a dry, cool and well-ventilated place.<br />

Advice on storage compatibility<br />

No special precautions required.<br />

Further information on storage conditions<br />

Keep containers dry and tightly closed to avoid moisture absorption and contamination.<br />

SECTION 8: Exposure controls/personal protection<br />

Revision No: 1,00 GB - EN<br />

Revision date: 01.09.2011


Safety Data Sheet<br />

according to Regulation (EC) No 1907/2006<br />

<strong>EGO</strong>CON <strong>790</strong><br />

<strong>EGO</strong> <strong>Dichtstoffwerke</strong> GmbH & Co.Betriebs KG<br />

Print date: 22.05.2012 Product code: 662<br />

Page 4 of 7<br />

Control parameters<br />

Exposure limits (EH40)<br />

CAS No Chemical name<br />

ml/m³ mg/m³ F/ml Category<br />

Origin<br />

71-36-3 Butan-1-ol<br />

-<br />

- TWA (8 h) WEL<br />

50 154 STEL (15 min) WEL<br />

64-17-5 Ethanol<br />

1000 1920 TWA (8 h) WEL<br />

- - STEL (15 min) WEL<br />

108-88-3 Toluene<br />

50 191 TWA (8 h) WEL<br />

Exposure controls<br />

100 384 STEL (15 min) WEL<br />

Protective and hygiene measures<br />

When using, do not eat, drink or smoke. Do not breathe vapours or spray mist. Avoid contact with the<br />

skin and the eyes.<br />

Respiratory protection<br />

Ensure adequate ventilation, especially in confined areas. When workers are facing concentrations<br />

above the exposure limit they must use appropriate certified respirators. (gas filter type A)<br />

Hand protection<br />

Solvent-resistant gloves (butyl-rubber)<br />

Eye protection<br />

Tightly fitting <strong>safety</strong> goggles<br />

Skin protection<br />

Protective suit<br />

Environmental exposure controls<br />

Avoid subsoil penetration. Do not flush into surface water or sanitary sewer system.<br />

SECTION 9: Physical and chemical properties<br />

Information on basic physical and chemical properties<br />

Physical state:<br />

Colour:<br />

Odour:<br />

liquid<br />

light yellow<br />

characteristic<br />

pH-Value: ca. 7<br />

Changes in the physical state<br />

Melting point:<br />

Boiling point:<br />

Flash point:<br />

Lower explosion limits:<br />

Upper explosion limits:<br />

Ignition temperature:<br />

not applicable<br />

116 - 142 °C<br />

9 °C<br />

0,9 vol. %<br />

7,0 vol. %<br />

420 °C<br />

Vapour pressure:<br />

(at 20 °C)<br />

8 hPa<br />

Density (at 20 °C): 0,75 g/cm³<br />

Water solubility: insoluble<br />

Test method<br />

Revision No: 1,00 GB - EN<br />

Revision date: 01.09.2011


Safety Data Sheet<br />

according to Regulation (EC) No 1907/2006<br />

<strong>EGO</strong>CON <strong>790</strong><br />

<strong>EGO</strong> <strong>Dichtstoffwerke</strong> GmbH & Co.Betriebs KG<br />

Print date: 22.05.2012 Product code: 662<br />

Page 5 of 7<br />

Viscosity / dynamic:<br />

(at 20 °C)<br />

SECTION 10: Stability and reactivity<br />

Reactivity<br />

No dangerous reaction known under conditions of normal use.<br />

Conditions to avoid<br />

Heat, flames and sparks. humid air and water.<br />

Incompatible materials<br />

Oxidizing agents, Acids, Bases; Water.<br />

Hazardous decomposition products<br />

No decomposition if used as directed.<br />

SECTION 11: Toxicological information<br />

Information on toxicological effects<br />

Acute toxicity<br />

No <strong>data</strong> is available on the product itself.<br />

CAS No<br />

108-88-3 toluene<br />

Chemical name<br />

ca. 0,76 mPa·s<br />

Exposure routes Method Dose Species<br />

Source<br />

dermal<br />

78-10-4 ethyl silicate, tetraethyl silicate<br />

oral<br />

dermal<br />

LD50 12200<br />

mg/kg<br />

Rabbit<br />

GESTIS<br />

LD50 6270 mg/kg Rat<br />

GESTIS<br />

LD50 5880 mg/kg Rabbit<br />

GESTIS<br />

Further information<br />

Harmful by inhalation and in contact with skin. Repeated or prolonged contact with the preparation<br />

may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and<br />

absorption through the skin.<br />

SECTION 12: Ecological information<br />

Toxicity<br />

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.<br />

CAS No Chemical name<br />

108-88-3<br />

Aquatic toxicity Method Dose h Species<br />

Source<br />

toluene<br />

Bioaccumulative potential<br />

Acute fish toxicity LC50 13 mg/l 96 Carassius auratus<br />

IUCLID<br />

Acute algae toxicity ErC50 12,5 mg/l 72 Algen<br />

GESTIS<br />

Partition coefficient n-octanol/water<br />

CAS No Chemical name<br />

108-88-3 toluene 2,73<br />

Results of PBT and vPvB assessment<br />

Log Pow<br />

Revision No: 1,00 GB - EN<br />

Revision date: 01.09.2011


Safety Data Sheet<br />

according to Regulation (EC) No 1907/2006<br />

<strong>EGO</strong>CON <strong>790</strong><br />

<strong>EGO</strong> <strong>Dichtstoffwerke</strong> GmbH & Co.Betriebs KG<br />

Print date: 22.05.2012 Product code: 662<br />

Page 6 of 7<br />

This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).<br />

SECTION 13: Disposal considerations<br />

Waste treatment methods<br />

Advice on disposal<br />

Can be incinerated, when in compliance with local regulations.<br />

Contaminated packaging<br />

Empty remaining contents. Dispose of in accordance with local regulations.<br />

SECTION 14: Transport information<br />

Land transport (ADR/RID)<br />

UN number:<br />

UN proper shipping name:<br />

Transport hazard class(es):<br />

Packing group:<br />

Hazard No:<br />

1993<br />

1993 - Flammable liquid, n.o.s.<br />

3<br />

II<br />

33<br />

Other applicable information (land transport)<br />

Contains C7-C10 Isoalkane<br />

Marine transport<br />

UN number:<br />

UN proper shipping name:<br />

Transport hazard class(es):<br />

Packing group:<br />

Marine pollutant:<br />

1993<br />

1993 - Flammable liquid, n.o.s.<br />

3<br />

II<br />

ja<br />

Other applicable information (marine transport)<br />

Contains C7-C10 Isoalkane<br />

Air transport<br />

UN/ID number:<br />

UN proper shipping name:<br />

Transport hazard class(es):<br />

Packing group:<br />

Other applicable information (air transport)<br />

Contains C7-C10 Isoalkane<br />

SECTION 15: Regulatory information<br />

1993<br />

1993 - Flammable liquid, n.o.s.<br />

3<br />

II<br />

Safety, health and environmental regulations/legislation specific for the substance or mixture<br />

EU regulatory information<br />

1999/13/EC (VOC):<br />

National regulatory information<br />

Water contaminating class (D):<br />

SECTION 16: Other information<br />

83 %<br />

2 - water contaminating<br />

Full text of R-phrases referred to under sections 2 and 3<br />

10 Flammable.<br />

Revision No: 1,00 GB - EN<br />

Revision date: 01.09.2011


Safety Data Sheet<br />

according to Regulation (EC) No 1907/2006<br />

<strong>EGO</strong>CON <strong>790</strong><br />

<strong>EGO</strong> <strong>Dichtstoffwerke</strong> GmbH & Co.Betriebs KG<br />

Print date: 22.05.2012 Product code: 662<br />

Page 7 of 7<br />

11 Highly flammable.<br />

20 Harmful by inhalation.<br />

36/37 Irritating to eyes and respiratory system.<br />

36/38 Irritating to eyes and skin.<br />

38 Irritating to skin.<br />

41 Risk of serious damage to eyes.<br />

48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.<br />

51 Toxic to aquatic organisms.<br />

51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.<br />

53 May cause long-term adverse effects in the aquatic environment.<br />

63 Possible risk of harm to the unborn child.<br />

65 Harmful: may cause lung damage if swallowed.<br />

67 Vapours may cause drowsiness and dizziness.<br />

Full text of H-Statements referred to under sections 2 and 3<br />

H225 Highly flammable liquid and vapour.<br />

H226 Flammable liquid and vapour.<br />

H304 May be fatal if swallowed and enters airways.<br />

H315 Causes skin irritation.<br />

H318 Causes serious eye damage.<br />

H319 Causes serious eye irritation.<br />

H332 Harmful if inhaled.<br />

H335 May cause respiratory irritation.<br />

H336 May cause drowsiness or dizziness.<br />

H361d Suspected of damaging the unborn child.<br />

H373 May cause damage to organs through prolonged or repeated exposure.<br />

H411 Toxic to aquatic life with long lasting effects.<br />

Further Information<br />

These <strong>data</strong> describe only the <strong>safety</strong> requirements for the product(s) and are based on our present<br />

knowledge. However, they do not constitute a guarantee for any specific product features and shall<br />

not establish a legally valid contractual relationship.<br />

(The <strong>data</strong> for the hazardous ingredients were taken respectively from the last version of the sub-contractor's<br />

<strong>safety</strong> <strong>data</strong> <strong>sheet</strong>.)<br />

Revision No: 1,00 GB - EN<br />

Revision date: 01.09.2011

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