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Wouter Schroeyers, Leen Hulshagen, Veerle Pellens, Chris<br />

Vandervelpen, Marc Stals, Tim De Clerck, Jan Yperman, Robert<br />

Carleer, Sonja Schreurs<br />

Federale<br />

Overheidsdienst<br />

FINANCIEN


• NuTeC<br />

• NORM projects<br />

– NuTeC-NORM<br />

– B-NORM<br />

– EUR-NORM<br />

• New research topic:<br />

Outline<br />

– treatment of NORM contaminated waste


• XIOS University College (Diepenbeek, Belgium)<br />

– Industrial Sciences: “Nuclear and environmental Engineering”<br />

(Industrial Engineer)<br />

• Environmental Technology-Radiochemistry<br />

• Medical Nuclear Technology<br />

Nuclear Technological Center


• Environmental and Energy related research<br />

• Development and application of nuclear measurement<br />

aperture


• NuTeC<br />

• NORM projects<br />

– NuTeC-NORM<br />

– B-NORM<br />

– EUR-NORM<br />

• New research topic:<br />

Outline<br />

– treatment of NORM contaminated waste


NORM<br />

‘Naturally Occurring Radioactive Material’<br />

phosphate or<br />

zirconium sand<br />

granite<br />

potassium sulfate<br />

bismuth


NORM ‘Naturally Occurring Radioactive Material’<br />

gypsum<br />

deposition in pipeline<br />

gas industry<br />

thorium containing components<br />

fly ash


• Sponsored by:<br />

“NORM” projects<br />

– Flemish Community (Hermesfonds, 45%),<br />

– European Funds for Regional Development<br />

(EFRO-support, 40%)<br />

– XIOS University College Limburg (15%).


• NuTeC<br />

• NORM projects<br />

– NuTeC-NORM<br />

– B-NORM<br />

– EUR-NORM<br />

• New research topic:<br />

Outline<br />

– treatment of NORM contaminated waste


• Aims:<br />

“NuTeC – NORM” project<br />

– “Knowledge diffusion” regarding Natural Occurring Radioactive<br />

Materials by supporting the Flemish Non- Nuclear industry.<br />

Preparing companies for future (European) directives.<br />

• Duration of the project:<br />

– 15/12/08 – 14/12/10<br />

• Collaboration : Federal Agency for Nuclear Control (FANC)<br />

Federale<br />

Overheidsdienst<br />

FINANCIEN<br />

Administratie der Douane en Accijnzen<br />

3 NORM companies


NuTeC –NORM project<br />

1. Construction of a NORM-database<br />

(Harbor of Antwerp)<br />

Federale<br />

Overheidsdienst<br />

FINANCIEN


NORM Database [23/04/07 – 31/08/10]:<br />

Alarms at detection portals at customs of Antwerp:<br />

(103600 ‘events’): Federale<br />

Refractory materials others<br />

Pesticides<br />

Glass fibre<br />

Chemicals<br />

(not containing 40 K)<br />

Ceramics<br />

Fertilizers<br />

Potassium containing compounds<br />

Tobacco<br />

Food<br />

Building materials<br />

Minerals / Ores<br />

Overheidsdienst<br />

FINANCIEN


NuTeC –NORM project<br />

2. Developing a tool to estimate the activity<br />

concentration of NORM<br />

• For comparison:<br />

– NaI and LaBr experiments are benchmarked against a Laboratory<br />

experiment with Germanium detector after taking of sample


METHODOLOGY – Investigation of shipping containers and<br />

big bags<br />

U-238<br />

• Output = activity concentration radionuclide lies<br />

beneath, around or above the limits given by<br />

European Directives for NORM nuclides


NuTeC –NORM project<br />

3. Case Studies at several NORM Companies<br />

� Supplying information and training for companies in working with NORM<br />

� Making an inventory of the presence and activity of NORM and propose<br />

measures for radiation protection.<br />

GMA garnet<br />

K 2SO 4<br />

Rutile sand<br />

Zirconium sand<br />

Fluorspar


NORM industries (New European Directives)<br />

• List of NORM industries which will require regulatory consideration:<br />

– Extraction of rare earth from monazite<br />

– Production of thorium compounds and thorium containing products<br />

– Processing of niobium/tantalum ore<br />

– Oil and gas production<br />

– Geothermal energy production<br />

– TiO 2 pigment production<br />

– Thermal phosphorus production<br />

– Zircon and zirconia industry<br />

– Production of phosphate fertilisers<br />

– Cement production, maintenance of clinker ovens<br />

– Coal-fired power plants, maintenance of boilers<br />

– Phosphoric acid production<br />

– Primary iron production<br />

– Tin/Lead/Copper smelting<br />

– Ground water filtration facilities<br />

– Mining of ores other than Uranium ore<br />

• including relevant secondary processes<br />

• Member States should add other relevant activities


A new method for characterisation of NORM<br />

*European list NORM-industries for strict regulation:<br />

NORM-nuclides:<br />

238 U<br />

232 Th<br />

226 Ra<br />

40 K<br />

Notification if<br />

> 1 Bq/g<br />

> 10 Bq/g


Results on sands<br />

238 U > 1 Bq/g ?<br />

(Ge)


K-40<br />

Results on fertilizers<br />

40 K > 10 Bq/g ?


NuTeC-NORM � educational support<br />

• Training on the job at NORM companies<br />

• Workshops (at companies)<br />

• NORM Forum (www.nutec.be)<br />

• Publication in technical journal (Prevent Actua)<br />

• Part of XIMER course on ENVIRONMENTAL<br />

RADIOACTIVITY: Confronting students with the<br />

historical contamination of NORM industries<br />

• Master and bachelor thesis for students in<br />

Computer sciences / ICT


NuTeC-NORM � educational support<br />

• Sensitization industry regarding the<br />

new directives and confronting<br />

regulators with the practical situation<br />

in industry<br />

– EAN-NORM network<br />

– Presentation of results at several<br />

workshops/ congresses<br />

• 2x on workshop EAN-NORM network<br />

(Dresden)<br />

• NORM & Natural Radiation Management<br />

(London)<br />

• NORM VI (Marrakech),<br />

• 3 e IRPA Congress (Helsinki),


• NuTeC<br />

• NORM projects<br />

– NuTeC-NORM<br />

– B-NORM<br />

– EUR-NORM<br />

• New research topic:<br />

Outline<br />

– treatment of NORM contaminated waste


• Aims:<br />

“B – NORM” project<br />

– “Knowledge diffusion” regarding Natural Occurring Radioactive<br />

Materials in building materials by supporting the Flemish building<br />

industry. Preparing companies for future (European) directives.<br />

• Duration of the project:<br />

– 15/12/10 – 14/12/12<br />

• Collaboration : Federal Agency for Nuclear Control<br />

Federale<br />

Overheidsdienst<br />

FINANCIEN<br />

Administratie der Douane en Accijnzen<br />

Bouwkunde @XIOS


• Materials including by-products or residues from<br />

NORM industries such as<br />

– fly ash,<br />

– phosphogypsum,<br />

– phosphorous slag,<br />

– tin slag,<br />

– copper slag,<br />

NORM in building materials<br />

(New European Directives)<br />

– red mud (residue from aluminium production),<br />

– residues from steel production


B-NORM: Goals<br />

1. Create an inventory of building materials: Determination of activity index<br />

CRa<br />

226 Bq CTh232<br />

Bq CK<br />

40 Bq<br />

I �<br />

� �<br />

300 kg 200 kg 3000 kg<br />

2. Optimization of software tool for building materials and dosimetric studies<br />

3. Radon measurements in buildings + correlation with the technical<br />

properties of the dwelling


NaI vs. LaBr<br />

NaI<br />

LaBr<br />

Peaks related to La 138:1436 keV+X-rays:<br />

� interference with K 40


B-NORM<br />

• Current status<br />

– Contacting building material<br />

manufacturers and<br />

suppliers<br />

– Measurements on bulk<br />

samples<br />

– Creating database with<br />

radiological properties of<br />

several building materials


B-NORM � educational support<br />

• Sensitization industry regarding the new directives and<br />

confronting regulators with the practical situation in the<br />

building sector<br />

• Part of XIMER activity (measuring building materials in<br />

Hasselt)<br />

• Master thesis topics for students in ‘Nuclear Technology’<br />

and from ‘Building Engineering’<br />

– Master student Nuclear Technology (2011-2012)<br />

• Possibilities for PhD?<br />

– XIOS/Uhasselt is trying to acquire new instrument:<br />

Ultra low background germanium detector<br />

– Collaboration with SCK - CEN


• NuTeC<br />

• NORM projects<br />

– NuTeC-NORM<br />

– B-NORM<br />

– EUR-NORM<br />

• New research topic:<br />

Outline<br />

– treatment of NORM contaminated waste


EUR-NORM<br />

Duration of the project: 15 December 2010 – 14 December 2011<br />

Networking to exchange expertise regarding NORM in Europe and to<br />

further spread knowledge regarding NORM related problems<br />

&<br />

To verify in which way the practical implementation of the new European<br />

directives regarding NORM can occur


EUR-NORM: 4th EAN-NORM workshop<br />

• Duo presentations<br />

• Exhibition<br />

• http://www.ean-norm.net/<br />

• Call for abstracts<br />

Contacts:<br />

•Sonja Schreurs: sonja.schreurs@xios.be<br />

•Astrid Schellenberger: schellenberger@iaf-dresden.de


B-NORM � educational support<br />

• Sensitization industry regarding the<br />

new directives and confronting<br />

regulators with the practical situation<br />

in the industry<br />

• Expand European network to<br />

increase the international<br />

possibilities for students<br />

• Visit institutes to explore NORM<br />

related research (master, PhD,<br />

projects,…) collaboration<br />

possibilities.


• NuTeC<br />

• NORM projects<br />

– NuTeC-NORM<br />

– B-NORM<br />

– EUR-NORM<br />

• New research topic:<br />

Outline<br />

– treatment of NORM contaminated waste


NuTeC - Environmental and Energy related research<br />

Characterisation of various types of biomass<br />

(eg. waist products of several industries)<br />

Pyrolyse - Calorimetry


Pyrolysis<br />

� Input: Biomass / waste:<br />

� rapeseed cake<br />

� Metal contaminated willow<br />

� Domestic waste<br />

� Slib from water treatment<br />

� …<br />

� NORM contaminated biomass<br />

or waste?


Pyrolysis<br />

� Output � validation<br />

� Pyrolysis liquid<br />

� Pyrolysis gas<br />

� Char<br />

� Validation (Activated) char carbon:<br />

Adsorbens for metals, radionuclides?


New research topic: a ‘in situ’ strategy for treatment<br />

soil and related waste water<br />

1. Bio- and/or phytoremediation for the<br />

treatment of the radiological contaminated<br />

soils.<br />

2. Contaminated biomass can be converted to<br />

char, liquid and gasses by means of pyrolysis.<br />

3. The (activated) char carbon can be studied for<br />

the treatment of the waste water at the<br />

contaminated site.<br />

Collaboration: XIOS – <strong>UHasselt</strong> – SCK-CEN<br />

Bio-/Phytoremediation<br />

Biodegradability<br />

Pyrolysis<br />

Water treatment /<br />

purification


New research topic<br />

• Educational and research collaboration<br />

possibilities<br />

– PhD / exchange of master thesis students /<br />

projects / …<br />

• Selection of NORM contaminated sites (in<br />

Europe) for study and treatment


NuTeC – www.nutec.be<br />

PHONE: 0032(0)11370794<br />

GSM: 0032(0)472361469<br />

Idea’s for new projects???<br />

Collaboration?<br />

Sonja.schreurs@xios.be<br />

Wouter.schroeyers@xios.be

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