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Water Quality in Slovenia - Agencija RS za okolje

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S U R F A C E W A T E R S<br />

Compliant to the regulations, the quality of fresh water needed for the life of fish species is evaluated for each<br />

year <strong>in</strong>dividually, accord<strong>in</strong>g to the mandatory and guide values for salmonid and cypr<strong>in</strong>id waters, specified<br />

<strong>in</strong> Table 10. Only the results of the samples collected <strong>in</strong> exceptional natural conditions are excluded. The<br />

mandatory or guide values of salmonid and cypr<strong>in</strong>id waters are not exceeded, if the measurements of the<br />

samples collected with<strong>in</strong> the m<strong>in</strong>imum frequency of a one-year period shows that:<br />

• 95% of samples do not exceed the mandatory or guide values for the parameters pH, BOD , non-<br />

5<br />

ionized ammonia, total ammonium, nitrite, total residual chlor<strong>in</strong>e, total z<strong>in</strong>c and dissolved copper;<br />

when the sampl<strong>in</strong>g frequency is lower than one sample per month, both the abovementioned<br />

values and comments shall be respected for all the samples,<br />

• the percentage of samples perta<strong>in</strong><strong>in</strong>g to the ‘dissolved oxygen’ parameter, as listed <strong>in</strong> Table 10, is<br />

not lower than the mandatory or guide values,<br />

• the average concentration def<strong>in</strong>ed for the ‘suspended solids’, does not exceed the mandatory or<br />

guide values.<br />

Salmonid or cypr<strong>in</strong>id water is of not compliant quality and is considered over polluted if the<br />

results, accord<strong>in</strong>g to the above-mentioned evaluation show that the mandatory values have been<br />

exceeded.<br />

Table 10: Mandatory and guide values for salmonid and cypr<strong>in</strong>id waters<br />

Parameter Expressed<br />

as<br />

Unit<br />

Dissolved oxygen (1) O 2 mg/L<br />

pH<br />

Salmonid waters Cypr<strong>in</strong>id waters<br />

Guide value<br />

50% ≥ 9<br />

100% ≥ 7<br />

Mandatory<br />

value<br />

50% ≥ 9<br />

100% ≥ 6<br />

6 - 9<br />

∆± 0.5 (2)<br />

Guide value<br />

50% ≥ 8<br />

100% ≥ 5<br />

Mandatory<br />

value<br />

50% ≥ 7<br />

100% ≥ 4<br />

6 - 9<br />

∆± 0.5 (2)<br />

Suspended solids mg/L ≤ 25 ≤ 25<br />

BOD5 O2 mg/L ≤ 3 ≤ 6<br />

Total phosphorus PO4 mg/L ≤ 0.2 ≤ 0.4<br />

Nitrite NO2 mg/L ≤ 0.01 ≤ 0.03<br />

Ammonia NH3 mg/L ≤ 0.005 ≤ 0.025 ≤ 0.005 ≤ 0.025<br />

Ammonium NH4 mg/L ≤ 0.04 ≤ 1 ≤ 0.2 ≤ 1<br />

Total residual chlor<strong>in</strong>e HOCl mg/L ≤ 0.005 ≤ 0.005<br />

Total z<strong>in</strong>c (3) , Zn mg/L 0.3 1.0<br />

Dissolved copper (3) , Cu mg/L 0.04 0.04<br />

(1) The percentage represents the number of samples collected <strong>in</strong> a one-year period<br />

(2) Artificially <strong>in</strong>duced pH changes must not exceed ± 0.5<br />

(3) The values coresponded to water hardness of 100 mg/L CaCO3<br />

The quality of salmonid and cypr<strong>in</strong>id waters <strong>in</strong> 2006 is shown <strong>in</strong> Map 9. In salmonid water sections,<br />

the mandatory values were not exceeded at any monitor<strong>in</strong>g sites; <strong>in</strong> cypr<strong>in</strong>id water sections, a not<br />

compliant quality of the Dragonja at Podkaštel was determ<strong>in</strong>ed due to too low oxygen concentration<br />

<strong>in</strong> one sample.<br />

The assessment of the salmonid and cypr<strong>in</strong>id water sections quality <strong>in</strong> the years 2003 to 2006 is<br />

presented <strong>in</strong> Table 11; not compliant parameters are shown <strong>in</strong> Table 12.<br />

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