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Proceedings World Bioenergy 2010

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combination with pressure transducers specifically to the<br />

installed chimney is used to measure the transient flue<br />

gas flow in the chimney during start-up and stop phases.<br />

The whole set of the boiler/stove was installed on a scale<br />

and the fuel consumption was continuously monitored.<br />

However, the fuel consumption during the start-up and<br />

stop period was too small relative to the scale’s<br />

measurement resolution. Therefore, the fuel consumption<br />

during start-up and stop phases are calculated using<br />

measured flue gas flow with the combustion calculation<br />

according to Wester [6].<br />

The sample flue gas is extracted from the chimney<br />

and transported via a heated tube (180°C). Carbon<br />

dioxide (CO 2), carbon monoxide (CO) and nitrogen oxide<br />

(NO) are measured with an non- dispersive infra-red gas<br />

analyser, oxygen (O 2) with a paramagnetic gas analyser<br />

and total organic carbon (TOC) with a flame ionisation<br />

detector (FID). The emissions of TOC are presented in<br />

propane equivalent. The particle emissions are sampled<br />

in the dilution channel (Figure 1) with an electrical low<br />

pressure impactor (ELPI). Particulate matters are<br />

measured in number concentration and size distribution<br />

in the range of 7 nm to 10 µm and are characterized for<br />

PM 2.5.<br />

2.2 Combustion devices<br />

Both boiler and stove are modern pellet heating<br />

devices with electrical ignition and automatic pellet<br />

feeding from above. The 20 kW boiler has an integrated<br />

hot water preparation unit with water volume of 150<br />

liters. The maximum combustion power was set to 80%<br />

of the nominal power and combustion air supply and. The<br />

boiler has a cleaning routine during a stop phase in which<br />

the glowing pellet are blown with compressed air into the<br />

ash box and the stove has 1.5 cleaning routine at every<br />

1.5 hours of operation.<br />

2.3 Pellet<br />

Only a brand of soft wood pellet were used.<br />

However, two batch or order were made through all the<br />

measurements. The composition of the pellet fuel used in<br />

the measurements are listed in table I.<br />

Table I: Fuel composition of the pellet<br />

86 world bioenergy <strong>2010</strong><br />

Element Unit Start-up Stop<br />

Carbon wt% dry 51.20 50.74<br />

Hydrogen wt% dry 42.00 42.52<br />

Oxygen wt% dry 6.30 6.23<br />

Nitrogen wt% dry 0.20 0.10<br />

Ash wt% dry 0.30 0.41<br />

Moisture wt% dry 8.20 6.80<br />

Lower heating<br />

value<br />

3 RESULTS<br />

MJ/kg 19.14 18.99<br />

The accumulated emissions measured during start-up<br />

and stop phase of the boiler and stove are presented in<br />

table II. The duration of the start-up phase and stop phase<br />

of the boiler are 5 minutes and 24 minutes. Comparing<br />

with the boiler, the stove has higher accumulated<br />

emissions during start-up with 12 minutes duration and<br />

lower emissions during stop phase with 25 minutes.<br />

Cleaning with compressed air during stop phases of the<br />

boiler caused glowing in the ash box resulting higher<br />

emissions for stop phase.<br />

Table II: Accumulated emissions of start-up and stop<br />

phase of 20 kW boiler and 12 kW stove<br />

Boiler* Stove<br />

Start-up Stop Start-up Stop<br />

CO (g) 0.72 8.99 1.05 6.78<br />

NO (g) 0.10 0.04 0.35 0.03<br />

TOC (g) 0.15 0.43 0.12 0.01<br />

PM 2.5 (g) 0.23 0.41 0.35 0.17<br />

Energy (MJ) 2.12 1.22 6.81 1.02<br />

* Win,. et al.[7]<br />

Emission concentrations during start-up, steady state and<br />

stop phases are compared in figure 2. Steady state<br />

emissions characterised per MJ combusted fuel are in<br />

general lower than start-up and stop emissions. CO<br />

emissions during steady state operation of the stove is<br />

higher than from the boiler due to the cleaning routine at<br />

every 1.5 hours occurred during long steady state periods.<br />

Figure 2: Average emission concentrations during startup,<br />

stationary periods and during stop periods<br />

Steady state emissions are lower than from start-up<br />

and stop periods, significantly in CO and TOC. Cleaning<br />

with compressed air during stop phases of the boiler<br />

caused the accumulation of uncombusted pellet in the ash<br />

box leading to glowing in the ash box resulting in higher<br />

stop emissions. The 1.5 hourly cleaning routine of the<br />

stove was taken into the steady state. Both the boiler and<br />

the stove has near zero TOC emissions during steady state.

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