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The Columbia EFRC - Lenfest Center for Sustainable Energy ...

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Carbon-based Conductor and Semiconductors.<br />

Philip Kim<br />

Tony Heinz<br />

With Ioannis Kymissis, Charles Black (BNL), Ken Shepard.<br />

Conventional solar cells need work<br />

functions matched to materials.<br />

Simplified band diagram (shown at V oc) of a P3HT:PCBM solar cell<br />

having PEDOT and Al contacts.<br />

Band offsets are major source of loss!<br />

Graphene work function is controllable through<br />

chemical doping and through applied electric fields.<br />

Program Goal: Develop carbon-based electrode structures <strong>for</strong> high<br />

efficiency charge extraction from nanostructured heterojunction devices.<br />

file: <strong>Lenfest</strong> Symp 05-04-10 rev b.ppt Page 23

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