- Page 1 and 2:
SHORT-TIME SUZUKI REACTIONS OF ARYL
- Page 3 and 4:
ACKNOWLEDGEMENTS Firstly, I’d lik
- Page 5 and 6:
ÖZET ARİL HALOJENÜRLERİN HAVA A
- Page 7 and 8:
3.2.2. Catalysts Anchored to Inorga
- Page 9 and 10:
LIST OF FIGURES Figure Page Figure
- Page 11 and 12:
Figure A.27. 13 C NMR of 4-cyanobip
- Page 13 and 14:
CHAPTER 1 INTRODUCTION The palladiu
- Page 15 and 16:
CHAPTER 2 PALLADIUM CATALYSTS IN SU
- Page 17 and 18:
2.1.2. The Coordination Geometry of
- Page 19 and 20:
R 1 R 1 4. Sonogashira Reaction: H
- Page 21 and 22:
2.2.1. Mechanism of Suzuki Coupling
- Page 23 and 24:
As a result, organic group or hydri
- Page 25 and 26:
2.2.2.2. Halogen Effect Nearly all
- Page 27 and 28:
found to be excellent complexes for
- Page 29 and 30:
R Table 2.2. Examples from literatu
- Page 31 and 32:
L R Pd X R Pd L OR'' X L L + OR' R'
- Page 33 and 34:
omides and iodides is performed eff
- Page 35 and 36:
times for the transformation of a l
- Page 37 and 38:
R Br + (HO) 2B R' 5% Pd(OAc) 2 15%
- Page 39 and 40:
of insoluble solids are among the m
- Page 41 and 42:
could be reused multiple times. The
- Page 43 and 44:
3.2.2. Catalysts Anchored to Inorga
- Page 45 and 46:
SO 2NH N Pd SO 2 N SO 2 NH NH H O1.
- Page 47 and 48:
utilized them in Heck and Suzuki co
- Page 49 and 50:
Smith et al introduced the use of P
- Page 51 and 52:
• Complexes immobilized in zeolit
- Page 53 and 54:
3.3.3. Preparation of Zeolite-Suppo
- Page 55 and 56:
CHAPTER 4 EXPERIMENTAL STUDY 4.1. P
- Page 57 and 58:
temperature, the catalyst was recov
- Page 59 and 60:
amount of both reactant and product
- Page 61 and 62:
4-Methoxybiphenyl: 1 H NMR (400 MHz
- Page 63 and 64:
51 Table 4.1. Purification of coupl
- Page 65 and 66:
CHAPTER 5 RESULTS AND DISCUSSIONS I
- Page 67 and 68:
Table 5.2. The effect of base on Pd
- Page 69 and 70:
Table 5.4. The Optimization of Pd-N
- Page 71 and 72:
H 3COC Table 5.5. Effect of zeolite
- Page 73 and 74:
Table 5.6. Pd(NH3)4 2+ -loaded NaY
- Page 75 and 76:
The type of other organic co-solven
- Page 77 and 78:
yield was very low (Table 5.8, entr
- Page 79 and 80:
evealed excellent reactivity toward
- Page 81 and 82:
CHAPTER 6 CONCLUSIONS In this thesi
- Page 83 and 84:
REFERENCES Albisson, D.A., Bedford,
- Page 85 and 86: Choudary, B.M., Madhi, S., Chowdari
- Page 87 and 88: Heiden, M. Plenio, H. 2004. ‘‘H
- Page 89 and 90: Coupling Reactions of Aryl Chloride
- Page 91 and 92: Phan, N.T.S., Brown, D.H., Styring,
- Page 93 and 94: Wolfe, J.P., Singer, R.A., Yang, B.
- Page 95 and 96: Figure A.1. 13 C NMR of 1-phenylnap
- Page 97 and 98: Figure A.3. 13 C NMR of 2-acetylbip
- Page 99 and 100: Figure A.5 . 13 C NMR of 2-methoxyb
- Page 101 and 102: Figure A.7. 13 C NMR of 2-methylbip
- Page 103 and 104: Figure A.9. 13 C NMR of 2-phenylnap
- Page 105 and 106: Figure A.11. 13 C NMR of 3-acetylbi
- Page 107 and 108: Figure A.13. 13 C NMR of 3-methoxyb
- Page 109 and 110: Figure A.15. 13 C NMR of 3-phenylpy
- Page 111 and 112: Figure A.17. 13 C NMR of 4-acetyl-4
- Page 113 and 114: Figure A.19. 13 C NMR of 4-methoxyb
- Page 115 and 116: Figure A.21. 13 C NMR of 4-methylbi
- Page 117 and 118: Figure A.23. 13 C NMR of 4-phenylbe
- Page 119 and 120: Figure A.25. 13 C NMR of 4-acetylbi
- Page 121 and 122: Figure A.27. 13 C NMR of 4-cyanobip
- Page 123 and 124: Figure A.29. 13 C NMR of 4-nitrobip
- Page 125 and 126: Figure A.31. 13 C NMR of 4-phenylan
- Page 127 and 128: APPENDIX B MASS SPECTRUMS OF SUZUKI
- Page 129 and 130: Figure B.2. Mass spectrum of 2-acet
- Page 131 and 132: Figure B.4. Mass spectrum of 2-meth
- Page 133 and 134: Figure B.6. Mass spectrum of 3-acet
- Page 135: Figure B.8. Mass spectrum of 3-phen
- Page 139 and 140: Figure B.12. Mass spectrum of 4-met
- Page 141 and 142: Figure B.14. Mass spectrum of 4-cya
- Page 143: Figure B.16. Mass spectrum of 4-met