chapter 2 palladium catalysts in suzuki cross- coupling reaction
chapter 2 palladium catalysts in suzuki cross- coupling reaction
chapter 2 palladium catalysts in suzuki cross- coupling reaction
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3.3.3. Preparation of Zeolite-Supported Metal Catalysts<br />
Metals can be <strong>in</strong>troduced <strong>in</strong>to a zeolite by basically two procedures accord<strong>in</strong>g to<br />
the chemical composition of metal ion; the ion exchange and sorption method. If the<br />
metal forms cations, negative charge carried by AlO2 unit is neutralized by these cations<br />
through ion exchange. In the sorption method, neutral metal compounds are treated with<br />
zeolite. As for synthesis of metal complexes which dimensions exceed pore size, the<br />
ship-<strong>in</strong>-bottle method is used to immobilize such complexes with<strong>in</strong> the zeolite cavities<br />
(Figure 3.16). The ship <strong>in</strong> bottle is used to immobilize such complexes with<strong>in</strong> the<br />
zeolite cavities provid<strong>in</strong>g an opportunity to heterogenize a homogeneous catalyst<br />
system (Weitkamp and Puppe 1999).<br />
Figure 3.16. Ship <strong>in</strong> bottle synthesis<br />
(Source: Weitkamp and Puppe 1999)<br />
In their study, Djakovitch et al. prepared [Pd]-exchanged NaY zeolite by ionexchange<br />
method and characterized by MAS-NMR (Figure 3.17) (Djakovitch et al.<br />
2001, Djakovitch et al. 1999).<br />
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