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Solid & Liquid State Hydrogen Storage Materials<br />

Dr. Gary Sandrock<br />

Private Consultant<br />

Davis, CA, USA<br />

Operating Agent for the<br />

U.S. Department of Energy<br />

ORIGINS & OVERVIEW<br />

Task 17 is oriented toward hydrogen<br />

storage, a key problem in the imple­<br />

mentation of H 2 fuel and the creation of<br />

the hydrogen economy. In particular,<br />

it focuses on predominantly solid­state<br />

hydrogen storage materials such as<br />

metal hydri<strong>de</strong> absorbents and high<br />

surface area absorbents. It was <strong>de</strong>rived<br />

from earlier Task 12 (Metal Hydri<strong>de</strong>s and<br />

Carbon for Hydrogen Storage), which<br />

was completed in 2000 and summarized<br />

in the Final Report available at the IEA<br />

Hydrogen Implementing Agreement<br />

website (http://www.ieahia.org). Task 17<br />

was begun in June 2001 and is sched­<br />

uled to expire at the end of May 2006.<br />

The thirteen national participants are<br />

Australia, Canada, the European Com­<br />

mission, Finland, Italy, Japan, Lithuania,<br />

Norway, Spain, Swe<strong>de</strong>n, Switzerland,<br />

the United Kingdom and the United<br />

States. This report summarizes the<br />

constitution of the Task as of the end<br />

of 2005, its targets, and its technical<br />

projects. A more complete and techni­<br />

cally <strong>de</strong>tailed Annual Report can be<br />

found at the Task’s website (http://hyd­<br />

park.ca.sandia.gov/ieaframe.html). As<br />

Task 17 moves toward its end, plans are<br />

being ma<strong>de</strong> to forge a new IEA HIA An­<br />

nex that will involve more countries and<br />

operate in close communication with<br />

H­storage activities contained within the<br />

International Partnership for the Hydro­<br />

gen Economy (IPHE).<br />

& PROJECT TYPES<br />

The Task is oriented toward the<br />

<strong>de</strong>velopment of new reversible hydrogen<br />

storage media with increased gravi­<br />

metric and volumetric capacity, along<br />

with the <strong>de</strong>velopment of fundamental<br />

un<strong>de</strong>rstandings of those materials so as<br />

ress. The main application of interest is<br />

onboard vehicular H­storage (Target 1,<br />

below), although stationary storage is<br />

also in the Task’s R&D thinking (Target<br />

2, below). The vehicular storage work<br />

assumes a PEM fuel cell or internal<br />

combustion engine as the source of<br />

propulsion, thus setting the maximum<br />

temperature available from waste heat.<br />

for the required enthalpy for H 2 liberation<br />

from the storage media. The stationary<br />

storage work is oriented toward low cost<br />

H 2 <strong>de</strong>stined for fuel cell use. Thus, the<br />

three targets resulting from the above<br />

philosophies can be stated as follows:<br />

1. Develop a reversible hydrogen<br />

storage medium with > 5 wt.% H 2 re­<br />

coverable at < 80˚C and 1 bar absolute<br />

pressure, with charging and discharging<br />

rates suitable for practical use in a fuel<br />

cell or internal combustion engine H 2 ­fu­<br />

eled vehicle.<br />

2. Develop a low­cost, revers­<br />

ible hydrogen storage medium that can<br />

be rapidly charged and discharged at<br />

near­ambient temperatures, is tolerant<br />

to impurities in the H 2 used, and dis­<br />

charges hydrogen of ultra high purity for<br />

use directly in a PEM fuel cell.<br />

3. Develop the fundamental and<br />

engineering un<strong>de</strong>rstanding of hydrogen<br />

storage <strong>by</strong> advanced storage media that<br />

have the capability of meeting Targets 1<br />

5<br />

“Task 17 is<br />

oriented toward the<br />

<strong>de</strong>velopment of new<br />

reversible hydrogen<br />

storage media with<br />

increased gravimetric<br />

and volumetric<br />

capacity, along with<br />

the <strong>de</strong>velopment<br />

of fundamental<br />

un<strong>de</strong>rstandings of<br />

those materials.”<br />

“The main<br />

application of<br />

interest is onboard<br />

vehicular H­storage.”

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