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33 Years NEET-AIPMT Chapterwise Solutions - Physics 2020

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114 NEET-AIPMT Chapterwise Topicwise Solutions Physics

\ Total energy

1

= − = − P.E.

P.E. P.E.

=−34

. eV.

2 2

\ K.E. = + 3.4 eV

24. (a)

25. (a) : Radius of first orbit, r ∝ 1 ,

Z

for doubly ionized lithium Z (= 3) will be maximum,

hence for doubly ionized lithium, r will be minimum.

2

Z

26. (a) : E ∝

2

n

27. (a)

28. (a) : Centripetal force = force of attraction of

nucleus on electron

2 2

mv 1 e

e

= v

a0 0 a0 2 ⇒ =

4πε

4πε0a0m

29. (c) : Energy of the ground electronic state of

hydrogen atom E = –13.6 eV.

We know that energy of the first excited state for second

orbit (where n = 2)

13.

6 136 .

En =− =− =− 34 . eV.

2 2

( n)

() 2

30. (b) : When a hydrogen atom is in its excited level,

then n = 2.

Therefore radius of hydrogen atom in its first excited

level (r) = n 2 r 0 = (2) 2 r 0 = 4r 0 .

31. (d) : According to Bohr’s principle, radius of orbit

2 2

(r) = 2

4πε0

× nh

; r

2 2

me

∝ n

where n = principal quantum number.

32. (d)

33. (a) : As r ∝ n 2 , therefore, radius of 2 nd Bohr’s orbit = 4a 0

34. (d) : E = E 4 – E 3

13. 6

=− − ⎛ 13.

6 ⎞

4 3

=− 085 . + 151 . = 066 . eV

2 2

35. (a) : Second excited state corresponds to

n = 3

Energy needed to ionize,

∴ E = 13 . 6 eV = 151 . eV

2

3

36. (b) : Bohr used quantisation of angular momentum.

nh

For stationary orbits, Angular momentum mvr = 2π

where n = 1, 2, 3,...etc.

37. (d) : E ∝ Z 2 and Z for singly ionised helium is 2 (i.e.,

2 protons in the nucleus)

\ (E) He = 4 × 13.6 = 54.4 eV

38. (c) : When electron jumps from higher orbit to

lower orbit then, wavelength of emitted photon is given

by,

so,

1 1 1

λ = ⎛

2 − ⎞

R

⎜ 2 ⎟

⎝ n f n i ⎠

1 1 1 5

λ = R ⎛

2 2

2

− ⎞

3 ⎠

⎟ = R 1 1 1 7

and

36 ′ = ⎛

2 2

3

− ⎞

4 ⎠

⎟ = R

R

λ

144

144 5λ

20λ

∴ λ′ = × =

7 36 7

39. (c) : Energy of the photon, E = hc

λ

−34 8

663 . × 10 × 3×

10

E =

J

−10

975 × 10

−34 8

663 . × 10 × 3×

10

=

eV = 12.

75 eV

−10 −19

975 × 10 × 16 . × 10

After absorbing a photon of energy 12.75 eV, the electron

will reach to third excited state of energy –0.85 eV, since

energy difference corresponding to n = 1 and n = 4 is

12.75 eV.

\ Number of spectral lines emitted

40. (d)

()( n n− 1) ()( 4 4− 1)

= = = 6

2 2

41. (a) : According to Rydberg formula

1 1 1

λ = ⎡

2 − ⎤

R ⎢ 2⎥

⎣⎢

n f n i ⎦⎥

Here, n f = 1, n i = 5

1 ⎡ 1 1 ⎤

∴ = ⎢ − ⎥

⎣ ⎦

= ⎡1

⎢ − 1 ⎤

1 5 1 25

= 24

λ R 2 2

R 25

R

According to conservation of linear momentum, we get

Momentum of photon = Momentum of atom

h

h h R hR

mv v

λ

= = mλ

= ⎛ 24 ⎞ 24

or

m ⎝

⎟ =

25 25 m

42. (d)

43. (c) :

The maximum wavelength emitted here corresponds to

the transition n = 4 → n = 3 (Paschen series 1 st line)

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