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Fig. 110 Flap opening in the textile structure [195]<br />
The project has been chosen as one of eight to represent United Kingdom science at Expo 2005 in<br />
Japan.<br />
Fig. 111 ........Temperature regulating jacket exhibited at EXPO 2005<br />
Another example of fabrics that change their performance in response to moisture is textiles coated<br />
with a polyurethane film. The company Baxenden Chemicals has developed a hydrophilic<br />
polyurethane coating for textiles that becomes more breathable, the more moisture is build up inside<br />
the clothing. In general, a solid, hydrophilic polyurethane coating constantly adapts to surrounding<br />
conditions of water vapour pressure. Their resistance values decrease with the amount of water<br />
contained in the polymer. In extreme cases, when liquid water is in contact with the polymer surface,<br />
hydrophilic polyurethanes reversibly absorb up to three water molecules per ethylene oxide unit and<br />
may become swollen. In this state water vapour transport through the molecular network is enhanced<br />
and the diffusion coefficient increases [58].<br />
Researchers at the Indian Institute of Technology succeeded in developing a smart breathable cotton<br />
fabric coating which responds to changes in ambient temperature. They used a temperature sensitive<br />
copolymer-poly (N-tert-butylacrylamide-ran-acrylamide). The coating on the fabric shows a retained<br />
temperature-sensitive swelling behaviour and a transition in the temperature range of 15-40°C. Below<br />
15°C, the coating swells by 800% while above 40°C it deswells to a swelling percentage of less than<br />
50% (on the basis of dry weight). The response was found to be reversible and stable to repeated<br />
cycles of transition [196].<br />
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