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Redefining Reality - The Intellectual Implications of Modern Science

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In 1873, James Clerk Maxwell published a paper called “Molecules,”<br />

in which he derived the ideal gas law from a mechanical picture <strong>of</strong><br />

gases—a picture in which a gas is a collection <strong>of</strong> atoms. It would<br />

have been a massive coincidence if the law accidentally fell out<br />

<strong>of</strong> the atomic picture. Everything in the results is macroscopically<br />

measurable except one thing—the number <strong>of</strong> molecules. <strong>The</strong><br />

anti-atomistic chemists would have to say that it was a lucky but<br />

meaningless occurrence that assuming atoms generates a world that<br />

behaves exactly like this one.<br />

From Avogadro’s work, it follows that the number <strong>of</strong> molecules in<br />

<br />

or .<br />

To determine Avogadro’s number would be to make a statement<br />

about the reality <strong>of</strong> atoms. Such physicists as Albert Einstein<br />

and Jean Perrin became serial derivers <strong>of</strong> Avogadro’s number<br />

and found it everywhere—in the study <strong>of</strong> gases, liquids, alpha<br />

particles, cathode rays, and so on.<br />

<br />

Einstein proposed a way to experimentally determine<br />

<br />

to do. Perrin took up the challenge and, through painstakingly<br />

delicate work, determined Avogadro’s number and showed it<br />

to be a constant across many different situations. Perrin’s work<br />

<br />

<br />

<br />

In 1897, the British physicist J. J. Thomson discovered that the<br />

cathode rays physicists had been investigating were actually<br />

negatively charged particles, what we now know as electrons.<br />

Scientists eventually realized that these were pieces <strong>of</strong> atoms that<br />

were capable <strong>of</strong> being stripped out. Atoms had parts and structure.<br />

<br />

Because atoms were electrically neutral and electrons were<br />

negative, there had to be a positive part <strong>of</strong> the atom to balance out<br />

the electrons. But there didn’t seem to be a positive correlate to the<br />

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