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18 MACROCYCLIC LIGANDS as (5), have been examined primarily because of their thermodynamic stability. 6 RELATED ARTICLES Ammonia & N-donor Ligands; Mixed Donor Ligands P-donor Ligands; S-donor Ligands; Water & O-donor Ligands. 7 REFERENCES 1. J. Van Alphen, Recl. Trav. Chim. Pays-Bas, 1936, 55, 835. 2. M. C. Thompson and D. H. Busch, Chem. Eng. News, 1962, 57. 3. N. F. Curtis, J. Chem. Soc., 1960, 4409. 4. C. J. Pedersen, J. Am. Chem. Soc., 1967, 89, 7017. 5. B. Dietrich, J.-M. Lehn, and J.-P. Sauvage, Tetrahedron Lett., 1969, 2889. 6. J. Almy, D. C. Garwood, and D. J. Cram, J. Am. Chem. Soc., 1973, 95, 2961. 7. T. Mashiko and D. Dolphin, in ‘Comprehensive Coordination Chemistry’, eds. G. Wilkinson, R. D. Gillard, and 8. J. A. McCleverty, Pergamon, Oxford, 1982, Vol. 2, p. 813. V. T. Souza and M. L. Bender, Acc. Chem. Res., 1987, 20, 146. 9. G. A. Melson ed., ‘Coordination Chemistry of Macrocyclic Compounds’, Plenum, New York, 1979. 10. D. H. Busch, Acc. Chem. Res., 1978, 11, 393. 11. T. A. Kaden, Top. Curr. Chem., 1984, 121, 157. 12. E. Kimura, Top. Curr. Chem., 1985, 128, 113. 13. L. F. Lindoy, ‘The Chemistry of Macrocyclic Ligand 14. Complexes’, Cambridge University Press, Cambridge, MA, 1989. P. Chaudhuri and K. Wieghardt, Prog. Inorg. Chem., 1987, 35, 329. 15. D. Parker, Chem. Soc. Rev., 1990, 19, 271. 16. R. Bhula, P. Osvath, and D. C. Weatherburn, Coord. Chem. Rev., 1988, 91, 89. 17. A. Bianchi, M. Micheloni, and P. Paoletti, Coord. Chem. Rev., 1991, 110, 17. 18. A. Bianchi, M. Micheloni, and P. Paoletti, Pure Appl. Chem., 1988, 60, 525. 19. D. H. Busch and C. Cairns, in ‘Progress in Macrocyclic Chemistry’, eds. R. M. Izatt and J. J. Christensen, Wiley, New York, 1987, Vol. 3, Chap. 1, p. 1. 20. A. M. Sargeson, Pure Appl. Chem., 1984, 56, 1603. 21. J. L. Sessler, T. Murai, and V. Lynch, Inorg. Chem., 1989, 28, 1333. 22. F. V. Acholla, F. Takusagawa, and K. B. Mertes, J. Am. Chem. Soc., 1985, 107, 6902. 23. I. Murase, K. Hamada, and S. Kida, Inorg. Chim. Acta, 1981, 54, L171. 24. N. B. Tucker and E. E. Reid, J. Am. Chem. Soc., 1933, 55, 775. 25. L. Horner, H. Kunz, and P. Walach, Phosphorus Relat. Group BElem., 1975, 6, 63. 26. J. Ennen and T. Kauffmann, Angew. Chem., Int. Ed. Engl., 1981, 28, 118. 27. L. Lindoy, in ‘Cation Binding by Macrocycles’, eds. Y. Inoue and G. W. Gokel, Dekker, New York, 1990, Chap. 16, p. 599. 28. D. E. Fenton, U. Casellato, P. A. Vigato, and M. Vidali, Inorg. Chim. Acta, 1982, 62, 57. 29. C. O. Dietrich-Buchecker, J.-M. Kern, and J.-P. Sauvage, J. Am. Chem. Soc., 1984, 106, 3043. 30. Y. Inoue and G. W. Gokel eds, ‘Cation Binding by 31. Macrocycles’, Dekker, New York, 1990. I. Tabushi, Y. Kobuki, and T. Nishiya, Tetrahedron Lett., 1979, 20, 3515. 32. A. Shanzer, J. Libman, and F. Frolow, J. Am. Chem. Soc., 1981, 103, 7339. 33. E. Schwartz and A. Shanzer, J. Chem. Soc., Chem. Commun., 1981, 634. 34. D. J. Cram, S. Karbach, Y. H. Kim, L. Baczynskyj, and 35. W. Kalleymeyn, J. Am. Chem. Soc., 1985, 107, 2575. G. W. Gokel, D. M. Dishong, and C. J. Diamond, J. Chem. Soc., Chem. Commun., 1980, 1053. 36. D. J. Cram, Angew. Chem., Int. Ed. Engl., 1986, 25, 1039. 37. C. D. Gutsche, in ‘Calixarenes’, ed. G. F. Stoddart, Royal Society Chemistry, Cambridge, MA, 1989. 38. C. D. Gutsche, I. Alam, M. Iqbal, T. Mangiafico, K. C. Nam, J. Rogers, and K. A. See, J. Inclusion Phenom., 1989 7, 61. 39. R. Bhula, P. Osvath, and D. C. Weatherburn, Coord. Chem. Rev., 1988, 91, 89. 40. J. E. Richman and T. J. Atkins, J. Am. Chem. Soc., 1974, 96, 2268. 41. F. Chavez and A. D. Sherry, J. Org. Chem., 1989, 54, 2990. 42. R. W. Alder, R. W. Mowlam, D. J. Vachon, and G. R. Weisman, J. Chem. Soc., Chem. Commun., 1992, 507. 43. M. W. Hosseini, J. Comarmond, and J.-M. Lehn, Helv. Chim. Acta, 1989, 72, 1066. 44. Y.-D. Choi and J. P. Street, J. Org. Chem., 1992, 57, 1258. 45. L. Qian, Z. Sun, M. P. Mertes, and K. B. Mertes, J. Org. Chem., 1991, 56, 4904. 46. E. K. Barefield, D. Chueng, D. vanDerveer, and F. Wagner, J. Chem. Soc., Chem. Commun., 1981, 302. 47. M. C. Thompson and D. H. Busch, J. Am. Chem. Soc., 1964, 86, 3651.
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Page 1 and 2: Macrocyclic Ligands Kristin Bowman-
Page 3 and 4: 2.1.5 Bis-Macrocycles Bis-macrocycl
Page 5 and 6: Me 2.4.4 Calixarenes O Me OMe OMe M
Page 7 and 8: N N CHO H2N + CHO H2N M n+ extremel
Page 9 and 10: HO O O OH + Cl O O Cl Scheme 9 Sphe
Page 11 and 12: to six, the complex stability decre
Page 13 and 14: NH NH NH NH NH NH (46) HN HN HN HN
Page 15 and 16: mechanism is the assumption that co
Page 17: their guests more strongly and are,

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