Dames & Moore, 1999 - USDA Forest Service

Dames & Moore, 1999 - USDA Forest Service Dames & Moore, 1999 - USDA Forest Service

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1 I .J Quartz-rich layeis of 40 percent quartz, 30 percent plagioclase, 20 percent diopside, 4 percent hornblende, 2 percent sphene (CaTiO(Si04)) and 2 percent biotite In the vicinity of the mineralized zone, the amphibole is altered to a black biotite, with local chlorite ((Mg,Fe)3(Si,Al)4010(OH)2.(Mg,Fe)3(OH)s) and sericite (KA12(AISi3010)(OH)2) alteration, and additional amounts of quartz and sulfides. The increase in the biotite is usually accompanied by a decrease in the lime-silicate (e.g., diopside) content. 6.1.1.2 Ore Deposit Geologists at the Holden Mine originally classified the ore deposit as a vein-type deposit formed in a shear zone (Youngberg and Wilson, 1952); However, it has recently. been re-classified as a metamorphosed Kuroko-type VMS deposit (Dragovich and Derkey, 1994). The ore zone is interpreted to be located within the limb of a large, northwest-trending, overturned, isoclinal fold. Three distinct zones of mineralization, based on sulfide minerals can be distinguished (Dragovich and Derkey, 1994): 1. The "original foatwall sulfide zone," contains pyrrhotite (Fel,S), pyrite (FeS2), biotite and sericite. Pyrite and pyrrhotite in this zone is largely disseminated, and the contact with the original footwall is diffise or irregular. 2. The "original footwall ore zone" which contains pyrrhotite, chalcopyrite (CuFeS2) and gold (Au) mineralization. This is partially interbedded with the footwall sulfide zone. Economically, it was the most important unit at the mine. 3. The "hanging wall ore zone," which contains pyrite and sphalerite (ZnS), with lesser amounts of pyrrhotite, chalcopyrite and galena (PbS). Over 50 percent of the mineralization in this zone is present as sulfides. The contact with the original hanging wail rocks is sharp. Because this sequence is overturned, the "original footwall" is now the structural hanging wall. Other minerals identified in the deposit include: magnetite (FqOd), quartz, molybdenite (MoS3, calcite (CaC03), bournonite (PbCuSbS3), silver (Ag), and possibly pitchblende (U4) (Youngberg and Wilson, 1952). Post-ore intrusive "diabase" dykes cross the ore zone in several locations, varying from approximately twenty-four percent abundance at the 2125 level to almost fifty percent at the 2500 level (Ebbutt, 1956) (Figure 6.1-2). The dykes have a well-developed igneous texture, and are comprised of quartz-diorite. Typical specimens are light colored, with a porphyritic medium grained texture. They contain 10 percent -quartz, 70 percent plagioclase, 10 percent hornblende, and 5 percent chlorite, with minor biotite, apatite (ca~(P0~)3(0H,F,Cl)), sphene, sericite and magnetite. They form sharp contacts with their host rocks (Dubois, 1954). The intrusives appear to be related to the late-Triassic Marblemount belt (Dragovich and Derkey, 1994). The dykes represent an important waste component of the ore and therefore the minerals are expected to be present in the tailings. \\DM-sMI\voLI\coMMoMwP\~~\~~I~~~M\~~.~~~ 6-3 17693-005019Uuly 27.1999;4:42 PMPRAlT FINAL RI REPORT

Other geologic units in the deposit area include: a An anhydrite (CaSO,) lens which was mapped for 120 feet along strike, immediately overlying the original hanging wall. The anhydride was described as a light gray, purple tinged mass, banded with the amphibolite host. a Occasional bands of marble and limesilicate granulites, with a composition of 5 percent qua* 30 percent plagioclase, 30 percent diopside, 20 percent grossularite (Ca3A12Si3012), and 10 percent calcite, with minor wollastonite (CaSi03). 6.1.13 Occurrence of Significant Sulfide Minerals The primary sulfide minerals in the Holden Mine ore deposit occur in the following forms: a Pyrite - abundant in mineralized zones, and as disseminations in the argillites. In the ore zone, it is highly brecciated, with corroded 'kdges. Outside of the ore zone, cubes of pyrite are "not uncommon." a Pyrrhotite -Abundant within ore zone, generally massive in form. a Sphalerite - gradational phases between disseminations and massive replacements in the footwall of the ore zone: Sphalerite has a high iron content, and approaches mannatite (Zn-FeS) in composition. It is concentrated in the east-end of the mine. • Chalcopyrite - Concentrated in the central part of the mineralized zone, varying from massive to disseminated. Replaces and/or heals fractures in pyrite and pynhotite. 6.1.1.4 Conclusion The conclusions from the review of mineralogical information are: The dominant sulfide minerals present at the Holden Mine are iron-based (pyrite, pyrrhotite). Weathering of these minerals is a primary mechanism of the Holden Mine Site water chemistry. a The dominant silicates are aluminum-based (plagioclase and biotite). Carbonate minerals are rare at the Holden Mine. a Non-sulfide mineralogy of the tailings is expected to be dominated by minerals contained in the diabase dykes because the dykes intersect the ore zone, whereas the mine wall rocks and waste rock are more likely to be dominated by biotite schist. 6.1.2 Mineralogy of Secondary Minerals Minerals (i.e., crystalline substances) and amorphous solids produced by weathering processes are visually apparent throughout the Holden Mine Site. These include ubiquitous orange-brown iron-stains on waste rock and tailings indicating iron oxides and white precipitates observed in the 1500-level main .portal drainage (Figures 6.1-1 and 6.1-la). The latter is believed to be amorphous aluminum hydroxide. Green (copper) stain is also present on marble waste rock in the two waste rock piles near the 1500-level main portal and in the abandoned mill building. \U)M-SMI\VOLI\COMMOMWR~W)~\hoI~2\n1M).doc 6-4 DAMES & MOORE 1769340541 Wuly 27.1999;4:11 -RAFT FINAL RI REPORT a C, . .-. J

1<br />

I<br />

.J<br />

Quartz-rich layeis of 40 percent quartz, 30 percent plagioclase, 20 percent diopside, 4<br />

percent hornblende, 2 percent sphene (CaTiO(Si04)) and 2 percent biotite<br />

In the vicinity of the mineralized zone, the amphibole is altered to a black biotite, with local chlorite<br />

((Mg,Fe)3(Si,Al)4010(OH)2.(Mg,Fe)3(OH)s) and sericite (KA12(AISi3010)(OH)2) alteration, and additional<br />

amounts of quartz and sulfides. The increase in the biotite is usually accompanied by a decrease in the<br />

lime-silicate (e.g., diopside) content.<br />

6.1.1.2 Ore Deposit<br />

Geologists at the Holden Mine originally classified the ore deposit as a vein-type deposit formed in a<br />

shear zone (Youngberg and Wilson, 1952); However, it has recently. been re-classified as a<br />

metamorphosed Kuroko-type VMS deposit (Dragovich and Derkey, 1994). The ore zone is interpreted to<br />

be located within the limb of a large, northwest-trending, overturned, isoclinal fold.<br />

Three distinct zones of mineralization, based on sulfide minerals can be distinguished (Dragovich and<br />

Derkey, 1994):<br />

1. The "original foatwall sulfide zone," contains pyrrhotite (Fel,S), pyrite (FeS2), biotite<br />

and sericite. Pyrite and pyrrhotite in this zone is largely disseminated, and the contact<br />

with the original footwall is diffise or irregular.<br />

2. The "original footwall ore zone" which contains pyrrhotite, chalcopyrite (CuFeS2) and<br />

gold (Au) mineralization. This is partially interbedded with the footwall sulfide zone.<br />

Economically, it was the most important unit at the mine.<br />

3. The "hanging wall ore zone," which contains pyrite and sphalerite (ZnS), with lesser<br />

amounts of pyrrhotite, chalcopyrite and galena (PbS). Over 50 percent of the<br />

mineralization in this zone is present as sulfides. The contact with the original hanging<br />

wail rocks is sharp.<br />

Because this sequence is overturned, the "original footwall" is now the structural hanging wall.<br />

Other minerals identified in the deposit include: magnetite (FqOd), quartz, molybdenite (MoS3, calcite<br />

(CaC03), bournonite (PbCuSbS3), silver (Ag), and possibly pitchblende (U4) (Youngberg and Wilson,<br />

1952).<br />

Post-ore intrusive "diabase" dykes cross the ore zone in several locations, varying from approximately<br />

twenty-four percent abundance at the 2125 level to almost fifty percent at the 2500 level (Ebbutt, 1956)<br />

(Figure 6.1-2). The dykes have a well-developed igneous texture, and are comprised of quartz-diorite.<br />

Typical specimens are light colored, with a porphyritic medium grained texture. They contain 10 percent<br />

-quartz, 70 percent plagioclase, 10 percent hornblende, and 5 percent chlorite, with minor biotite, apatite<br />

(ca~(P0~)3(0H,F,Cl)), sphene, sericite and magnetite. They form sharp contacts with their host rocks<br />

(Dubois, 1954). The intrusives appear to be related to the late-Triassic Marblemount belt (Dragovich and<br />

Derkey, 1994). The dykes represent an important waste component of the ore and therefore the minerals<br />

are expected to be present in the tailings.<br />

\\DM-sMI\voLI\coMMoMwP\~~\~~I~~~M\~~.~~~<br />

6-3<br />

17693-005019Uuly 27.<strong>1999</strong>;4:42 PMPRAlT FINAL RI REPORT

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