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OELCHECKER - Spring 2012

> Putzmeister - offering quality worldwide > Analysis kits and gas-tight sample bottles for refrigeration compressor oils > More playtime fun - thanks to OELCHECK! > 2012 customer survey results > The viscosity robot - the new OELCHECK laboratory assistant > Underground maintenance - K+S KALI GmbH workshops > Electrostatic discharges in hydraulic oils and lubricants > Question time: Could lengthy storage times have an influence on your oil samples? > and much more...

> Putzmeister - offering quality worldwide
> Analysis kits and gas-tight sample bottles for refrigeration compressor oils
> More playtime fun - thanks to OELCHECK!
> 2012 customer survey results
> The viscosity robot - the new OELCHECK laboratory assistant
> Underground maintenance - K+S KALI GmbH workshops
> Electrostatic discharges in hydraulic oils and lubricants
> Question time: Could lengthy storage times have an influence on your oil samples?
> and much more...

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OELCHECK INSIDER INFO<br />

Optimised analysis kits and gas-tight<br />

sample containers for refrigeration compressor oils<br />

Our test procedures selected for analysing oils from refrigeration compressors have<br />

proven themselves time and time again over the years. However, we have further<br />

optmised the tests, our laboratory equipment and the sample containers for these<br />

products yet again. It‘s not just the users of modern synthetic refrigeration machine<br />

oils who are benefiting!<br />

New analysis kits VK1 and VK2 for refrigeration compressor oils identify:<br />

• Wear metals: iron, chrome, tin, aluminium, nickel, copper, lead and molybdenum<br />

• Additives: calcium, magnesium, zinc, phosphorus, barium, boron and sulphur<br />

• Contaminants: silicon, potassium, sodium and lithium<br />

• PQ index<br />

◦ Oxidation<br />

• Optical check (colour change, visible particles)<br />

◦ Special outgassing process<br />

• Viscosity at 40°C and 100°C as well as the viscosity index ◦ Water content according to<br />

Karl Fischer<br />

In addition to the tests above for analysis kit VK 2:<br />

Neutralisation Number (NN) or Acid Number (AN) or Base Number (BN)<br />

Refrigeration compressor oils should lubricate, minimise<br />

friction, protect from wear and corrosion, cool,<br />

clean, prevent deposits and create a seal or reduce<br />

any leakage flow in the compression chamber. However,<br />

for the most part they also come into direct<br />

contact with the refrigerating agent. A refrigeration<br />

machine oil therefore has to work in harmony<br />

with it as much as possible. Impurities from seal<br />

materials or negative impacts from moisture or even<br />

water are one of the criteria for an oil change or<br />

additional oil servicing measures. The temperatures<br />

during compression of the gaseous refrigerating<br />

agent of up to 120°C can significantly accelerate<br />

oil oxidation, hence its ageing. During an oxidation<br />

process, mostly acids form in the oil which can have<br />

a corrosive effect on the compressor components,<br />

particularly if there is any residual moisture.<br />

The production capacity of the refrigeration compressor<br />

oil and its interaction with the refrigerating<br />

agent have decisive effects on the service life of the<br />

compressor. Therefore, regular lubricant analyses<br />

are vital. They provide information on the condition<br />

of the oil and the complex chemical reactions that<br />

have taken place in the compressor oil. If necessary,<br />

any potential damage and disruptions to operations<br />

can be counteracted.<br />

There are special OELCHECK analysis kits for the<br />

extremely important task of monitoring refrigeration<br />

compressor oils. When the test processes in the kits<br />

were compiled, not only were our experience and<br />

the recommendations of previous compressor and<br />

oil manufacturers taken into consideration, but also<br />

the specifications of work group E-DIN 51503-2.<br />

NEW<br />

Acids or bases in refrigeration machine<br />

oils<br />

The Neutralisation Number (Acid Number or AN)<br />

provides information on the level of mineral acids as<br />

well as water-soluble and insoluble organic acids in<br />

a refrigeration compressor oil. Mineral acids, such<br />

as hydrochloric or hydrofluoric acid, are formed<br />

through the decomposition of halogen refrigerating<br />

agents or upon interaction with the refrigeration machine<br />

oil. Organic acids result from the oxidation of<br />

refrigeration machine oils and the decomposition of<br />

ester oils. All of these acids lead to the corrosion of<br />

the metallic materials in refrigeration systems, promote<br />

oil ageing and cause unfavourable changes in<br />

the electrical isolation values of motor compressors.<br />

The Base Number (BN) provides information on<br />

the level of alkaline substances in the oil. They<br />

are caused by oxidation in ammonia refrigeration<br />

systems in the case of thermal loading. Inside the<br />

compressor they lead to oil silting and on the hot<br />

side, in pressure chambers<br />

and on valves, to<br />

carbonaceous deposits.<br />

Top tip: If you want to learn more about<br />

refrigeration machines and their oils, read the<br />

article „OELCHECK analyses keep refrigeration<br />

machines fit“ in ÖlChecker Summer 2008 at<br />

www.oelcheck.de.<br />

New sample containers<br />

With pre-paid kits VK1 and VK2 for oils from refrigeration<br />

compressors, from now on, customers<br />

are provided with newly designed gas-tight 100 ml<br />

sample containers made from shatter-proof glass<br />

with a metal lid. They are suitable for all oil types<br />

and refrigerating agents. In addition, they can withstand<br />

the internal pressure, which can build up due<br />

to residual refrigerating agent in the sample. The<br />

sample amount is extracted via the oil outlet provided<br />

by the manufacturer in the compressor circuit.<br />

If the sample foams quite heavily, some of the gas<br />

can be released from the refrigerating agent prior<br />

to sealing. Gas should not be released if a synthetic<br />

compressor oil is used and/or ammonia is used as<br />

a refrigerating agent. The container must be carefully<br />

sealed immediately since these substances are<br />

extremely hygroscopic and can soak up moisture<br />

from the air even if the contact with the atmosphere<br />

is short.<br />

Extensive sample preparation<br />

The individual process steps were redesigned for<br />

refrigeration machine oils. A partial quantity of max.<br />

5 g is directly extracted when the sample container<br />

is first opened. That way, the exact water content<br />

can be ascertained according to the Karl Fischer<br />

method. To ascertain the other values, the proportions<br />

of refrigerating agents in the sample must<br />

be removed. The opened sample containers are<br />

therefore clamped in a gas-tight appliance. After<br />

the samples are warmed to 80°C, inert gas flows<br />

through the oil until no more refrigerating agent<br />

can be found in the waste air flow. Only after this<br />

process, which lasts for more than an hour, has<br />

been completed, is the sample ready for further<br />

extensive laboratory tests.<br />

Our technical team can advise you on the right analysis kit for you:<br />

+49(0)8034-9047-210, tsek@oelcheck.de.<br />

Measuring the Neutralisation Number for refrigerating machine oils in the<br />

OELCHECK laboratory

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