Oscillations, Waves, and Interactions - GWDG

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376 U. Kaatze and R. Behrends Figure 7. Ultrasonic excess attenuation spectra for aqueous solutions of 1 mol/l D-xylose at 25 ◦ C without CaCl2 (◦) and with 1 mol/l CaCl2 added (•). Dotted and dashed lines indicate the subdivision of the former and the latter spectrum, respectively, in Debye-type relaxation terms. Solid lines represent the sum of these terms, respectively [46]. form inclusion complexes with a variety of molecules [51–55] and ions [56–60], including drugs [61,62]. Due to the hydrophilic outer surface of the cyclodextrin cone the complexes with guest molecules are soluble in water. Cyclodextrins are thus used to enhance or provide the solubility of molecules or organic ions, they act as stabilizers, selective agents, molecular recognition systems and also as capsules for the controlled delivery of specific molecules, with wide fields of applications. Recently α-cyclodextrin (α-CD)-iodide (I − ) complex formation has been found [60] that follows the simple equilibrium kf − α − CD + I ⇋ r k α − CD · I− where α − CD · I − denotes the monoiodide inclusion complex and k f and k r are the forward and reverse rate constants, respectively, related to one another by the (17) Figure 8. Structure of a tridentate calcium ion-anhydroglucopyranoside complex.
Liquids: Formation of complexes and complex dynamics 377 Figure 9. Scheme of relaxation process associated with a chemical equilibrium between species X and species Y. equilibrium constant K = k f /k r . (18) Within the framework of the simple reaction scheme shown in Fig. 9, the species on both sides of Eq. (17) differ from one another by the volume difference ∆V and the enthalpy difference ∆H. They are separated from one another by the enthalpy barriers ∆H ♯ X and ∆H♯ Y = ∆H♯ X + ∆H, where normally ∆H ≪ ∆H♯ X , thus ∆H♯ Y ≈ ∆H ♯ X . Here X and Y denote α − CD + I− and α − CD · I − , respectively. The van’t Hoff equation d ln K = −∆H d T −1 R relates the equilibrium constant to the enthalpy difference ∆H, indicating that, according to our expectations, the larger the reaction enthalpy ∆H the larger K, that is the more the equilibrium is shifted to the right-hand side of Eq. (17). The thermal activation relaxation scheme of Fig. 9 predicts ultrasonic excess attenuation that features Debye-type relaxation characteristics with the relaxation time τ given by and the relaxation amplitude following as (αλ) exc = RD(ν) = Aωτ 1 + ω 2 τ 2 τ −1 = k f � [α − CD] + � I −� + K −1� (19) (20) (21) A = πΓc(∞) RT ∆V 2 S . (22)
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Thomas Kurz, Ulrich Parlitz, and Ud
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erschienen im Universitätsverlag G
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Bibliographische Information der De
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iv Contents Laser speckle metrology
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Oscillations, Waves and Interaction
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Applied physics at the “Dritte”
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noise component [GNE] 5 4 3 2 1 can
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3.4 Transfer to running speech Spee
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3.4.2 Analysis of running speech Sp
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Speech research 33 Area [Pixels] 60
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Speech research 35 [13] D. Michaeli
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Specific signal types in hearing re
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74 D. Ronneberger et al. Mechel fou
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76 D. Ronneberger et al. (flow velo
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78 D. Ronneberger et al. |t + acous
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80 D. Ronneberger et al. Figure 6.
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82 D. Ronneberger et al. Figure 8.
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84 D. Ronneberger et al. (flow velo
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86 D. Ronneberger et al. R / L ⋅
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88 D. Ronneberger et al. e. g. temp
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90 D. Ronneberger et al. 3.2 Qualit
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92 D. Ronneberger et al. As usual t
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94 D. Ronneberger et al. (wavenumbe
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96 D. Ronneberger et al. powers of
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98 D. Ronneberger et al. an increas
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100 D. Ronneberger et al. The term
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102 D. Ronneberger et al. Neverthel
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104 D. Ronneberger et al. [4] J. Br
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106 D. Ronneberger et al. strömung
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108 D. Guicking synchronised tuning
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110 D. Guicking primary noise micro
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112 D. Guicking primary sensor desi
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114 D. Guicking by an antiphase sou
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116 D. Guicking R L C C + + 1 1−C
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118 D. Guicking More involved than
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120 D. Guicking In the 1980s, longi
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122 D. Guicking with electrodynamic
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124 D. Guicking 3.6 Noise reduction
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126 D. Guicking the turbulence of a
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128 D. Guicking References [1] Lord
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130 D. Guicking [44] Falcke, H.,
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132 D. Guicking [84] J. Melcher,
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134 D. Guicking [125] D. Heyland et
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136 D. Guicking [166] S. Zommer et
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138 D. Guicking [212] M. L. Post an
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140 W. Lauterborn et al. liquid κ
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142 W. Lauterborn et al. Figure 2.
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144 W. Lauterborn et al. nator, and
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146 W. Lauterborn et al. by types a
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148 W. Lauterborn et al. bubble rad
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154 W. Lauterborn et al. P koll [kb
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156 W. Lauterborn et al. Pulse widt
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158 W. Lauterborn et al. laser puls
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168 W. Lauterborn et al. R [µ m] 1
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170 W. Lauterborn et al. [17] M. P.
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172 R. Mettin (a) (b) Figure 1. Bub
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174 R. Mettin 0 ms 2 mm 1 ms 2 ms 3
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176 R. Mettin important quantity ch
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178 R. Mettin 100 kPa 200 kPa | | F
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180 R. Mettin Figure 7. Trapped sin
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182 R. Mettin concentration of spec
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184 R. Mettin which is called the p
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186 R. Mettin R 02 [µm] R 02 [µm]
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188 R. Mettin constant to M a = 2π
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190 R. Mettin (a) p a [Pa] 140 120
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192 R. Mettin z [mm] 5 4 3 2 1 0 -1
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194 R. Mettin Figure 17. Left: Expe
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196 R. Mettin - a hot microlaborato
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198 R. Mettin [52] R. Mettin, C.-D.
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200 W. Eisenmenger and U. Kaatze Th
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202 W. Eisenmenger and U. Kaatze Fi
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214 W. Eisenmenger and U. Kaatze 6
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216 W. Eisenmenger and U. Kaatze Pr
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218 A. Vogel, I. Apitz, V. Venugopa
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260 K. D. Hinsch Generally, any of
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262 K. D. Hinsch Figure 1. Monitori
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264 K. D. Hinsch Figure 3. ESPI stu
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266 K. D. Hinsch Figure 4. Deterior
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268 K. D. Hinsch Often, in-plane mo
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270 K. D. Hinsch Figure 7. Optical
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272 K. D. Hinsch Figure 9. Humidity
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274 K. D. Hinsch locations that tak
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276 K. D. Hinsch Figure 13. Map of
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278 K. D. Hinsch References [1] D.
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280 Schreiber not moving along with
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282 Schreiber These properties made
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284 Schreiber Figure 3. The G ring
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286 Schreiber Rotation Rate [rad/s]
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288 Schreiber and it is currently b
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290 Schreiber n1 D A B n Figure 8.
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292 Schreiber Beamwalk [µm] 80.0 7
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294 Schreiber ∆ Perimeter [*10e12
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296 Schreiber and the last term acc
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298 Schreiber Δf [µHz] 100 50 0 -
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300 Schreiber formation of a new wo
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302 Schreiber PSD [*10 16 (rad/s) 2
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304 Schreiber 7.2 The ring laser co
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306 Schreiber Demodulator Signal [V
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308 Schreiber Est. Phase Vel. (m/s)
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310 Schreiber [18] V. Frede and V.
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312 Martin Dressel tice is reduced
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314 Martin Dressel Metallic whisker
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316 Martin Dressel (a) (b) (c) CH 3
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318 Martin Dressel 3.1 Charge densi
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320 Martin Dressel Absorptivity σ
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322 Martin Dressel brought a confir
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324 Martin Dressel a charge disprop
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426 U. Parlitz LD1 LD2 M BS1 BS2 OD
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428 U. Parlitz with a clear tendenc
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430 U. Parlitz (a) y (c) y 40 20 È
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432 U. Parlitz [29] P. Grassberger,
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434 U. Parlitz [76] H. D. I. Abarba
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436 S. Lakämper and C. F. Schmidt
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462 Index basin of attraction, 144
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464 Index cone bubble structure, 19
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466 Index turbulent, 111, 126 fluct
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468 Index LPC, 29 luminescence of b
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470 Index peak factor, 38, 43 Peier
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472 Index laser-induced bubble, 152
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474 Index ultraharmonic resonance,
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