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SAPOTEC Soluções Ambientais LTDA. Part of Zech Group - RETech

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<strong>SAPOTEC</strong><br />

<strong>Soluções</strong> <strong>Ambientais</strong> <strong>LTDA</strong>.<br />

<strong>Part</strong> <strong>of</strong> <strong>Zech</strong> <strong>Group</strong><br />

Bioremediation in Brazil - Technology Transfer<br />

12/03/2009 Dr. Thomas Berger<br />

Biorremediação Bioremediation in no Brazil Brasil<br />

Ecogerma 2009<br />

São Paulo


Overview<br />

� <strong>Zech</strong> <strong>Group</strong> - Sapotec Ltda.<br />

� Concept <strong>of</strong> Bioremediation<br />

� Market for Bioremediation in Germany<br />

� Market for Bioremediation in Brazil<br />

� Technology Transfer<br />

� Case Study<br />

� Conclusion<br />

12/03/2009<br />

Dr. Thomas Berger<br />

Bioremediation in Brazil<br />

Ecogerma 2009<br />

São Paulo


<strong>SAPOTEC</strong> –<br />

A <strong>Zech</strong> <strong>Group</strong> Company<br />

Construction<br />

<strong>Zech</strong> Bau<br />

Holding<br />

GmbH<br />

12/03/2009<br />

Real Estate<br />

Deutsche<br />

Immobilien<br />

Holding AG<br />

Hotel<br />

<strong>Zech</strong> Hotel<br />

Holding<br />

GmbH<br />

Environment/<br />

Tecnology<br />

<strong>Zech</strong> Umwelt<br />

Holding<br />

GmbH<br />

Dr. Thomas Berger<br />

Bioremediation in Brazil<br />

<strong>Zech</strong> Management GmbH<br />

Industry<br />

Nordwest<br />

Industrie<br />

Capital GmbH<br />

International<br />

<strong>Zech</strong><br />

International<br />

Holding GmbH<br />

Ecogerma 2009<br />

São Paulo


Field <strong>of</strong> Action: ZECH Umwelt<br />

Soil<br />

Air<br />

12/03/2009<br />

Water<br />

Services:<br />

� Remediation technologies<br />

� Revitalization <strong>of</strong> degraded areas<br />

� Waste water treatment technologies<br />

� Reduction <strong>of</strong> gas emissions<br />

� Mobile und stationary treatment facilities<br />

� Waste management<br />

Dr. Thomas Berger<br />

Bioremediation in Brazil<br />

Ecogerma 2009<br />

São Paulo


<strong>SAPOTEC</strong> <strong>LTDA</strong>.<br />

� 2000: Foundation <strong>of</strong> Sapotec in Brazil;<br />

� 2002: Inauguration <strong>of</strong> the first bioremediation plant in<br />

Paulínia – São Paulo;<br />

� 2006: Inauguration <strong>of</strong> the second bioremediation plant in<br />

Nova St. Rita – Rio Grande do Sul;<br />

� 2009: Operating in all Federal States <strong>of</strong> Brazil, with a<br />

focus on the South and Southeast <strong>of</strong> Brazil<br />

(SC/PR/SP/MG/RIO);<br />

� Fields <strong>of</strong> action: Soil and waste treatment, environmental<br />

engineering services.<br />

12/03/2009<br />

Dr. Thomas Berger<br />

Bioremediation in Brazil<br />

Ecogerma 2009<br />

São Paulo


Concept <strong>of</strong> Bioremediation<br />

Contaminated<br />

soil/waste<br />

12/03/2009<br />

+<br />

Microorganisms<br />

Reduction <strong>of</strong><br />

pollutant concentration<br />

Dr. Thomas Berger<br />

Bioremediation in Brazil<br />

CO 2 + H 2O +<br />

Biomass<br />

Ecogerma 2009<br />

São Paulo


Restrictions <strong>of</strong> Bioremediation<br />

Achievement <strong>of</strong> a<br />

high degradation<br />

Increase <strong>of</strong> the<br />

microbial population<br />

12/03/2009<br />

� Type <strong>of</strong> microorganism (bacteria,<br />

fungi, yeasts)<br />

� O 2 , pH-value, temperature,<br />

humidity<br />

� Nutrients (N 2, K, P)<br />

� Contamination (concentration<br />

and toxicity)<br />

Dr. Thomas Berger<br />

Bioremediation in Brazil<br />

Ecogerma 2009<br />

São Paulo


Treatable Contaminants with Bioremediation<br />

12/03/2009<br />

Contaminants<br />

Hydrocarbons/<br />

Mineral oil products<br />

Polychlorinated aromatic<br />

hydrocarbons (PAC)<br />

Not<br />

applicable<br />

Volatile chlorinated hydrocarbons X<br />

Aromatic hydrocarbons (BTEX) X<br />

Polychlorinated biphenyles (PCB) X<br />

Other organic halogen compounds X<br />

Cyanates (also with complex<br />

compounds)<br />

Organic nitrogen compounds X<br />

Agrarian pollutants/pesticides X<br />

Heavy metals X<br />

Dioxines and furanes X<br />

Dr. Thomas Berger<br />

Bioremediation in Brazil<br />

In parts Applicable Unkown<br />

X<br />

X<br />

X<br />

Ecogerma 2009<br />

São Paulo


Biological test and<br />

optimization<br />

. .<br />

.<br />

. .<br />

Residuals<br />

etc. ...<br />

Landfill<br />

Flow diagram TERRAFERM ®<br />

Separation<br />

Delivery <strong>of</strong> soil<br />

at the plant<br />

Material<br />

appropriate<br />

for treatment<br />

Comminution<br />

Homogenization<br />

Structured materials<br />

12/03/2009 Dr. Thomas Berger<br />

Biorremediação Bioremediation in no Brazil Brasil<br />

.<br />

I<br />

II<br />

I<br />

process<br />

Substrates<br />

Recycling<br />

Mineral substances<br />

II<br />

Quality control<br />

Air purification<br />

I<br />

Landfill<br />

Treated soil<br />

Biological treatment<br />

on-site/<strong>of</strong>f-site<br />

Ecogerma 2009<br />

São Paulo


Soil Treatment Off-site<br />

Steps <strong>of</strong> Treatment<br />

12/03/2009<br />

Weighing<br />

Comminution and<br />

Homogenization<br />

Unloading <strong>of</strong><br />

soil<br />

Soil in the<br />

treatment phase<br />

Dr. Thomas Berger<br />

Bioremediation in Brazil<br />

Removal <strong>of</strong> soil from<br />

the docks<br />

Treatment <strong>of</strong> gaseous<br />

hydrocarbons<br />

Ecogerma 2009<br />

São Paulo


Soil Treatment On-site<br />

12/03/2009<br />

Dr. Thomas Berger<br />

Bioremediation in Brazil<br />

Ecogerma 2009<br />

São Paulo


The Market in Germany<br />

93 plants for bioremediation <strong>of</strong>fsite<br />

with:<br />

� Capacity > 6.5 Mio. ton per<br />

year (2007);<br />

� 76% capacity utilization.<br />

12/03/2009<br />

Dr. Thomas Berger<br />

Bioremediation in Brazil<br />

Ecogerma 2009<br />

São Paulo


Waste Treatment in Germany<br />

Example: Bioremediation plant in Ganderkesee (<strong>of</strong> ZECH Umwelt)<br />

Waste Code¹ Waste type<br />

13 05 01* Solid waste from sand traps and oil-/water seperators<br />

13 05 08* Waste mixtures from sand traps and oil-/water seperators<br />

17 05 03* Soil and stones containing hazardous materials<br />

17 05 04 Soil and stones exept <strong>of</strong> those under 17 05 03<br />

17 05 05* Dredged material containing hazardous materials<br />

17 05 07* Track ballast containing hazardous materials<br />

17 05 08 Track ballast except those under 17 05 07<br />

19 12 09 Minerals (e.g. sand, stones)<br />

19 13 01* Solid waste from soil remediation containing hazardous materials<br />

19 13 02 Solid waste from soil remediation except those under 19 13 01<br />

19 13 03* Sludges from soil remediation containing hazardous materials<br />

19 13 05* Sludges from ground water remediation containing hazardous materials<br />

20 03 03 Street cleaning waste<br />

20 03 06 Waste from sewer cleaning<br />

*Hazardous waste<br />

¹European Waste Catalogue<br />

12/03/2009<br />

Dr. Thomas Berger<br />

Bioremediation in Brazil<br />

Ecogerma 2009<br />

São Paulo


Final Disposal <strong>of</strong> Treated Soil<br />

Material in Germany<br />

� Return transport <strong>of</strong> treated soil to place <strong>of</strong> origin;<br />

� Cover layer for landfills;<br />

� Selling <strong>of</strong> treated soil for horticultures and anti-noisebarriers;<br />

� Recultivation <strong>of</strong> degraded areas.<br />

12/03/2009<br />

Dr. Thomas Berger<br />

Bioremediation in Brazil<br />

Ecogerma 2009<br />

São Paulo


Bioremediation in BRAZIL<br />

General Information:<br />

� Until the year 2000 there were<br />

no registered remediation<br />

plans for ex situ-technologies<br />

in Brazil<br />

� First soil remediation project<br />

<strong>of</strong> the Sapotec:<br />

� REPLAN: 2002/03<br />

12/03/2009<br />

Dr. Thomas Berger<br />

Bioremediation in Brazil<br />

Ecogerma 2009<br />

São Paulo


Bioremediation in BRAZIL<br />

Landfills class II-A<br />

Landfills class II-B<br />

Landfills class I<br />

Co-treatment<br />

Incineration<br />

Thermal treatment<br />

Biological treatment<br />

Recycling<br />

12/03/2009<br />

INDUSTRIAL WASTE<br />

5,9 MILLION TONS TREATED (2007)<br />

Source: ABETRE (Ass.Bras.de Empresas de Tratamento de Resíduos)<br />

Dr. Thomas Berger<br />

Bioremediation in Brazil<br />

Ecogerma 2009<br />

São Paulo


Final Disposal <strong>of</strong> Treated Soil<br />

� Return transport <strong>of</strong> treated soil material to<br />

place <strong>of</strong> origin;<br />

� Transfer to landfills class II.<br />

Dr. Thomas Berger<br />

Bioremediation in Brazil<br />

Ecogerma 2009<br />

São Paulo


TECHNOLOGY TRANSFER<br />

� Technology adaption to climatic conditions;<br />

� Problems with licensing;<br />

� Lack <strong>of</strong> legal and tecnical regulations (no<br />

classification into emplacement classes as Z0 to Z2 <strong>of</strong><br />

the technical rule TR Boden);<br />

� Problems with the importation <strong>of</strong> equipment.<br />

12/03/2009<br />

Dr. Thomas Berger<br />

Bioremediation in Brazil<br />

Ecogerma 2009<br />

São Paulo


Case Study<br />

History:<br />

Soil utilization over a time period <strong>of</strong> about 18 years (1970/80)<br />

as unsecured landfills for:<br />

� Solid waste and liquid, oleaginous sludges;<br />

� Construction waste;<br />

� Insetted landfill layers (soil).<br />

Total volume is estimated to be <strong>of</strong> approx. 30.000 tons <strong>of</strong><br />

contaminated soil with mineral oil hydrocarbons.<br />

Area utilization was stopped about 20 years ago leaving the<br />

substances exposed to natural mechanisms.<br />

12/03/2009<br />

Dr. Thomas Berger<br />

Bioremediation in Brazil<br />

Ecogerma 2009<br />

São Paulo


Case Study<br />

Flow diagram<br />

Treatment plant<br />

12/03/2009<br />

Transport to treatment<br />

plant<br />

Area<br />

After the end <strong>of</strong><br />

the project<br />

Transport to the<br />

client<br />

Dr. Thomas Berger<br />

Bioremediation in Brazil<br />

Reconstitution:<br />

Topography<br />

Vegetation<br />

Release <strong>of</strong> treated<br />

soil<br />

Ecogerma 2009<br />

São Paulo


After Removal <strong>of</strong> Vegetation<br />

12/03/2009<br />

Dr. Thomas Berger<br />

Bioremediation in Brazil<br />

Ecogerma 2009<br />

São Paulo


Topographic Investigation<br />

12/03/2009<br />

Dr. Thomas Berger<br />

Bioremediation in Brazil<br />

Ecogerma 2009<br />

São Paulo


Surface Excavation<br />

12/03/2009<br />

Dr. Thomas Berger<br />

Bioremediation in Brazil<br />

Ecogerma 2009<br />

São Paulo


Separation <strong>of</strong> Oil Sludges<br />

12/03/2009<br />

Dr. Thomas Berger<br />

Bioremediation in Brazil<br />

Ecogerma 2009<br />

São Paulo


Monitoring <strong>of</strong> Gas Emissions<br />

12/03/2009<br />

Dr. Thomas Berger<br />

Bioremediation in Brazil<br />

Ecogerma 2009<br />

São Paulo


Sampling<br />

12/03/2009<br />

Dr. Thomas Berger<br />

Bioremediation in Brazil<br />

Ecogerma 2009<br />

São Paulo


Loading <strong>of</strong> Materials and Transport<br />

to Treatment Plant<br />

12/03/2009<br />

Dr. Thomas Berger<br />

Bioremediation in Brazil<br />

Ecogerma 2009<br />

São Paulo


Return <strong>of</strong> Treated Soil onto the<br />

Before Excavated Surface<br />

12/03/2009<br />

Dr. Thomas Berger<br />

Bioremediation in Brazil<br />

Ecogerma 2009<br />

São Paulo


Conclusion<br />

• Bioremediation is a technology with a high<br />

application potential in Brazil.<br />

• Bioremediation is a technology sparsely<br />

utilized when compared to Germany.<br />

• Legislation/Standardization for this area<br />

should be enhanced.<br />

12/03/2009<br />

Dr. Thomas Berger<br />

Bioremediation in Brazil<br />

Ecogerma 2009<br />

São Paulo


Porto Alegre, RS / Brasil<br />

Rua Dona Gabriela, 128<br />

Bairro Menino Deus<br />

90850-010<br />

Tel. ++55(51) 3232 4242<br />

Fax.++55(51) 3232 8672<br />

info-rs@sapotec.com.br<br />

12/03/2009<br />

Nova Santa Rita, RS / Brasil<br />

Av. Getúlio Vargas, 7360<br />

Bairro Morretes<br />

92480-000<br />

Tel. ++55(51) 3232 4242<br />

Fax.++55(51) 3232 8672<br />

info-nsr@sapotec.com.br<br />

<strong>SAPOTEC</strong> Ltda.<br />

<strong>Zech</strong> Umwelt GmbH<br />

Germany<br />

August-Bebel-Alle I<br />

28329 Bremen<br />

Tel.++(49) (0)421 41007-0<br />

www.zech-umwelt.de<br />

contact@zech-umwelt.com<br />

Dr. Thomas Berger<br />

Bioremediation in Brazil<br />

Campinas, SP / Brasil<br />

Escritório de Apoio<br />

Av. José Bonifácio, 1425/32<br />

Jardim Flamboyant<br />

13091-140<br />

Tel. ++55(11) 9985 0966<br />

info-nsr@sapotec.com.br<br />

São Paulo, SP / Brasil<br />

Rua Franco da Rocha, 137<br />

Cj. 52 – Perdizes<br />

05015-040<br />

Tel. ++55(11) 3822 3681<br />

Info.sp@sapotec.com.br<br />

Ecogerma 2009<br />

São Paulo

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