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Joint International Conference on Long-term Experiments ...

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Table 1.The solubility of the calcium oxide in water<br />

and in the in sucrose soluti<strong>on</strong>s in water<br />

Sucrose The solubility of the calcium oxide in the in sucrose soluti<strong>on</strong>s in<br />

water, soluti<strong>on</strong> expressed in g CaO/100 mg, at temperature: [ºC]<br />

g/100 ml<br />

water<br />

0 20 40 60 80<br />

0,0 0,135 0,126 0,109 0,088 0,071<br />

1,5 0,252 0,175 0,132 0,118 -<br />

3,0 0,476 0,280 0,200 0,145 -<br />

6,0 1,172 0,660 0,310 0,212 0,130<br />

12,0 2,082 1,969 0,936 0,422 0,204<br />

18,0 4,140 3,553 1,942 1,168 0,356<br />

MATERIALS AND METHODS<br />

In order to obtain the largest amount of high-quality crystal sugar from the diffusi<strong>on</strong><br />

juice its purificati<strong>on</strong> and removing the n<strong>on</strong>-sugar are required. Actually, the current<br />

systems designed for diffusi<strong>on</strong> juice purificati<strong>on</strong> ensure a n<strong>on</strong>-sugar parts removal<br />

reaching at max. 45% of the n<strong>on</strong> sugar of diffusi<strong>on</strong> juice.<br />

With the purpose of diffusi<strong>on</strong> juice purificati<strong>on</strong> <strong>on</strong>e must make use of cheap<br />

methods and of those substances which would not alter the sugar and are not to cause<br />

sugar loses while n<strong>on</strong> sugar precipitated with these substances are to be easily separated<br />

out of the juice mass and subsequently eliminated. Nowadays, for diffusi<strong>on</strong> juice<br />

purificati<strong>on</strong> <strong>on</strong> utilise calcium oxide and carb<strong>on</strong> dioxide. That is the reas<strong>on</strong> for which<br />

the current technological process of purificati<strong>on</strong> is called “calco-carb<strong>on</strong>ic purificati<strong>on</strong>”.<br />

During the technological process of sugar beet processing, the aim of calco-carb<strong>on</strong>ic<br />

purificati<strong>on</strong> of the diffusi<strong>on</strong> juice is well settled and established. The amount of n<strong>on</strong><br />

sugar eliminated during the purificati<strong>on</strong> process favorably influences the subsequent<br />

development of the technological process in particular those operati<strong>on</strong>s accomplished at<br />

high-level temperatures e.g. the c<strong>on</strong>centrati<strong>on</strong> through vaporizati<strong>on</strong>, boiling and<br />

crystallizati<strong>on</strong> but also the outturn and the quality of the sugar obtained.<br />

The diffusi<strong>on</strong> juice purificati<strong>on</strong> may be accomplished through other methods e.g.<br />

i<strong>on</strong> exchange, ultra-filtrati<strong>on</strong>, i<strong>on</strong>-exclusi<strong>on</strong>, electro-dialysis and inverse-osmosis.<br />

Nevertheless, due to some reas<strong>on</strong>s of ec<strong>on</strong>omic effectiveness, the diffusi<strong>on</strong> juice<br />

purificati<strong>on</strong> obtained by the help of these methods is not used at industrial scale yet.<br />

By definiti<strong>on</strong>, diffusi<strong>on</strong> juice purificati<strong>on</strong> is the operati<strong>on</strong> which aims the optimal<br />

development of the subsequent phases of the technological process. The phases and the<br />

operati<strong>on</strong>s which c<strong>on</strong>stitute the calco-carb<strong>on</strong>ic purificati<strong>on</strong> process and the<br />

technological parameters at the level of which these operati<strong>on</strong>s are executed are all<br />

established functi<strong>on</strong> of the technological quality of the sugar beet and of the diffusi<strong>on</strong><br />

juice processed. The purificati<strong>on</strong> of the diffusi<strong>on</strong> juice must always have a positive<br />

influence up<strong>on</strong> the entire producti<strong>on</strong> process’ effectiveness, an influence materialized as<br />

following:<br />

524

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