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EO Regulations Review - Simple assimilative capacity model for transitional waters<br />
Background<br />
This model is used indicate a given licence’s compliance with Article 7 of the European<br />
Communities <strong>Environmental</strong> Objectives (Surface Waters) Regulations 2009.<br />
The model estimates, for a given discharge parameter, the resultant concentration in a<br />
receiving waterbody which has freshwater and saltwater inputs. Using the salinity values of<br />
the ‘open’ water and in the vicinity of the discharge, it estimates the flow of dilution water<br />
(i.e. seawater and freshwater inputs) within the estuary. This figure is then divided in to the<br />
mass flow rate of the substance being discharged to calculate its concentration in the<br />
receiving waters.<br />
The salinity value in the vicinity of the discharge point may be determined directly by the<br />
applicant from sampling analysis. Otherwise this salinity value may be taken as the salinity<br />
of the entire WFD ‘transitional’ waterbody within which the discharge is located. The open<br />
water salinity value may be taken as the salinity value for the WFD ‘coastal’ waterbody<br />
adjacent to transitional waterbody.<br />
Please Note: This model should only be used in the absence of more comprehensive<br />
modelling that may have already been completed for the current licensed discharges.<br />
Sources of data<br />
To determine the transitional and coastal waterbodies relevant to your discharge, you may<br />
use the EPA’s Envision website (using the WFD status layer).<br />
http://maps.epa.ie/InternetMapViewer/mapviewer.aspx<br />
Salinity data for most waterbodies in question should be available from the following EPA<br />
download file: http://www.epa.ie/downloads/data/water/name,30857,en.html (If using this<br />
download file, please use an average of the summer and winter median values.) More<br />
accurate salinity values and other information on estuaries is available from Shane O’Boyle,<br />
EPA Regional Inspectorate, Dublin (01 268 0100). For instances where salinity values for<br />
open water are not available from the <strong>Agency</strong>, the licensee may assume that the salinity<br />
value of the open water is 35 p.s.u.<br />
River flow data (95%ile) is also required for this model. This data is available from a number<br />
of sources, as listed below:<br />
� Long term flow records -Low Flow Statistics at selected hydrometric stations<br />
http://www.epa.ie/downloads/pubs/water/flows/name,30473,en.html<br />
� EPA HydroNet -online hydrometric data http://hydronet.epa.ie<br />
� Hydro-Data provided by the OPW http://www.opw.ie/hydro/
� For non-gauged locations use the EPA Hydrotool. This system provides an estimate<br />
of flows exceeded for 5% -95% of time. Register as a user at:<br />
http://watermaps.wfdireland.ie/HydroTool/Authentication/Register.aspx<br />
General queries on the use of this model should be directed to Gavin Clabby, EPA Regional<br />
Inspectorate, Inniscarra, County Cork. (021 487 5540)<br />
Model<br />
The model formula for calculating the flow of available dilution water (Qd) is as follows:<br />
Qd = (Qe + Qf) So/ (So-S) where Qe is the flow rate of licensed discharge (m 3 /s)<br />
Qf is the flow rate of the river (m 3 /s)<br />
So is the salinity of the open water<br />
S is the salinity of the water in the vicinity of licensed<br />
discharge<br />
The licensee will be required to measure, or otherwise obtain values, for Qe, Qf, S and So.<br />
Please see appendix for full derivation of the above equation.<br />
Once the value for Qd is established it can be substituted into the following formula to<br />
calculate the concentration (C) of a given discharged substance in the receiving water:<br />
C = Cb + [ (Ce - Cb)/ (1 + (Qd / QL)) ] where QL is the maximum flow of the discharged<br />
substance allowable under the licence.<br />
Cb is the background concentration.<br />
Ce is the maximum effluent discharge concentration<br />
allowable under the licence.<br />
NB When dividing Qd by QL, ensure units are consistent. If no max flow limit is specified in the<br />
licence, please use your declared maximum hourly rate or contact the reviewing inspector to<br />
discuss.<br />
Worked example<br />
• An industrial plant is licensed to discharge 0.5m 3 /s of effluent into an estuary (good<br />
status). This licensed discharge has and ELV of 5mg/l P for Orthophosphate (MRP).<br />
The mean background concentration of MRP is 0.02mg/l P. The 95%ile flow of the<br />
river entering the estuary is 10m 3 /s.<br />
• Salinity values for the discharge point (transitional) waterbody and the coastal<br />
waterbody were determined to be 19 p.s.u. and 33 p.s.u. respectively.
• Estimate the concentration of MRP of the receiving water in the vicinity of the<br />
discharge.<br />
Solution:<br />
i) Compute flow rate of available dilution water<br />
Qd = (Qe+Qf)So/(So-S)<br />
= (0.5 + 10) x 33 / (33 – 19)<br />
= 24.75 m 3 /s<br />
ii) Compute mean concentration of MRP in receiving water<br />
C = Cb + [(Ce - Cb)/ (1 + (Qd / QL))]<br />
= 0.02 +[ (5 - 0.02)/ (1 + (24.75/0.5))]<br />
= 0.02 + [4.98/ (1 + 49.5)]<br />
= 0.119 mg/l P<br />
This value is greater than the relevant MRP limit for 19 p.s.u. (0.058 mg/l P).<br />
� Therefore, the licence ELV, as set, does not appear compliant with Surface Waters<br />
Regulations 2009.<br />
(Please Note: EO Regulation limits for MRP in Transitional Waters are dependent on the<br />
salinity and WFD status of the receiving water. For convenience a table with the<br />
salinity/status dependent limits is available on the EPA website.)
Appendix<br />
1. Illustration of a typical estuary with indicated waterbodies and parameters relevant<br />
to equation.<br />
coastal Water body transitional waterbody river waterbody<br />
2. Derivation of model formula<br />
From salt mass balance:<br />
Qo So = (Qo + Qe + Qf)S => Qo So = QoS + QeS + QfS<br />
Qo So - QoS = + QeS + QfS => Qo (So – S) = + (Qe + Qf)S<br />
Therefore Qo = (Qe + Qf)S/(So - S)<br />
Qd = Qo + Qe + Qf => Qd = (Qe + Qf)S/(So - S) + Qe + Qf<br />
Qd(So - S) = (Qe + Qf)S + Qe(So - S) + Qf(So - S) => QdSo - QdS = Qe So + Qf So<br />
Therefore Qd = (Qe + Qf) So/ (So - S)