Dames & Moore, 1999 - USDA Forest Service

Dames & Moore, 1999 - USDA Forest Service Dames & Moore, 1999 - USDA Forest Service

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concentrations were not above MTCA levels. Iron ranged from 54,000 mgkg to 85,300 mg/kg, above background (24,100 mgkg). Aluminum ranged from 32,000 mgkg to 44,000 mgkg. A subsurface tailings sample, TP2-4 (5 to 10 fi bgs), was collected by the USBM in 1994. Barium, cadmium, copper, iron, lead, mercury, thallium, and zinc concentrations were above background; however MTCA levels were not exceeded with the exception of cadmium. Cadmium (16.2 mg/kg) was above the MTCA Method A level (2 mgkg). Iron (61,400 mgkg) was above background (24,100 mgkg). Aluminum concentrations were significantly greater in the samples collected by the USGS than those collected by the USBM. It was determined that the USGS samples were collected from the surface tailings at the toes of the tailings piles whereas the USBM and RI samples were collected on the top of the tailings piles. Additional metals detected at the toe of the slopes were above concentrations detected on the tops of the tailings piles. However, both of the data sets were considered when reviewing the data for PCOCs and comparing to the RI data. 5.2.6.2 RI Tailings Samples Surface and subsurface samples were collected during the RI from each tailings pile. The samples associated with each tailings pile is provided below. Surface Subsurface Tailings Pile 1 DMSS-I 1 DMSS-I2 DMSS-13 DMTP 1-2 DMTPI-3A DMTPI -3B DMTPI-4 Tailings Pile 3 DMSS-17 DMSS-I8 , DMSS- 19 DMTP3- I DMTP3-2 DMTP3-3A DMTP3-3B DMTP3-4A (7 feet bgs) DMTP3-4AX (Duplicate) DMTP3-4B (10 feet bgs) Sample locations are provided on Figure 5.2-1 and analytical data are summarized in Table 5.2-5. Samples were analyzed for metals only. Copper, iron, lead, molybdenum, and silver were above background in the surface samples collected; however, all concentrations were below available MTCA levels. Barium and zinc were above background in a limited number of samples, but well below MTCA levels. Iron ranged from 53,400 mgkg to 73,700 mgkg. The USBM data from surface samples collected from the tops of the tailings piles was compared to RI data. The data were similar in concentration and were well within an order of magnitude. The subsurface samples were collected between 2.5 and 5 feet bgs from test pits completed in tailings piles 1, 2, and 3, with the exception of sample DMTP3-4A that was collected at 7 feet bgs and sample DMTP3-4B that was collected at 10 feet bgs in tailings pile 3. Aluminum, barium, cadmium, chromium, copper, iron, lead, molybdenum, nickel, silver, thallium, uranium, and zinc were above background in one or more subsurface samples collected. Concentrations \U)M~SEA~\V~L~\C~MM~N\WP\WPDATA\~~~PORTSW~LDEN-~UUU-~.~OE 5- 1 1 17693-0OS-019Vuly 28.1999;11:09 AM;DRAFT FINAL RI REPORT Tailings Pile 2 DMSS- 14 DMSS-I5 DMSS-16 DMTP2-IA DMTP2- I B DMTP2-2

were below MTCA levels with the following exceptions: cadmium (21 mgkg) and copper (12,400 mgkg) in sample DMTPI-3B and cadmium (147 mgkg) and copper (16,500 mg/kg) in sample DMTP2- 1A. Iron ranged from 26,800 mgkg to 87,500 mgkg. Aluminum (29,700 m&g) was above background (20,900 mgkg) at one location (DMTP2- I A). The subsurface historical data (TP2-4 collected 5 to 10 ft bgs) was compared to the data collected at location DMTP2-2 (4 to 5 feet bgs) during the RI. Generally, the data were within an order of magnitude; however, concentrations of cadmium, lead, and zinc reported in the USBM sample were 20 to 40 times greater than the concentrations detected in the RI samples. Only cadmium levels in the USBM samples were above MTCA levels. Aluminum and iron are considered PCOCs in surface and subsurface tailings as it is above background; a MTCA level is not currently established. Cadmium and copper are considered PCOCs in subsurface tailings only. 5.2.7 Wind-Blown Tailings Five surface soil samples (DMSS-20 through DMSS-24) that contained visual evidence of tailings were collected downwind of RC-2 during the RI and were analyzed for metals only. Sample locations are shown in Figure 5.2-5 and the data are summarized in Table 5.2-5. Barium, copper, iron, lead, molybdenum, silver, and zinc were above background levels in one or more samples collected. However, none of the concentrations were above available MTCA levels. Iron concentrations ranged from 24,100 mgkg to 66,200 mgkg. Iron is identified as a PCOC as it is above background and a MTCA level is not currently established. 5.2.8 Summary Site-specific background values for metal concentrations were statistically calculated from surface soil samples collected Specifically for area background assessment. Metals data collected from Holden Village, the baseball field, maintenance yard, lagoon, tailings piles, and windblown tailings were compared initially to background values. If concentrations 'were above background, the data were then compared to available MTCA A or MTCA B cleanup levels. Metal concentrations above background and MTCA cleanup levels were preliminarily selected as PCOCs and are summarized by location in Table 5.2-6. Exceptions to the PCOC assessment were cations (calcium, magnesium, potassium, and sodium), aluminum and iron. The cations are generally considered nutrient metals and MTCA does not provide , cleanup levels for these metals. Aluminum and iron were considered PCOCs if the results were above background as MTCA does not provide guidance for these metals. Organic analytical data from the surface and subsurface soil samples collected from the lagoon and maintenance yard were compared to MTCA Method A and Method B cleanup levels. Total petroleum hydrocarbon concentrations above MTCA cleanup levels were considered PCOCs in subsurface soil in the maintenance yard in a localized area and in surface/subsurface lagoon soils. Organic PCOCs are also summarized in Table 5.2-6. G:\WPDATAUXI~WORTSWOLDM-Z\RN~.~W 17693405-0 19Uuly 28, 1999; 1 1 :2 1 AM:DRAFT FINAL RI REPORT

were below MTCA levels with the following exceptions: cadmium (21 mgkg) and copper (12,400<br />

mgkg) in sample DMTPI-3B and cadmium (147 mgkg) and copper (16,500 mg/kg) in sample DMTP2-<br />

1A. Iron ranged from 26,800 mgkg to 87,500 mgkg. Aluminum (29,700 m&g) was above background<br />

(20,900 mgkg) at one location (DMTP2- I A).<br />

The subsurface historical data (TP2-4 collected 5 to 10 ft bgs) was compared to the data collected at<br />

location DMTP2-2 (4 to 5 feet bgs) during the RI. Generally, the data were within an order of magnitude;<br />

however, concentrations of cadmium, lead, and zinc reported in the USBM sample were 20 to 40 times<br />

greater than the concentrations detected in the RI samples. Only cadmium levels in the USBM samples<br />

were above MTCA levels.<br />

Aluminum and iron are considered PCOCs in surface and subsurface tailings as it is above background; a<br />

MTCA level is not currently established. Cadmium and copper are considered PCOCs in subsurface<br />

tailings only.<br />

5.2.7 Wind-Blown Tailings<br />

Five surface soil samples (DMSS-20 through DMSS-24) that contained visual evidence of tailings were<br />

collected downwind of RC-2 during the RI and were analyzed for metals only. Sample locations are shown<br />

in Figure 5.2-5 and the data are summarized in Table 5.2-5.<br />

Barium, copper, iron, lead, molybdenum, silver, and zinc were above background levels in one or more<br />

samples collected. However, none of the concentrations were above available MTCA levels. Iron<br />

concentrations ranged from 24,100 mgkg to 66,200 mgkg.<br />

Iron is identified as a PCOC as it is above background and a MTCA level is not currently established.<br />

5.2.8 Summary<br />

Site-specific background values for metal concentrations were statistically calculated from surface soil<br />

samples collected Specifically for area background assessment. Metals data collected from Holden<br />

Village, the baseball field, maintenance yard, lagoon, tailings piles, and windblown tailings were<br />

compared initially to background values. If concentrations 'were above background, the data were then<br />

compared to available MTCA A or MTCA B cleanup levels. Metal concentrations above background and<br />

MTCA cleanup levels were preliminarily selected as PCOCs and are summarized by location in Table<br />

5.2-6. Exceptions to the PCOC assessment were cations (calcium, magnesium, potassium, and sodium),<br />

aluminum and iron. The cations are generally considered nutrient metals and MTCA does not provide ,<br />

cleanup levels for these metals. Aluminum and iron were considered PCOCs if the results were above<br />

background as MTCA does not provide guidance for these metals.<br />

Organic analytical data from the surface and subsurface soil samples collected from the lagoon and<br />

maintenance yard were compared to MTCA Method A and Method B cleanup levels. Total petroleum<br />

hydrocarbon concentrations above MTCA cleanup levels were considered PCOCs in subsurface soil in<br />

the maintenance yard in a localized area and in surface/subsurface lagoon soils. Organic PCOCs are also<br />

summarized in Table 5.2-6.<br />

G:\WPDATAUXI~WORTSWOLDM-Z\RN~.~W<br />

17693405-0 19Uuly 28, <strong>1999</strong>; 1 1 :2 1 AM:DRAFT FINAL RI REPORT

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