TiO - Creon
TiO - Creon TiO - Creon
DuPont and Titanium Dioxide April 2006 © 2004 E.I. du Pont de Nemours and Company. All Rights Reserved. The DuPont oval, the miracles of science, DuPont and Product Name® are trademarks or registered trademarks of E. I. du Pont de Nemours and Company.
- Page 2 and 3: Titanium Dioxide � Premium white
- Page 4 and 5: TiO 2 Characteristics � 1918 - Fi
- Page 6 and 7: World TiO 2 Market Demand 2005* Nor
- Page 8 and 9: Regional Demand by Segment* 2005 No
- Page 10 and 11: DuPont TiO 2 Plants and Lab Locatio
- Page 12 and 13: DuPont TiO 2 Milestones � 1931 -
- Page 14 and 15: The TiO 2 Process Feedstocks Proces
- Page 16 and 17: TiO 2 Manufacturing Processes Scrap
- Page 18 and 19: DuPont’s DuPont s Sustainable Chl
- Page 20 and 21: DuPont Advantages � Inventor of t
- Page 22 and 23: Chloride Process Block Diagram Cl 2
- Page 24 and 25: TiO 2 Properties � Superior Prope
DuPont and Titanium Dioxide<br />
April 2006<br />
© 2004 E.I. du Pont de Nemours and Company. All Rights Reserved. The DuPont oval, the miracles of science,<br />
DuPont and Product Name® are trademarks or registered trademarks of E. I. du Pont de Nemours and Company.
Titanium Dioxide<br />
� Premium white pigment<br />
– $9.3 Billion global Market<br />
– Highest “Hiding Power”<br />
– Critical ingredient<br />
� Coatings, Plastics, Paper and Paper<br />
Laminates<br />
� Other applications<br />
Plastics<br />
20%<br />
DUPONT CONFIDENTIAL<br />
» Printing inks, floor coverings, ceramics,<br />
textiles and fibers<br />
Paper<br />
10%<br />
Specialties<br />
10%<br />
Coatings<br />
60%<br />
<strong>TiO</strong> 2 Market - $9.3 Billion Industry<br />
<strong>TiO</strong> 2: : Decorative & Protective<br />
� Coatings<br />
� Plastics<br />
� Paper<br />
� Specialties<br />
2
<strong>TiO</strong> 2 - Applications<br />
� The most widely used white pigment in industry<br />
– Coatings<br />
DUPONT CONFIDENTIAL<br />
� Architectural, Industrial, Automotive<br />
– Plastics<br />
– Paper<br />
� Outdoor Furniture, Appliances, Plastic Bags & Boxes<br />
� Quality Magazines, Catalogs, Laminate<br />
– Specialty<br />
� Ink, Rubber, Leather, Elastomers<br />
3
<strong>TiO</strong> 2 Characteristics<br />
� 1918 - First Commercial plant<br />
– Still no cost effective functional alternatives to <strong>TiO</strong> 2<br />
� Highest light scattering efficiency<br />
� Chemically inert<br />
� Non-toxic<br />
� UV Barrier<br />
� Durable<br />
� Dispersible<br />
DUPONT CONFIDENTIAL<br />
4
A Global Industry<br />
Pigment Plants & Ore Sources<br />
DUPONT CONFIDENTIAL<br />
5
World <strong>TiO</strong> 2 Market Demand<br />
2005*<br />
North America<br />
1,230M tonnes<br />
1.5% AAG<br />
Latin America<br />
320M tonnes<br />
3.5% AAG<br />
DUPONT CONFIDENTIAL<br />
Europe ME/A<br />
1,570M tonnes<br />
3.0% AAG<br />
Total World: 4.5 Million tonnes<br />
3% AAG<br />
Asia Pacific<br />
1390M tonnes<br />
5% AAG<br />
* DuPont Estimate<br />
6
DuPont: World’s World s Leading <strong>TiO</strong> 2 Producer<br />
DUPONT CONFIDENTIAL<br />
Other<br />
33%<br />
Tronox<br />
12%<br />
Kronos<br />
10%<br />
DuPont<br />
21%<br />
Huntsman<br />
11%<br />
Lyondell<br />
13%<br />
7
Regional Demand by Segment*<br />
2005<br />
North America<br />
1,230 MT<br />
1.5%AAG<br />
Latin America<br />
320MT<br />
3.5% AAG<br />
DUPONT CONFIDENTIAL<br />
Coatings Plastics Paper Spec/other<br />
World Demand: 4.5 MMT<br />
3% AAG<br />
DuPont Share: 21%<br />
Europe, ME, Africa<br />
1,570MT<br />
3% AAG<br />
* DuPont Estimate<br />
AP Region<br />
1,390 MT<br />
5%AAG<br />
8
DuPont Titanium Technologies<br />
� Business Description<br />
– Titanium dioxide, specialty products<br />
and knowledge based offerings that<br />
enable our customers’ improved<br />
performance<br />
– Core Business to DuPont<br />
Corporation<br />
� Largest <strong>TiO</strong> 2 Producer and<br />
Technology Leader<br />
– 2005 Sales: $2Billion<br />
– Employees: ~ 2900<br />
– <strong>TiO</strong>2 Manufacturing Sites: 6<br />
– Technology Centers: 7<br />
DUPONT CONFIDENTIAL<br />
Paper<br />
Plastics<br />
Specialties<br />
Coatings<br />
DuPont Revenue: $2B<br />
9
DuPont <strong>TiO</strong> 2 Plants and Lab Locations<br />
DUPONT CONFIDENTIAL<br />
Plants<br />
Edge Moor, DE<br />
New Johnsonville, TN<br />
DeLisle, DeLisle,<br />
MS<br />
Altamira, Altamira,<br />
MX<br />
Uberaba, Uberaba,<br />
Brazil<br />
Kuan Yin,Taiwan<br />
Technical Service Centers<br />
Wilmington, DE<br />
Uberaba, Uberaba,<br />
Brazil<br />
Mechlen, Mechlen,<br />
Belgium<br />
Ulsan, Ulsan,<br />
Korea<br />
Mexico City, Mexico<br />
Kuan Yin, Taiwan<br />
Shanghai, China<br />
10
Chloride/Sulfate Capacity Trends<br />
(Mtonnes Mtonnes/year) /year)<br />
Global Totals by Technology* 2005 Totals by Producer*<br />
3500<br />
3000<br />
2500<br />
1400<br />
1200<br />
1000<br />
Chloride<br />
Sulfate<br />
2000<br />
800<br />
1500<br />
600<br />
1000<br />
400<br />
500<br />
200<br />
0<br />
0<br />
1984<br />
1987<br />
DUPONT CONFIDENTIAL<br />
1990<br />
1993<br />
1996<br />
1999<br />
2002<br />
Chloride Sulfate<br />
2005<br />
Emerging Small Scale, Low Quality Sulfate Capacity<br />
DuPont<br />
Huntsman<br />
Lyondell<br />
Kronos<br />
Tronox<br />
Kemira<br />
Isk<br />
Other<br />
11<br />
* DuPont Estimate
DuPont <strong>TiO</strong> 2 Milestones<br />
� 1931 - Acquisition of Krebs Pigment Co.<br />
� 1934 – Baltimore Sulfate Plant (Lithopone extended)<br />
� 1935 - Edge Moor Sulfate Plant (initially Lithopone extended pigment)<br />
� 1948 - Invented Chloride Process/Edge Moor Chloride Plant<br />
� 1959 - Johnsonville, TN Chloride Plant<br />
� 1959 – Altamira JV with Bancomer—2000 tonnes<br />
� 1963 - Antioch, CA Chloride Plant<br />
� 1965 – Introduced R-960 for durable coatings<br />
� 1968 – Baltimore Sulfate shutdown<br />
� 1972 - Johnsonville, TN, Line 2<br />
� 1973 - Antwerp Distribution Center<br />
� 1974 - Shutdown Edge Moor, DE Sulfate Plant<br />
� 1976 - Converted Altamira, MX Plant to Chloride<br />
DUPONT CONFIDENTIAL<br />
– DuPont: 100% Chloride Production<br />
� 1979 - DeLisle, MS Chloride Plant, Line 1<br />
� 1980 - Introduced RPS for paper industry<br />
� 1984 - Beijing, China Sales Office<br />
� 1986 - Shanghai, China Sales Office<br />
12
DuPont <strong>TiO</strong> 2 Milestones<br />
� 1989 - DuPont China Holding Established<br />
– Created dedicated Pigments sales force in EMEA<br />
� 1989 - DuPont China Holding Established1990 –<br />
� 1990 - Opened Mechlelen Lab for coatings 1991 - DeLisle, MS Line 2<br />
� 1993 - Kuan Yin, Taiwan Chloride Plant and<br />
– R-104 for Plastics<br />
� 1997 - Antioch Plant Closed<br />
� 1998 – Exit deepwells at Johnsonville<br />
� 1999 - Shanghai DuPont Titanium Technologies Lab - Grand Opening<br />
Ceremonies<br />
� 2000 - Johnsonville, TN, Line 3<br />
� 2002 - DuPont surpasses 1 Million tonnes of global capacity<br />
� 2003 - Tech Service Lab and Slurry facilities in Songjiang. Initiated<br />
Business Extension<br />
� 2004 - DuPont surpasses 1 Million tonnes of Sales!<br />
� 2005 - Negotiations progressing for China <strong>TiO</strong> 2 plant at Dong Ying<br />
DUPONT CONFIDENTIAL<br />
13
The <strong>TiO</strong> 2 Process<br />
Feedstocks<br />
Process Options<br />
The Sustainability Issue<br />
© 2004 E.I. du Pont de Nemours and Company. All Rights Reserved. The DuPont oval, the miracles of science,<br />
DuPont and Product Name® are trademarks or registered trademarks of E. I. du Pont de Nemours and Company.
Feedstock: Titanium Minerals<br />
Natural Occurring<br />
Beneficiates<br />
DUPONT CONFIDENTIAL<br />
– Titanium is a very abundant element in the earth crust. It exists in<br />
a number of minerals with a total world reserve of over 4 billion<br />
tonnes of contained <strong>TiO</strong> 2 .<br />
Dressing<br />
40 50 60 70 80 90 %<strong>TiO</strong> 2<br />
Ilmenite<br />
(TiFeO 3 )<br />
Acid leaching<br />
Slagging<br />
Slag<br />
Natural<br />
Rutile<br />
Synthetic<br />
Rutile<br />
15
<strong>TiO</strong> 2 Manufacturing Processes<br />
Scrap Iron<br />
Insoluble Solids<br />
& Waste Acid<br />
Copperas<br />
Pigment<br />
Base<br />
DUPONT CONFIDENTIAL<br />
Ilmenite<br />
SULFATE PROCESS CHLORIDE PROCESS<br />
Digestion Digestion<br />
Reduction<br />
Clarification<br />
Sulfuric Acid<br />
Crystallization Hydrolysis<br />
FeSO 4 -7H 2 O Filtration<br />
Calcination<br />
Slag<br />
Clarification<br />
Waste Acid<br />
Waste<br />
Acid<br />
Rutile,Synthetic Rutile,Slag, Ilmenite<br />
Coke Chlorine<br />
Metal<br />
Chlorides<br />
Chlorination<br />
Purification<br />
Oxygen Chlorine<br />
Oxidation<br />
Wet treatment Filtration Washing Drying Grinding Finished<br />
<strong>TiO</strong> 2<br />
16
Chloride Process Has Advantages<br />
� Old Process<br />
DUPONT CONFIDENTIAL<br />
SULFATE<br />
– Sulfuric Acid<br />
– Batch Process<br />
� More Waste<br />
– 3-4 tonnes of copperas (red<br />
mud) and 8 tonnes of spent acid<br />
per <strong>TiO</strong> 2 tonne<br />
� Produces Anatase and Rutile <strong>TiO</strong> 2<br />
– Additional processing required<br />
for crystal structure conversion<br />
CHLORIDE<br />
� “New” Technology<br />
– Chlorine Gas<br />
– Continuous Process<br />
� Less Waste<br />
– Up to 1.6 tonnes Iron Chloride<br />
per <strong>TiO</strong> 2 tonne<br />
� Produces Rutile <strong>TiO</strong> 2<br />
– Preferred crystalline form for<br />
maximum hiding power<br />
17
DuPont’s DuPont s Sustainable Chlorination Process<br />
� A life cycle view<br />
Low<br />
Grade Ore<br />
Energy Input<br />
Waste Rejection<br />
� Environmentally and economically more sustainable<br />
DUPONT CONFIDENTIAL<br />
Beneficiation<br />
Process<br />
Chlorination<br />
Process<br />
High<br />
Grade Ore<br />
Conventional<br />
Chlorination<br />
Process<br />
Purified<br />
TiCl 4<br />
<strong>TiO</strong> 2<br />
18
Back-Up Back Up Charts<br />
DUPONT CONFIDENTIAL<br />
19
DuPont Advantages<br />
� Inventor of the Chloride technology<br />
� Superior technologies and products<br />
� Lowest cost producer<br />
� World’s largest <strong>TiO</strong> 2 supplier<br />
DUPONT CONFIDENTIAL<br />
20
Ilmenite<br />
Ore<br />
<strong>TiO</strong> 2 Sulfate Process: Conceptual Flowsheet<br />
Water<br />
Ball Mill<br />
(-325<br />
mesh)<br />
Insoluble<br />
Solids<br />
Copperas Solids<br />
(FeSO 4 -7H 2 O)<br />
DUPONT CONFIDENTIAL<br />
Ilmenite<br />
Digestor<br />
(Batch)<br />
Solids<br />
Thickener<br />
Solids Filter<br />
and<br />
Centrifuge<br />
Copperas<br />
Filter<br />
Sulfuric<br />
Acid<br />
Evaporative<br />
Crystallizer<br />
150C<br />
Scrap Fe<br />
108°C<br />
Recycle<br />
H 2 SO 4<br />
(18%)<br />
Waste<br />
H 2 SO 4<br />
(3%)<br />
Vacuum<br />
Evaporator<br />
Titanyl<br />
Sulfate<br />
Hydrolyzer<br />
Filter and<br />
Wash Tank<br />
Hydrous <strong>TiO</strong>2 Precipitate<br />
Bleaching<br />
50°C Reactor<br />
Salt Treatment<br />
950°C<br />
<strong>TiO</strong> 2 Solids<br />
Filter and<br />
Wash Tank<br />
<strong>TiO</strong> 2<br />
Calciner<br />
Waste<br />
H 2 SO 4<br />
Sulfuric<br />
Acid<br />
Seed Nuclei<br />
and Zinc Metal<br />
Pigment<br />
Grinding<br />
Pigment<br />
Coating<br />
Treatment<br />
Pigment<br />
Filtration and<br />
Washing<br />
Dryer<br />
Micronizers<br />
Storage,<br />
Blending<br />
and<br />
Shipping<br />
<strong>TiO</strong> 2 Pigment<br />
Coating<br />
Reagents<br />
21
Chloride Process Block Diagram<br />
Cl 2<br />
Cl2 Plant<br />
O2 Plant<br />
Steam<br />
DUPONT CONFIDENTIAL<br />
O 2<br />
Cl 2<br />
Cl2 Cl Ilmenite Coke<br />
Chlorination<br />
Purification<br />
Oxidation<br />
Pigment base<br />
Wet Treatment<br />
Filtration,<br />
Washing, Drying<br />
Grinding<br />
<strong>TiO</strong>2 <strong>TiO</strong> Product<br />
2Fe<strong>TiO</strong> 3 + 6 Cl 2 --> 2TiCl 4 + 2FeCl 2 + 3O 2<br />
Metal chloride liquor for UI<br />
Unreacted coke and ore for landfill<br />
TiCl 4 + O 2 --> <strong>TiO</strong> 2 +2Cl 2<br />
Wash water (discharged after treatment)<br />
Frond end<br />
Finishing<br />
Integrated suppliers<br />
22
<strong>TiO</strong> 2 Value Chain<br />
Raw Materials<br />
Titanium Ore<br />
Chlorine<br />
Coke<br />
Sulfuric<br />
Acid<br />
DUPONT CONFIDENTIAL<br />
<strong>TiO</strong> 2Producers<br />
DuPont<br />
Tioxide<br />
MIC/Thann<br />
/Tibras<br />
Kronos<br />
Kerr McGee/<br />
Bayer<br />
Other<br />
Customer Level 2<br />
Paint Producer<br />
- Architectural<br />
- Auto/Industrial<br />
PVC Profile<br />
Producer<br />
Powder Coatings<br />
Producer<br />
Laminate Paper<br />
Producer<br />
Engg. Polymer<br />
Compounder<br />
Paper Producer<br />
Coated Board<br />
Producer<br />
Polyolefin<br />
Masterbatch<br />
Compounder<br />
Other/Specialties<br />
Laminator<br />
Processor<br />
Packaging<br />
Materials<br />
Converter<br />
Customer Level 1<br />
Home Impr. Centers<br />
- Building Supplies<br />
- Paint<br />
- Hardware<br />
Contractors<br />
Construction<br />
OEM<br />
- Auto/Indust. Prod<br />
- Appliances<br />
-Furniture<br />
-Electronics<br />
Printing/Publishing<br />
Packaged Retail Sales<br />
= Growing Power Centers<br />
23<br />
C<br />
O<br />
N<br />
S<br />
U<br />
M<br />
E<br />
R<br />
S
<strong>TiO</strong> 2 Properties<br />
� Superior Properties As A White Pigment<br />
DUPONT CONFIDENTIAL<br />
– High refractive index - Whiteness, Brightness, Opacity<br />
– Chemically inert<br />
– Disperse easily<br />
– UV absorber<br />
24
Sustainable Core Growth: Objectives<br />
● Reduce environmental footprint<br />
● Environmentally sustainable operations<br />
DUPONT CONFIDENTIAL<br />
● Manage business profitably in cyclical industry<br />
● Develop Growth Opportunities<br />
Footprint<br />
Market<br />
Productivity<br />
● Leading Technology and human<br />
capital to improve productivity<br />
25
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