Dames & Moore, 1999 - USDA Forest Service
Dames & Moore, 1999 - USDA Forest Service Dames & Moore, 1999 - USDA Forest Service
8.3.4.1 Western Portion of Site During the MayIJune 1997 sampling events, the results of the analysis indicated concentrations of cadmium, copper, and zinc above groundwater regulatory threshold (MTCA Method B) for the western portion of the Site. Two seeps sampled below the west waste rock pile (SP-6 and SP-I5E) were found to have concentrations of beryllium and manganese slightly above the MTCA groundwater levels, respectively. Seeps SP-11 contained arsenic and SP-IOE contained iron above groundwater threshold levels. The results of the SeptemberIOctober 1997 sampling event detected concentrations of cadmium, copper, and zinc below those measured during the MayIJune sampling events, but above groundwater MTCA Method B levels. 8.3.4.2 Eastern Portion of Site During the MayIJune sampling events, the results of the analyses indicated that concentrations of cadmium, copper, iron, and zinc were above the MTCA Method A or B groundwater levels. The area of the highest groundwater concentrations was found in tailings pile 1. The concentrations in wells and seeps associated with tailings piles 2 and 3 were generally lower than for tailings pile 1. For tailings piles 1 and 2. concentrations of cadmium, copper, arsenic, beryllium, manganese, iron, and zinc were also detected slightly above the groundwater regulatory levels. For tailings pile 3, lead, beryllium, manganese, cadmium, copper, and iron were detected above the groundwater regulatory levels. In comparison, the results of the SeptemberIOctober sampling detected higher concentrations of iron, and lower concentrations of the other metals found in the MayIJune sampling event at all tailings piles. Cadmium, copper, arsenic, manganese and iron were detected above the groundwater regulatory criteria for tailings piles 1 and 2. Iron and manganese exceeded groundwater MTCA levels were detected for tailings pile 3 for the SeptemberIOctober event. iron concentrations were generally much higher in the eastern portion of the Site during the SeptemberlOctober sampling event than during the MayIJune event. 8.3.4.3 Lucerne USFS Guard Station Well The water supply well located at the USFS Guard Station in Lucerne was sampled during the SeptemberIOctober event. The results of the analyses indicated concentrations of iron slightly above the secondary MCL (less than 20 percent higher), a non-health based standard. 8.3.5 Sediment 8.3.5.1 Railroad Creek Sediment in Railroad Creek was observed to consist primarily of relatively large grain size gravel, cobbles, and boulders. The grain size of the stream substrate decreases slightly from the Site to the mouth of Railroad Creek. Stream sediment samples were collected by others in 1994, 1995, and 1996. The results indicate a general increase in iron, zinc, and copper concentrations from upstream of the Site to River Mile 7. However, the metal concentrations were below the Ecology freshwater sediment quality guidance value (FSQV). \U)M-SEAI\VOLI\COMMOMWP\WPDATA\OOS\REWRTS\HOLDEN-~\R~~-O.~OC 8-3 1 17693-005-019Uuly 28. 1999;10:37 AM;DMFT FINAL RI REPORT
8.3.5.2 Lucerne Bar & Stehekin River Bar Sediment was collected from near the mouth of Railroad Creek at Lucerne Bar and a reference site near the mouth of the Stehekin River, approximately 10 miles north of Lucerne Bar in Lake Chelan. The results indicate concentrations of zinc slightly above FSQVs (approximately 5 percent higher)for one sample out of 12 collected at Lucerne Bar; the sample was collected near the eastern margin of the study area. All others metal concentrations were below FSQVs. 8.3.6 Other Media 8.3.6.1 Ferricrete Three samples of femcrete were collected during the RI to characterize the chemistry to assess the formation of the deposits. The samples were collected from the areas near seeps located northwest and northeast of tailings pile. Iron was the dominant metal present, followed by lessor concentrations of aluminum, magnesium, calcium, and copper. 8.3.6.2 Flocculent Three samples of flocculent were collected during the RI from the substrate in Railroad Creek to assess the formation of the precipitates. The flocculent was similar in metals composition to femcrete, but generally contained a higher proportion of iron (up to 43 percent higher). 8.3.6.3 Portal Film Two samples of film or flocculent were collected from the portal drainage substrate. One sample was collected each during the July and SeptemberIOctober 1997 events. Aluminum was the dominant metal in the portal film, followed by iron, calcium, copper, and zinc. Aluminum was approximately twice as high in July when compared to September/October. Zinc and copper were higher by approximately two times in September/October as compared to July. 8.3.6.4 Air Air samples were collected as part of the pre- and post-construction monitoring associated with the tailings pile rehabilitation project completed at the Site by the USFS between 1989 and 1991. A dust bucket study was completed between 1974 and 1976; however, the dust was not chemically characterized. The post- construction sampling consisted of establishing air monitoring stations both west and east of the Site, as well as on top of the tailings piles. The results indicate that the metals of highest concentrations were aluminum, calcium, magnesium, potassium, and sodium. These data were utilized to evaluate potential risk as discussed in a later subsection. 8.4 CONTAMINANT PATHWAYS AND CHEMICAL LOADING 8.4.1 General The contaminant pathways were evaluated based on the potential sources of contaminants and chemistry as discussed in the previous subsection. This discussion presents the contaminant pathways for the western and eastern portions of the Site, and Railroad Creek. The western portion of the Site principally includes the \U)M~SEAI\VOLI\COMMOMWP\WPDATA\OO5\REPORTSWOLDEN-2W4.d~ 8-32 DAMES & MOORE 17693-005-01 9Uuly 28. 1999; 10:24 AM:DRAFT FINAL RI REPORT *.
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8.3.5.2 Lucerne Bar & Stehekin River Bar<br />
Sediment was collected from near the mouth of Railroad Creek at Lucerne Bar and a reference site near<br />
the mouth of the Stehekin River, approximately 10 miles north of Lucerne Bar in Lake Chelan. The<br />
results indicate concentrations of zinc slightly above FSQVs (approximately 5 percent higher)for one<br />
sample out of 12 collected at Lucerne Bar; the sample was collected near the eastern margin of the study<br />
area. All others metal concentrations were below FSQVs.<br />
8.3.6 Other Media<br />
8.3.6.1 Ferricrete<br />
Three samples of femcrete were collected during the RI to characterize the chemistry to assess the<br />
formation of the deposits. The samples were collected from the areas near seeps located northwest and<br />
northeast of tailings pile. Iron was the dominant metal present, followed by lessor concentrations of<br />
aluminum, magnesium, calcium, and copper.<br />
8.3.6.2 Flocculent<br />
Three samples of flocculent were collected during the RI from the substrate in Railroad Creek to assess the<br />
formation of the precipitates. The flocculent was similar in metals composition to femcrete, but generally<br />
contained a higher proportion of iron (up to 43 percent higher).<br />
8.3.6.3 Portal Film<br />
Two samples of film or flocculent were collected from the portal drainage substrate. One sample was<br />
collected each during the July and SeptemberIOctober 1997 events. Aluminum was the dominant metal in<br />
the portal film, followed by iron, calcium, copper, and zinc. Aluminum was approximately twice as high in<br />
July when compared to September/October. Zinc and copper were higher by approximately two times in<br />
September/October as compared to July.<br />
8.3.6.4 Air<br />
Air samples were collected as part of the pre- and post-construction monitoring associated with the tailings<br />
pile rehabilitation project completed at the Site by the USFS between 1989 and 1991. A dust bucket study<br />
was completed between 1974 and 1976; however, the dust was not chemically characterized. The post-<br />
construction sampling consisted of establishing air monitoring stations both west and east of the Site, as well<br />
as on top of the tailings piles. The results indicate that the metals of highest concentrations were aluminum,<br />
calcium, magnesium, potassium, and sodium. These data were utilized to evaluate potential risk as<br />
discussed in a later subsection.<br />
8.4 CONTAMINANT PATHWAYS AND CHEMICAL LOADING<br />
8.4.1 General<br />
The contaminant pathways were evaluated based on the potential sources of contaminants and chemistry as<br />
discussed in the previous subsection. This discussion presents the contaminant pathways for the western<br />
and eastern portions of the Site, and Railroad Creek. The western portion of the Site principally includes the<br />
\U)M~SEAI\VOLI\COMMOMWP\WPDATA\OO5\REPORTSWOLDEN-2W4.d~ 8-32 DAMES & MOORE<br />
17693-005-01 9Uuly 28. <strong>1999</strong>; 10:24 AM:DRAFT FINAL RI REPORT<br />
*.