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Clevertex - Grado Zero Espace Srl

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2.6.2.2 Patents published<br />

The company International Flavors & Fragrances patented the method of making a fragrance<br />

containing fibre in US 6517759.<br />

2.6.3 Applications in the interior textile sector<br />

2.6.3.1 Research projects and products<br />

2.6.3.2 Patents published<br />

2.6.4 Applications in the technical textile sector<br />

2.6.4.1 Research projects and products<br />

In 1950, two researchers (W. Kuhn and A. Katchalsky) developed fibres being able to contract under<br />

the influence of a pH change. However, a disadvantage was the slow reaction time of the polymer: the<br />

change lasted for some minutes. Through the years, other fibres have been developed having much<br />

shorter reactions: from a few seconds (De Rossi 1987) to a few tenths of seconds (Suzuki 1989).<br />

These fibres also have a high tensile strength.<br />

The degree of contraction and the developed forces equal those of a human muscle.<br />

At the University of New Mexico, U.S., research is going on into the development of artificial muscles.<br />

To this end, a polyacrylonitrile fibre, ORLON 11 is used. A few years ago, researchers discovered that<br />

PAN fibres are able to contract when the degree of acidity in the surroundings changes. In two tenths<br />

of a second, they can shrink 20%, this is almost as fast as a human muscle. Depending on the degree<br />

of acidity, PAN fibres can contract to half or a tenth of their original length. Moreover, the fibres are<br />

strong: they can bear up to 4 kg/cm 2 , which is more than a human muscle.<br />

A big disadvantage of these PAN muscles is the need of a chemical activator. The possibilities would<br />

become more extensive if one would succeed in having the artificial muscles functioning with<br />

electricity for example [3].<br />

Superabsorbent polymers are produced by polymerising acrylic acid to become crosslinked sodium<br />

poly-acrylate. The carboxylic groups of the absorbent polymer are solvated when brought into contact<br />

with a water based liquid. As a result, the groups partially dissociate into negatively charged carboxylic<br />

ions. In this state, the polymer chain contains a large number of similarly charged ionic groups which<br />

repel each other. The polymer coils become more bulky and thus extend their propensity to absorb<br />

11 ORLON is an acrylic fibre produced by the company Du Pont<br />

123

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