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Dames & Moore, 1999 - USDA Forest Service

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Sources<br />

The mining related waste contained within tailings piles 1, 2 and 3 is assumed to represent the source area<br />

for potential human health exposure of metals of concern for the Site. The former mill building may also<br />

act as a relatively minor metals source area In addition, a former storage area immediately north of the mill<br />

was identified as a potential source of polychlorinated biphenyl (PCB) and petroleum hydrocarbons.<br />

Potential Mieration Pathwaw<br />

The mining related wastes and former storage area may contribute compounds of concern to air. surface<br />

water, seeps, mine portal drainage, sediment, groundwater, and soil (surface and subsurface) at the Site. The<br />

potential for site constituents to migrate from source media to points of exposure depends on their<br />

distribution, physical and chemical properties of the constituents of concern, and properties of the media.<br />

Transfer to these environmental media may occur via one or more of the following general mechanisms:<br />

Leaching: Migration of Constituents from Soil or Mining Wastes to Groundwater,<br />

Surface Water, and ~edimeni The infiltration of precipitation into the soil and tailings<br />

and subsequent leaching into groundwater may result in the transfer of Site constituents<br />

to the groundwater. This leaching process depends on several physical and chemical<br />

characteristics of the constituents and the soil and tailings, including water solubility,<br />

octanoVwater partition coefficient, oxidation/reduction potential, mineralogy, organic<br />

carbon content, cation exchange capacity, and soiVtailings surface area. PCBs tend to be<br />

tightly bound to the soil. The potential for metals to leach depends on the state of the<br />

metal and soihilings characteristics. Once Site constituents reach groundwater, they<br />

can migrate laterally and venically in groundwater throu& gross fluid movement and<br />

dispersion. The rate of migration is dependent on aquifer characteristics and chemical<br />

and physical characteristics of the constituent. Hydrophobic and cationic constituents<br />

(e.g., PCBs) will migrate slower than water soluble and nonionic constituents (e.g..<br />

metals). Additionally, Site constituents in groundwater can be transferred to surface<br />

water through seeps or directly to a surface water body, and, in the case of the Holden<br />

Mine, through mine portal drainage. Groundwater at the Site may discharge through<br />

these mechanisms into Railroad and Copper Creeks. Once in surface water bodies, some<br />

Site constituents have the potential of accumulating in sediment andfor fish.<br />

Runoff: Migration of Constituents from Soil or Mining Wastes to Surface Water<br />

and Sediment. Precipitation can carry Site-related constituents or suspended soil or<br />

tailings into surface water bodies such as Railroad Creek and Copper Creek through<br />

' storm water runoff processes. Erosion of the tailings pile also contributes Site<br />

constituents to surface water. Once in surface water bodies, some Site constituents have<br />

the potential of accumulating in sediment and/or fish.<br />

Suspension: Migration of Constituents from Soils or Mining Wastes to Air. The<br />

transfer of constituents present in soils or tailings to the air may occur through agitation<br />

of the surface soils resulting in the generation of fugitive particulate emissions.<br />

Volatilization is considered an insignificant migration pathway since the constituents<br />

associated with the Site are nonvolatile metals and ,PCBs. Particulate emissions are<br />

G:\~WD~b1dcn-Z\ni74.dos 7-10<br />

176934054 19Uuly 27.<strong>1999</strong>,5:16 PWRAFT FINAL RI REPORT

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