Dames & Moore, 1999 - USDA Forest Service
Dames & Moore, 1999 - USDA Forest Service Dames & Moore, 1999 - USDA Forest Service
,' .... . control and buffering by alumino-silicates. The Baker Mine is believed to have a regional stable geochemical conditions. Likewise, the Holden Mine is also believed to be stable. The similarities with other mines indicates that the experience gained at other sites will be applicable to \ planning remediation at the Holden Mine. 6.8 FLOCCULENT AND FERRICRETE 6.8.1 Flocculent Iron flocculent is a colloidal material that is generated from baseflow groundwater contributed to Railroad Creek from the tailings piles. As the pH of the groundwater increases upon contact and mixing with surface water, iron oxyhydroxides become stable and precipitate. Some of the copper that is in solution and lesser amounts of cadmium, zinc and other metals coprecipitate with the iron as the iron flocculent is formed. During the fall and winter months when groundwater flow is low and the flow in Railroad Creek is low, the majority of the flocculent that is generated settles in the base of the creek bed 'with some limited transport downstream. In the spring, when both groundwater and surface water flows m high, flocculent continues to be generated. Due to the high flow, spring flocculent and flocculent that has accumulated in the Creek bed from fallhinter are mobilized and are both transported downstream. Flocculent is transported during spring runoff and precipitation events. 6.8.2 Ferricrete Formation Ferricrete is typically defined as a conglomerate consisting of sand and gravel cemented into a hard mass by .
Upstream of the tailings piles, significant fdcrete deposits have not been observed. However, it generally apm that most contribution in the spring is by surface flow and in the fall the load contributed by groundwater is small. A hyporheic zone, if present, would be significant only in the fall. 6.9 SEDIMENT As noted in Section 5, a number of stream sediment samples were collected historically from Railroad Creek by others (reported in Kilburn, et al., 1994; U.S. Bureau of Mines or Lambeth, R.E., 1995; and Ecology, or Johnson A., et al., 1997) and in Lake Chelan by Dames & Moore as part of the RI in 1998. Sediments were collected historically upstream, within and downstream of the Site from 11 sampling stations; no duplicate samples to measure variation within a particular sampling station were collected. Analyses for total metals were performed on the medium to fine sand, silt and clay fraction of the sediment. Metal (aluminum, arsenic, cadmium, copper, iron, manganese, lead, and zinc) concentrations for samples collected during 1994 show a slight increase in concentration in the vicinity of the Site in relation to the upstream concentrations. Data from tributary streams along Railroad Creek had similar but slightly lower concentrations of metals in sediments. Lake sediments were collected offshore of the mouth of Railroad Creek in 1998. Compared to the Railroad Creek sediment data, metals in lake sediments from the Lucerne bar have a similar but slightly higher concentration range. In general, the concentrations remain relatively constant fiom the Site to Lake Chelan. Assuming that the sediment samples are representative, the uniformity of the metal concentrations . downstream of the Site suggests that the stream sediment is not significantly diluted during downstream transport between the Site and Lake Chelan, andor the tributaries contribute sediment with metals. Railroad Creek is characterized by a coarse (70 to 90 percent cobble-boulder matrix) grain size that is related to channel morphology and gradient. Fine sediment sources include limited areas of Railroad Creek, tributaries and the streambanks upstream and downstream of the Site. Sediment derived from the watershed area are transported downstream and deposited eventually into Lake Chelan. Although downstream sediment transport in Railroad Creek is a potential compound of concern migration pathway, several physical mechanisms reduce the potential for this pathway to be significant. The majority of metals that have been deposited in the sireambank sediments become progressively attenuated in a downstream direction as they migrate. Downstream sediment becomes interspersed with sediments from tributary and Railroad Creek streambed sources. Copper and zinc remain slightly elevated (approximately two-fold higher than upstream of the Site) from the Site to Lake Chelan. However, the metals are presumed to be present in the sediment as iron oxides andor manganese oxides which are relatively inert and not readily available due to the neutral pH of both Railtoad Creek and Lake Chelan. \\oM-S~l\VOLI\COMMOMWRwpQn~\baldm-2\n7M).dos 6-50 17693405419Uuly 27.1999;4:11 PMDRAFT FINAL RI REPORT DAMES & MOORE
- Page 754 and 755: SOURCE: SRK 10 -i DAMES & MOORE + H
- Page 756 and 757: (* 6.0 TRANSPORT AND FATE OF COMPOU
- Page 758 and 759: 1 I .J Quartz-rich layeis of 40 per
- Page 760 and 761: Crystalline crusts were observed in
- Page 762 and 763: I ( 4. -.- h .*, Evidence of signif
- Page 764 and 765: Predicted saturation indices (SI) f
- Page 766 and 767: Another iron sulfide mineral at the
- Page 768 and 769: . .. . .I.- ..9 6 If water flow is
- Page 770 and 771: pH Control on Precipitation~Dissolu
- Page 772 and 773: summer. Efflorescence occurs when w
- Page 774 and 775: 6.4.1 Evidence of Iron Sulfide Mine
- Page 776 and 777: to the underground mine workings, r
- Page 778 and 779: The pH to copper relationship (Figu
- Page 780 and 781: 6.5.1 Air and Water Movement Associ
- Page 782 and 783: .._/ not originating from the under
- Page 784 and 785: ,' sulfate discharged from the port
- Page 786 and 787: decreases also, aiding in the disso
- Page 788 and 789: .: ._..I $ . .,'. Seasonal s , - We
- Page 790 and 791: . ., Miring of Seeps with Railroad
- Page 792 and 793: through diffusion. This is indicate
- Page 794 and 795: MlNTEQA2 indicates that the seep wa
- Page 796 and 797: In order to. provide comparative fl
- Page 798 and 799: main source of zinc load (82 percen
- Page 800 and 801: ,:..' -- . source areas was estimat
- Page 802 and 803: Monitoring of seeps from drill hole
- Page 806 and 807: , ; . ..' , . .. .. -. . ..&. .< .
- Page 808 and 809: -- (i,e., portal drainage) for cadm
- Page 810 and 811: TABLE 6.0-1 KEY OF SITE FEATURES 8
- Page 812 and 813: TABLE 6.0-1 KEY OF SITE FEATURES 8
- Page 814 and 815: TABLE 6.0-1 KEY OF SITE FEATURES 8
- Page 816 and 817: T.bk abi Losding WNlatlons - R d W
- Page 818 and 819: TABLE 6.6-3 LOADING CALCULATIONS -
- Page 820 and 821: J O NO. ~ 17693-005-019 Draft Final
- Page 824 and 825: Approximate -1 % Grade for 15OPLeve
- Page 826 and 827: LEGEND SP14 Seep sample location P-
- Page 828 and 829: Oxidant I ZnS H20 (transport mechan
- Page 830: Figure 6.3-4a I SOURCE: SRK Figure
- Page 835 and 836: 0 RC 1 0 RC4 A RC7 X RC2 0 RC5 Tail
- Page 837 and 838: 0 RC 1 0 RC4 A RC7 X RC2 0 RC5 Tail
- Page 839 and 840: 0 RC 1 RC4 A RC7 X RC2 0 RC5 Tailin
- Page 841 and 842: 1000 -: 0 RC 1 RC4 A RC7 X RC2 0 RC
- Page 843: P A DAMES MOORE GROUP COMPANY ' + 0
- Page 846 and 847: I ARC7 XRC 2 I I ORC5. Tailings Pil
- Page 848 and 849: ORC 1 ORC 4 ARC 7 XRC2 ORC 5 Tailin
- Page 850: SOURCES: SRK Northwest Geophpysrcal
- Page 853 and 854: Date Figure 6.5-5 DAMES & MOORE 199
Upstream of the tailings piles, significant fdcrete deposits have not been observed. However, it generally<br />
apm that most contribution in the spring is by surface flow and in the fall the load contributed by<br />
groundwater is small. A hyporheic zone, if present, would be significant only in the fall.<br />
6.9 SEDIMENT<br />
As noted in Section 5, a number of stream sediment samples were collected historically from Railroad<br />
Creek by others (reported in Kilburn, et al., 1994; U.S. Bureau of Mines or Lambeth, R.E., 1995; and<br />
Ecology, or Johnson A., et al., 1997) and in Lake Chelan by <strong>Dames</strong> & <strong>Moore</strong> as part of the RI in 1998.<br />
Sediments were collected historically upstream, within and downstream of the Site from 11 sampling<br />
stations; no duplicate samples to measure variation within a particular sampling station were collected.<br />
Analyses for total metals were performed on the medium to fine sand, silt and clay fraction of the<br />
sediment. Metal (aluminum, arsenic, cadmium, copper, iron, manganese, lead, and zinc) concentrations<br />
for samples collected during 1994 show a slight increase in concentration in the vicinity of the Site in<br />
relation to the upstream concentrations. Data from tributary streams along Railroad Creek had similar but<br />
slightly lower concentrations of metals in sediments. Lake sediments were collected offshore of the<br />
mouth of Railroad Creek in 1998. Compared to the Railroad Creek sediment data, metals in lake<br />
sediments from the Lucerne bar have a similar but slightly higher concentration range. In general, the<br />
concentrations remain relatively constant fiom the Site to Lake Chelan.<br />
Assuming that the sediment samples are representative, the uniformity of the metal concentrations .<br />
downstream of the Site suggests that the stream sediment is not significantly diluted during downstream<br />
transport between the Site and Lake Chelan, andor the tributaries contribute sediment with metals.<br />
Railroad Creek is characterized by a coarse (70 to 90 percent cobble-boulder matrix) grain size that is<br />
related to channel morphology and gradient. Fine sediment sources include limited areas of Railroad<br />
Creek, tributaries and the streambanks upstream and downstream of the Site. Sediment derived from the<br />
watershed area are transported downstream and deposited eventually into Lake Chelan.<br />
Although downstream sediment transport in Railroad Creek is a potential compound of concern migration<br />
pathway, several physical mechanisms reduce the potential for this pathway to be significant. The majority<br />
of metals that have been deposited in the sireambank sediments become progressively attenuated in a<br />
downstream direction as they migrate. Downstream sediment becomes interspersed with sediments from<br />
tributary and Railroad Creek streambed sources. Copper and zinc remain slightly elevated (approximately<br />
two-fold higher than upstream of the Site) from the Site to Lake Chelan. However, the metals are presumed<br />
to be present in the sediment as iron oxides andor manganese oxides which are relatively inert and not<br />
readily available due to the neutral pH of both Railtoad Creek and Lake Chelan.<br />
\\oM-S~l\VOLI\COMMOMWRwpQn~\baldm-2\n7M).dos 6-50<br />
17693405419Uuly 27.<strong>1999</strong>;4:11 PMDRAFT FINAL RI REPORT<br />
DAMES & MOORE